Non-Equilibrium Phase Behavior of Immiscible Polymer-Grafted Nanoparticle Blends

2019 ◽  
Vol 52 (15) ◽  
pp. 5811-5818
Author(s):  
Deul Kim ◽  
Moon Ryul Sihn ◽  
Min-Gi Jeon ◽  
Guangcui Yuan ◽  
Sushil K. Satija ◽  
...  
Keyword(s):  
Phase Behavior ◽  
Equilibrium Phase ◽  
Immiscible Polymer ◽  
Grafted Nanoparticle ◽  
Non Equilibrium

scholarly journals Thermodynamic Analysis of Relaxation Model for Non-Equilibrium Phase Behavior of Hydrocarbon Mixtures

2021 ◽  
Vol 2090 (1) ◽  
pp. 012138
Author(s):  
I M Indrupskiy ◽  
P A Chageeva
Keyword(s):  
Relaxation Time ◽  
Phase Behavior ◽  
Relaxation Process ◽  
Thermodynamic Analysis ◽  
Balance Equation ◽  
Equilibrium Phase ◽  
Characteristic Relaxation Time ◽  
Relaxation Model ◽  
Entropy Balance ◽  
Non Equilibrium

Abstract Mathematical models of phase behavior are widely used to describe multiphase oil and gas-condensate systems during hydrocarbon recovery from natural petroleum reservoirs. Previously a non-equilibrium phase behavior model was proposed as an extension over generally adopted equilibrium models. It is based on relaxation of component chemical potentials difference between phases and provides accurate calculations in some typical situations when non-instantaneous changing of phase fractions and compositions in response to variations of pressure or total composition is to be considered. In this paper we present a thermodynamic analysis of the relaxation model. General equations of non-equilibrium thermodynamics for multiphase flows in porous media are considered, and reduced entropy balance equation for the relaxation process is obtained. Isotropic relaxation process is simulated for a real multicomponent hydrocarbon system with different values of characteristic relaxation time using the non-equilibrium model implemented in the PVT Designer module of the RFD tNavigator simulation software. The results are processed with a special algorithm implemented in Matlab to calculate graphs of the total entropy time derivative and its constituents in the entropy balance equation. It is shown that the constituents have different signs, and the greatest influence on the entropy is associated with the interphase flow of the major component of the mixture and the change of the total system volume in the isotropic process. The characteristic relaxation time affects the rate at which the entropy is approaching its maximum value.

Assessment of Non-Equilibrium Phase Behavior Model Parameters for Oil and Gas-Condensate Systems by Laboratory and Field Studies (Russian)

2020 ◽  
Author(s):  
Ilya Mikhailovich Indrupskiy ◽  
Mikhail Yurievich Danko ◽  
Timur Nikolaevich Tsagan-Mandzhiev ◽  
Ayguzel Ilshatovna Aglyamova
Keyword(s):  
Phase Behavior ◽  
Oil And Gas ◽  
Equilibrium Phase ◽  
Field Studies ◽  
Gas Condensate ◽  
Model Parameters ◽  
Behavior Model ◽  
Non Equilibrium

A novel visualization approach for foamy oil non-equilibrium phase behavior study of solvent/live heavy oil systems

Fuel ◽  
2020 ◽  
Vol 272 ◽  
pp. 117648 ◽  
Author(s):  
Hongyang Wang ◽  
Farshid Torabi ◽  
Fanhua Zeng ◽  
Huiwen Xiao
Keyword(s):  
Phase Behavior ◽  
Heavy Oil ◽  
Equilibrium Phase ◽  
Foamy Oil ◽  
Behavior Study ◽  
Non Equilibrium

Non-Equilibrium Phase Behavior of Confined Molecular Films at Low Shear Rates

2017 ◽  
Vol 254 (12) ◽  
pp. 1600862 ◽  
Author(s):  
Szymon Maćkowiak ◽  
David M. Heyes ◽  
Slawomir Pieprzyk ◽  
Daniele Dini ◽  
Arkadiusz C. Brańka
Keyword(s):  
Phase Behavior ◽  
Equilibrium Phase ◽  
Molecular Films ◽  
Shear Rates ◽  
Low Shear ◽  
Non Equilibrium

Numerical Simulation of Non-Equilibrium Phase Behavior of Hydrocarbons for Modeling Oil and Gas Fields with Gas Injection

2019 ◽  
Author(s):  
Faisal Al-Jenaibi ◽  
Kirill Bogachev ◽  
Sergey Milyutin ◽  
Sergey Zemtsov ◽  
Evgenii Gusarov ◽  
...  
Keyword(s):  
Numerical Simulation ◽  
Phase Behavior ◽  
Oil And Gas ◽  
Gas Injection ◽  
Equilibrium Phase ◽  
Oil And Gas Fields ◽  
Gas Fields ◽  
Non Equilibrium

Kinetic study of CO2 hydrates crystallization: Characterization using FTIR/ATR spectroscopy and contribution modeling of equilibrium/non-equilibrium phase-behavior

2018 ◽  
Vol 192 ◽  
pp. 371-379 ◽  
Author(s):  
Amokrane Boufares ◽  
Elise Provost ◽  
Didier Dalmazzone ◽  
Véronique Osswald ◽  
Pascal Clain ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Phase Behavior ◽  
Equilibrium Phase ◽  
Atr Spectroscopy ◽  
Non Equilibrium

scholarly journals Non-equilibrium phase behavior of hydrocarbons in compositional simulations and upscaling

2017 ◽  
Vol 21 (5-6) ◽  
pp. 1173-1188 ◽  
Author(s):  
Ilya M. Indrupskiy ◽  
Olga A. Lobanova ◽  
Vadim R. Zubov
Keyword(s):  
Phase Behavior ◽  
Equilibrium Phase ◽  
Non Equilibrium
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