Investigation on Low-Temperature Thermoelectric Properties of Ag2Se Polycrystal Fabricated by Using Zone-Melting Method

Author(s):  
Min Jin ◽  
Jiasheng Liang ◽  
Pengfei Qiu ◽  
Hui Huang ◽  
Zhongmou Yue ◽  
...  
2008 ◽  
Vol 368-372 ◽  
pp. 547-549
Author(s):  
Jun Jiang ◽  
Ya Li Li ◽  
Gao Jie Xu ◽  
Ping Cui ◽  
Li Dong Chen

In the present study, n-type (Bi2Se3)x(Bi2Te3)1-x crystals with various chemical compositions were fabricated by the zone melting method. Thermoelectric properties, including Seebeck coefficient (α), electrical conductivity (σ) and thermal conductivity (κ), were measured in the temperature range of 300-500 K. The influence of the variations of Bi2Te3 and Bi2Se3 content on thermoelectric properties was studied. The increase of Bi2Se3 content (x) caused an increase in carrier concentration and thus an increase of σ and a decrease of α. The maximum figure of merit (ZT = α2σT/κ) of 0.87 was obtained at about 325 K for the composition of 93%Bi2Te3-7%Bi2Se3 with doping TeI4.


2001 ◽  
Vol 294 (1-2) ◽  
pp. 202-205 ◽  
Author(s):  
Yuji Arita ◽  
Satoshi Mitsuda ◽  
Yoshimasa Nishi ◽  
Tsuneo Matsui ◽  
Takanori Nagasaki

2012 ◽  
Vol 512-515 ◽  
pp. 1647-1650
Author(s):  
Ting Zhang ◽  
Jun Jiang ◽  
Sheng Hui Yang ◽  
Yong Biao Zhai ◽  
Gao Jie Xu

A series of n-type BiTeSe/ZnAlO composites were prepared by zone melting method. Thermoelectric properties, including the electrical conductivity σ, Seebeck coefficient α and thermal conductivity κ, were measured in the temperature range of 300-550K. Results show that the electrical properties have been slightly lowered due to the reduced carrier concentration by ZnAlO addition. However, the low-temperature-shifted peak α, resulting from the prematurely happened intrinsic excitation, have shifted peak ZT to lower temperatures. As a result, the ZT values at 300 K were significantly enhanced for BiTeSe/ZnAlO composites compared to that of BiTeSe, making more attractive for cooling applications at ambient temperature.


1994 ◽  
Vol 35 (12) ◽  
pp. 923-926 ◽  
Author(s):  
Akihisa Inoue ◽  
Yoshihiko Yokoyama ◽  
Yoshiyuki Shinohara ◽  
Tsuyoshi Masumoto

1979 ◽  
Vol 9 (12) ◽  
pp. 2387-2398 ◽  
Author(s):  
J Boxus ◽  
J Heremans ◽  
J -P Michenaud ◽  
J -P Issi

2009 ◽  
Vol 79 (23) ◽  
Author(s):  
C. Candolfi ◽  
B. Lenoir ◽  
A. Dauscher ◽  
J. Hejtmánek ◽  
J. Tobola

2013 ◽  
Vol 06 (05) ◽  
pp. 1340008 ◽  
Author(s):  
DALE HITCHCOCK ◽  
YEN-LIANG LIU ◽  
YUFEI LIU ◽  
TERRY M. TRITT ◽  
JIAN HE ◽  
...  

Over the past decade the widely used p-type ( Bi 2-x Sb x) Te 3 bulk thermoelectric materials have been subject to various nanostructuring processes for higher thermoelectric performance. However, these nanostructuring processing were conducted on compositions optimized for bulk materials (x ~ 1.52–1.55). This leads to the question of whether the optimal composition for bulk materials is the same for their nanoscale counterparts. In this work we hydrothermally grew Bi 2-x Sb x Te 3 nanopowders (nominally, x = 1.46, 1.48, 1.52 and 1.55) and measured their thermoelectric properties on cold-pressed vacuum-sintered pellets (74–78% of the theoretical density) below 300 K. The measurements were conducted 18 months apart to probe the aging phenomena, with the samples stored in ambient conditions. We have found that (i) the peak of thermopower shifts to lower temperatures upon nanostructuring but it shifts back to higher temperatures upon aging; (ii) the electrical conductivity degrades by a factor of 1.5–2.3 upon aging while the temperature dependence is largely retained; and (iii) the ZT of freshly made samples is sensitive to the x value, a maximum ZT ~ 1.25(~ 0.62) at ~ 270 K (~ 255 K) was attained in the freshly made sample x = 1.55(x = 1.46), respectively; while the ZT of aged samples is significantly lowered by a factor of 2–4 but lesser x-dependent. These observations have been discussed in the context of charge buildup and compensation at grain boundaries.


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