In Situ Observation of Lithiation and Delithiation Reactions of a Silicon Thin Film Electrode for All-Solid-State Lithium-Ion Batteries by X-ray Photoelectron Spectroscopy

2020 ◽  
Vol 11 (16) ◽  
pp. 6649-6654 ◽  
Author(s):  
Raimu Endo ◽  
Tsuyoshi Ohnishi ◽  
Kazunori Takada ◽  
Takuya Masuda
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Lithium Ion Batteries ◽  
Photoelectron Spectroscopy ◽  
Lithium Ion ◽  
In Situ Observation ◽  
Film Electrode ◽  
Silicon Thin Film ◽  
X Ray

scholarly journals Operando hard X-ray photoelectron spectroscopy of LiCoO2 thin film in an all-solid-state lithium ion battery

2020 ◽  
Vol 118 ◽  
pp. 106790
Author(s):  
Hisao Kiuchi ◽  
Kazuhiro Hikima ◽  
Keisuke Shimizu ◽  
Ryoji Kanno ◽  
Fukunaga Toshiharu ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Lithium Ion Battery ◽  
Photoelectron Spectroscopy ◽  
Lithium Ion ◽  
X Ray

scholarly journals Electrochemical study on nickel aluminum layered double hydroxides as high-performance electrode material for lithium-ion batteries based on sodium alginate binder

2021 ◽  
Author(s):  
Xinyue Li ◽  
Marco Fortunato ◽  
Anna Maria Cardinale ◽  
Angelina Sarapulova ◽  
Christian Njel ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Material ◽  
Photoelectron Spectroscopy ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Electrochemical Study ◽  
Ex Situ ◽  
Potential Range ◽  
X Ray ◽  
Storage Mechanism

AbstractNickel aluminum layered double hydroxide (NiAl LDH) with nitrate in its interlayer is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the performance of the material is investigated in 1 M LiPF6 in EC/DMC vs. Li. The NiAl LDH electrode based on sodium alginate (SA) binder shows a high initial discharge specific capacity of 2586 mAh g−1 at 0.05 A g−1 and good stability in the potential range of 0.01–3.0 V vs. Li+/Li, which is better than what obtained with a polyvinylidene difluoride (PVDF)-based electrode. The NiAl LDH electrode with SA binder shows, after 400 cycles at 0.5 A g−1, a cycling retention of 42.2% with a capacity of 697 mAh g−1 and at a high current density of 1.0 A g−1 shows a retention of 27.6% with a capacity of 388 mAh g−1 over 1400 cycles. In the same conditions, the PVDF-based electrode retains only 15.6% with a capacity of 182 mAh g−1 and 8.5% with a capacity of 121 mAh g−1, respectively. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. Graphical abstract The as-prepared NiAl-NO3−-LDH with the rhombohedral R-3 m space group is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the material’s performance is investigated in 1 M LiPF6 in EC/DMC vs. Li. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. This work highlights the possibility of the direct application of NiAl LDH materials as negative electrodes for LIBs.

scholarly journals In‐situ/operando (soft) X‐ray spectroscopy study of beyond lithium‐ion batteries

2021 ◽  
Author(s):  
Feipeng Yang ◽  
Xuefei Feng ◽  
Yi‐Sheng Liu ◽  
Li Cheng Kao ◽  
Per‐Anders Glans ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Spectroscopy Study ◽  
X Ray

Thin-Film Solid State Lithium-Ion Batteries of the LiCoC2/LiPON/Si@O@Al System

2021 ◽  
Vol 50 (5) ◽  
pp. 333-338
Author(s):  
A. S. Rudy ◽  
A. A. Mironenko ◽  
V. V. Naumov ◽  
I. S. Fedorov ◽  
A. M. Skundin ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Lithium Ion Batteries ◽  
Lithium Ion
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