Synthesis and Isomeric Characterization of Well-Defined 8-Shaped Polystyrene Using Anionic Polymerization, Silicon Chloride Linking Chemistry, and Metathesis Ring Closure

2017 ◽  
Vol 50 (15) ◽  
pp. 5779-5789 ◽  
Author(s):  
Qiming He ◽  
Jialin Mao ◽  
Chrys Wesdemiotis ◽  
Roderic P. Quirk ◽  
Mark D. Foster
2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Dandan Sun ◽  
Jiang Li ◽  
Qinghua Pan ◽  
Chaowei Hao ◽  
Guoqiao Lai

PA6/LiCl composites were synthesized by in situ anionic polymerization based on the interaction between the inorganic salts and PA6. Sodium hydroxide as initiator and N-acetylcaprolactam as activator were used in the preparation of PA6/LiCl composites with variety of LiCl content. X-ray diffraction (XRD) and differential scanning calorimeter (DSC) testing results showed that both of degree of crystallinity and melting temperature of the composites were decreased under the influence of LiCl. And theγcrystal phase proportion increased with increasing the LiCl content to appropriate amount.


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