(η4-Tetrafluorobenzobarrelene)-η1-((tri-4-fluorophenyl)phosphine)-η1-(2-phenylphenyl)rhodium(I): A Catalyst for the Living Polymerization of Phenylacetylenes

2021 ◽  
Author(s):  
Nicholas Sheng Loong Tan ◽  
Gareth L. Nealon ◽  
Stephen A. Moggach ◽  
Jason M. Lynam ◽  
Mark I. Ogden ◽  
...  
Keyword(s):  
Living Polymerization

Controlled and Efficient Polymerization of Methyl Methacrylate Catalyzed by Pyridinylidenaminophosphines Based Lewis Pairs

2021 ◽  
Author(s):  
Fang Ge ◽  
Sun Li ◽  
Zhe Wang ◽  
Wenzhong Zhang ◽  
Xiaowu Wang
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Living Polymerization ◽  
Narrow Molecular Weight Distribution ◽  
Synthetic Approaches ◽  
Lewis Pairs

Developing different synthetic approaches to realize controlled or living polymerization are aspirational to achieve polymers with defined molecular weight, narrow molecular weight distribution and unambiguous structures by polymer chemists. Herein,...

Living Polymerization Caught in the Act: Direct Observation of an Arrested Intermediate in Metathesis Polymerization

2019 ◽  
Vol 141 (25) ◽  
pp. 10039-10047 ◽  
Author(s):  
Jung-Ah Song ◽  
Bohyun Park ◽  
Soohyung Kim ◽  
Cheol Kang ◽  
Dongwhan Lee ◽  
...  
Keyword(s):  
Direct Observation ◽  
Living Polymerization ◽  
Metathesis Polymerization

Synthesis of PMMA-b-PS Block Copolymer by Emulsion ATRP and its Self-Assembly Property

2013 ◽  
Vol 705 ◽  
pp. 115-119
Author(s):  
Bao Yong Tian ◽  
Er Jun Tang ◽  
Miao Yuan ◽  
Rui Xia Hao ◽  
Cun Man Li ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Block Copolymer ◽  
Self Assembly ◽  
Potential Application ◽  
Morphological Characteristic ◽  
Living Polymerization ◽  
The Self ◽  
Emulsion System ◽  
Copolymer Concentration ◽  
Ft Ir

The well-defined block copolymer PMMA-b-PS was prepared by two-step ATRP in emulsion system. GPC results indicate that Mn increased linearly with conversion and polydispersity remained relatively narrow. It presents the characteristics of living polymerization in emulsion system. FT-IR demonstrated that block copolymer PMMA-b-PS could be successfully synthesized by ATRP with macroinitiator PMMA-Cl in emulsion system. The morphological characteristic of the self-assembly depends on the block copolymer concentration and transforms between spheres and rodlike micelles. The property indicates a perfect potential application in drug delivery materials.

scholarly journals Living Polymerization of Propylene with ansa-Dimethylsilylene(fluorenyl)(cumylamido) Titanium Complexes

Polymers ◽  
2017 ◽  
Vol 9 (12) ◽  
pp. 131 ◽  
Author(s):  
Huajin Wang ◽  
Xinwei Wang ◽  
Yanjie Sun ◽  
Hailong Cheng ◽  
Takeshi Shiono ◽  
...  
Keyword(s):  
Living Polymerization ◽  
Titanium Complexes

Novel Rare Earth Catalysts for the Living Polymerization and Block Copolymerization of ε-Caprolactone

1996 ◽  
Vol 29 (26) ◽  
pp. 8289-8295 ◽  
Author(s):  
Youqing Shen ◽  
Zhiquan Shen ◽  
Yifeng Zhang ◽  
Kemin Yao
Keyword(s):  
Rare Earth ◽  
Living Polymerization ◽  
Block Copolymerization

scholarly journals A versatile living polymerization method for aromatic amides

2021 ◽  
Author(s):  
Subhajit Pal ◽  
Dinh Phuong Trinh Nguyen ◽  
Angélique Molliet ◽  
Mahshid Alizadeh ◽  
Aurélien Crochet ◽  
...  
Keyword(s):  
Living Polymerization ◽  
Polymerization Method

Living polymerization of naturally renewable butyrolactone-based vinylidenes mediated by a frustrated Lewis pair

2021 ◽  
Vol 12 (38) ◽  
pp. 5548-5555
Author(s):  
Yun Bai ◽  
Huaiyu Wang ◽  
Jianghua He ◽  
Yuetao Zhang
Keyword(s):  
Lewis Acid ◽  
Living Polymerization ◽  
Controlled Polymerization ◽  
Frustrated Lewis Pair

The frustrated Lewis pair composed of an organophosphorus(iii) superbase and a bulky organoaluminum Lewis acid promoted the living/controlled polymerization of naturally renewable butyrolactone-based vinylidenes.

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