Controlling Domain Spacing and Grain Size in Cylindrical Block Copolymer Thin Films by Means of Thermal and Solvent Vapor Annealing

2016 ◽  
Vol 49 (9) ◽  
pp. 3373-3381 ◽  
Author(s):  
Xiaodan Gu ◽  
Ilja Gunkel ◽  
Alexander Hexemer ◽  
Thomas P. Russell
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Block Copolymer ◽  
Solvent Vapor ◽  
Vapor Annealing ◽  
Solvent Vapor Annealing ◽  
Cylindrical Block

scholarly journals Widely Tunable Morphologies in Block Copolymer Thin Films Through Solvent Vapor Annealing Using Mixtures of Selective Solvents

2015 ◽  
Vol 25 (20) ◽  
pp. 3057-3065 ◽  
Author(s):  
Michelle A. Chavis ◽  
Detlef-M. Smilgies ◽  
Ulrich B. Wiesner ◽  
Christopher K. Ober
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Solvent Vapor ◽  
Selective Solvents ◽  
Vapor Annealing ◽  
Solvent Vapor Annealing

scholarly journals Temperature-Controlled Solvent Vapor Annealing of Thin Block Copolymer Films

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1312 ◽  
Author(s):  
Xiao Cheng ◽  
Alexander Böker ◽  
Larisa Tsarkova
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Thermal Annealing ◽  
Saturated Vapor ◽  
Polymer Chains ◽  
Special Focus ◽  
Solvent Vapor ◽  
Copolymer Films ◽  
Vapor Annealing ◽  
Solvent Vapor Annealing

Solvent vapor annealing is as an effective and versatile alternative to thermal annealing to equilibrate and control the assembly of polymer chains in thin films. Here, we present scientific and practical aspects of the solvent vapor annealing method, including the discussion of such factors as non-equilibrium conformational states and chain dynamics in thin films in the presence of solvent. Homopolymer and block copolymer films have been used in model studies to evaluate the robustness and the reproducibility of the solvent vapor processing, as well as to assess polymer-solvent interactions under confinement. Advantages of utilizing a well-controlled solvent vapor environment, including practically interesting regimes of weakly saturated vapor leading to poorly swollen states, are discussed. Special focus is given to dual temperature control over the set-up instrumentation and to the potential of solvo-thermal annealing. The evaluated insights into annealing dynamics derived from the studies on block copolymer films can be applied to improve the processing of thin films of crystalline and conjugated polymers as well as polymer composite in confined geometries.

Synthesis and characterization of nanostructured PS-b-P4VP/Fe2O3 thin films with magnetic properties prepared by solvent vapor annealing

RSC Advances ◽  
2015 ◽  
Vol 5 (116) ◽  
pp. 95840-95846 ◽  
Author(s):  
I. Barandiaran ◽  
G. Kortaberria
Keyword(s):  
Thin Films ◽  
Magnetic Properties ◽  
Block Copolymer ◽  
Synthesis And Characterization ◽  
Maghemite Nanoparticles ◽  
Solvent Vapor ◽  
Vapor Annealing ◽  
Inorganic Nanocomposites ◽  
Solvent Vapor Annealing

In this work hybrid organic/inorganic nanocomposites with magnetic properties, based on a PS-b-P4VP block copolymer and Fe2O3 maghemite nanoparticles have been prepared.

An In Situ Grazing Incidence X-Ray Scattering Study of Block Copolymer Thin Films During Solvent Vapor Annealing

2013 ◽  
Vol 26 (2) ◽  
pp. 273-281 ◽  
Author(s):  
Xiaodan Gu ◽  
Ilja Gunkel ◽  
Alexander Hexemer ◽  
Weiyin Gu ◽  
Thomas P. Russell
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Grazing Incidence ◽  
Solvent Vapor ◽  
X Ray ◽  
X Ray Scattering ◽  
Vapor Annealing ◽  
Scattering Study ◽  
Solvent Vapor Annealing

scholarly journals Restructuring in block copolymer thin films: In situ GISAXS investigations during solvent vapor annealing

2017 ◽  
Vol 66 ◽  
pp. 80-115 ◽  
Author(s):  
Dorthe Posselt ◽  
Jianqi Zhang ◽  
Detlef-M. Smilgies ◽  
Anatoly V. Berezkin ◽  
Igor I. Potemkin ◽  
...  
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Solvent Vapor ◽  
Vapor Annealing ◽  
Solvent Vapor Annealing

scholarly journals Simulation methods for solvent vapor annealing of block copolymer thin films

Soft Matter ◽  
2015 ◽  
Vol 11 (19) ◽  
pp. 3794-3805 ◽  
Author(s):  
A. F. Hannon ◽  
W. Bai ◽  
A. Alexander-Katz ◽  
C. A. Ross
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Simulation Methods ◽  
Solvent Vapor ◽  
Vapor Annealing ◽  
Solvent Vapor Annealing

Solvent vapor annealing of block copolymer thin films: removal of processing history

2014 ◽  
Vol 292 (8) ◽  
pp. 1795-1802 ◽  
Author(s):  
Xiaodan Gu ◽  
Ilja Gunkel ◽  
Alexander Hexemer ◽  
Thomas P. Russell
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Solvent Vapor ◽  
Vapor Annealing ◽  
Processing History ◽  
Solvent Vapor Annealing
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