The C–H functionalization has been extensively studied as a direct C–C bond forming reaction with high atomic efficiency. The efforts have also been made on the reaction using supported catalysts, which are superior in terms of catalyst separation from the reaction mixture and reusability. In this review, an overview of the C–H functionalization reactions, especially for Pd and Au supported catalysts will be described. In particular, we discuss reaction mechanisms, active species, leaching, reusability, etc.
1 Introduction
2 Types of supported metal catalysts and their active species
3 Modes of C–H bond activation
4 Oxidative C–H C–H coupling of aryl compounds
5 C–H C–H coupling where one side is aromatic
6 C–H acylation of aromatic compounds and related reactions
7 Conclusion