Molecular Adsorption Kinetics: Nonlinear Entropy–Enthalpy Loss Quantified by Constrained AIMD and Insights into the Adsorption-Site Determination on Metal Oxides

An analysis combining SERS and current–voltage response measurements with DFT calculations has identified the molecular adsorption site in a single molecule junction.

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A fundamental study of adsorption kinetics of surfactants onto metal oxides using quartz crystal microbalance with dissipation (QCM-D)

Colloids and Surfaces A Physicochemical and Engineering Aspects ◽

10.1016/j.colsurfa.2019.124237 ◽

2020 ◽

Vol 586 ◽

pp. 124237 ◽

Cited By ~ 4

Author(s):

Sandra C. Medina ◽

Andreia S.F. Farinha ◽

Abdul-Hamid Emwas ◽

Assiyeh Tabatabai ◽

TorOve Leiknes

Keyword(s):

Metal Oxides ◽

Quartz Crystal Microbalance ◽

Adsorption Kinetics ◽

Quartz Crystal ◽

Fundamental Study ◽

Kinetics Of

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Molecular adsorption on the surface of strongly correlated transition-metal oxides: A case study for CO/NiO(100)

Physical Review B ◽

10.1103/physrevb.69.075413 ◽

2004 ◽

Vol 69 (7) ◽

Cited By ~ 176

Author(s):

A. Rohrbach ◽

J. Hafner ◽

G. Kresse

Keyword(s):

Transition Metal ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Molecular Adsorption ◽

Strongly Correlated

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Infection of Escherichia coli with bacteriophages

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100063767 ◽

1969 ◽

Vol 27 ◽

pp. 370-371

Author(s):

Manfred E. Bayer

Keyword(s):

Escherichia Coli ◽

Nucleic Acid ◽

Cell Surface ◽

Virus Type ◽

Infection Process ◽

Adsorption Site ◽

The Other ◽

Specific Receptors ◽

Bacterial Receptors

The first step in the infection of a bacterium by a virus consists of a collision between cell and bacteriophage. The presence of virus-specific receptors on the cell surface will trigger a number of events leading eventually to release of the phage nucleic acid. The execution of the various "steps" in the infection process varies from one virus-type to the other, depending on the anatomy of the virus. Small viruses like ØX 174 and MS2 adsorb directly with their capsid to the bacterial receptors, while other phages possess attachment organelles of varying complexity. In bacteriophages T3 (Fig. 1) and T7 the small conical processes of their heads point toward the adsorption site; a welldefined baseplate is attached to the head of P22; heads without baseplates are not infective.

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HREM Study of electron-induced surface radiation damage in ReO3

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100087495 ◽

1991 ◽

Vol 49 ◽

pp. 636-637

Author(s):

R. Ai ◽

H.-J. Fan ◽

L. D. Marks

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Metal Oxides ◽

Electron Irradiation ◽

Transition Metal Oxides ◽

Carbon Film ◽

Transition Metal Ions ◽

Surface Radiation ◽

Valence Transition ◽

Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

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Problems with oxygen analysis in the system MgO-Al2O3-SiO2 with the electron microprobe

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100132753 ◽

1992 ◽

Vol 50 (2) ◽

pp. 1624-1625

Author(s):

Michel Fialin ◽

Guy Rémond

Keyword(s):

Transition Metal ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Electrostatic Charge ◽

Carbon Layer ◽

Sample Holder ◽

Rock Matrix ◽

Electrical Discharges ◽

Thin Carbon ◽

Beam Instabilities

Oxygen-bearing minerals are generally strong insulators (e.g. silicates), or if not (e.g. transition metal oxides), they are included within a rock matrix which electrically isolates them from the sample holder contacts. In this respect, a thin carbon layer (150 Å in our laboratory) is evaporated on the sections in order to restore the conductivity. For silicates, overestimated oxygen concentrations are usually noted when transition metal oxides are used as standards. These trends corroborate the results of Bastin and Heijligers on MgO, Al2O3 and SiO2. According to our experiments, these errors are independent of the accelerating voltage used (fig.l).Owing to the low density of preexisting defects within the Al2O3 single-crystal, no significant charge buildup occurs under irradiation at low accelerating voltage (< 10keV). As a consequence, neither beam instabilities, due to electrical discharges within the excited volume, nor losses of energy for beam electrons before striking the sample, due to the presence of the electrostatic charge-induced potential, are noted : measurements from both coated and uncoated samples give comparable results which demonstrates that the carbon coating is not the cause of the observed errors.

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