Synthesis and Deblocking Investigations of Phenol Blocked Aliphatic Isocyanates and Their Application in the Development of Epoxy-Polyurethane Films

Phenol blocked hexamethylenediisocyanate adducts and polyisocyanates were synthesized and their structure was validated by FTIR, 1H & 13C NMR spectroscopy, TGA, DSC and CO2 evolution techniques were used to evaluate the deblocking temperature of blocked isocyanates. Gel time studies of blocked isocyanates with terathane polyol and solubility study of blocked isocyanates with different polyols were conducted to demonstrate the structure-property correlation. Epoxy-polyurethane films were produced utilizing the blocked isocyanates reported in this work with epoxy resin and their structure was verified by ATR Spectroscopy. TGA, DSC, shore A hardness, tensile strength and flexural strength analysis were used to investigate the thermal and mechanical characteristics of these films. The findings of deblocking temperature and gel time revealed that unsubstituted phenol blocked isocyanates and polyisocyanates deblock at lower temperatures and cure for a shorter time period than substituted phenol blocked isocyanates. Thermal and mechanical characteristics of epoxy-polyurethane films based on blocked polyisocyanates are satisfactory.

Innovative Substrate-Integrated Hollow Waveguide Coupled Attenuated Total Reflection Sensors for Quantum Cascade Laser Based Infrared Spectroscopy in Harsh Environments

An innovative mid-infrared spectroscopic sensor system based on quantum cascade lasers has been developed. The system combines the versatility of substrate-integrated hollow waveguides (IHWGs) with the robustness of attenuated total reflection (ATR) crystals employed as internal reflection waveguides for evanescent field sensing. IHWGs are highly reflective metal structures that propagate infrared (IR) radiation and were used as light pipes for coupling radiation into the ATR waveguide. The combined IHWG-ATR device has been designed such that the utmost stability and robustness of the optical alignment were ensured. This novel assembly enables evanescent field absorption measurements at yet unprecedently harsh conditions, that is, high pressure and temperature. Combining these advantages, this innovative sensor assembly is perfectly suited for taking ATR spectroscopy into the field where the robustness of the assembly and optical alignment is essential.

Simultaneous Infrared Spectroscopy, Raman Spectroscopy and Luminescence Sensing: A Multi-Spectroscopic Analyti-cal Platform

Scientific questions in fields such as catalysis, monitoring of biological processes or environmental chemistry demand for analytical technologies combining orthogonal spectroscopies. Combined spectroscopic concepts facilitate in-situ on-line monitoring of dynamic processes providing for a better understanding of the involved reaction pathways. In the present study, a low-liquid-volume multi-spectroscopic platform was developed based on infrared attenuated total reflection (IR-ATR) spectroscopy combined with Raman spectroscopy and lumines-cence sensing. For demonstrating the measurement capabilities, exemplary analyte systems including water / heavy water and aqueous solutions of ammonium sulfate were analyzed as proof-of-principle studies. It was successfully demonstrated that three optical techniques may be integrated into a single analytical platform with-out interference providing synchronized and complementary datasets by probing the same minute sample vol-ume. In addition, the developed assembly provides a gas-tight lid sealing the headspace above the probed liq-uid for monitoring the concentration of molecular oxygen also in the gas phase via luminescence quenching. Hence, the entire assembly may be operated at inert conditions, as required for example during the analysis of photocatalytic processes.

The Function of Organic Additives in Enhancing the Q-values for Peat Pellet Biofuel

In Malaysia, peat make up for around 7.5 % of the entire land area. The positive effect of the vast wet organic compounds accumulates over a long time has stored high content of soil’s carbon which are highly useful as fuel and biomass energy generation. Thus, this study gives an outline of peat pellet as potential biofuel energy. The peat pellets were soaked into several kinds of flammable additives such as petrol, kerosene and diesel. The percentages of 69.41 % of carbon, 28.73% of oxygen and 0.97% of silicon were obtained using Energy Dispersive X-ray (EDX). The Fourier-Transformed Infrared (FTIR)- Attenuated Total Reflectance (ATR) Spectroscopy was used to identify the sample. From the spectra, it reveals that most of the additives contribute mainly functional groups with hydroxyl, alcohol and phenol groups were found leading to higher boiling and melting points. The heat combustion properties of peat pellets were evaluated using a calorimeter technique by boiling off 50 ml and 100 ml of water. The pellet with diesel has the highest Q-values and combustion rate due to larger number of carbons in rigid molecular structure. The high amount of unique chemical compound found naturally in diesel known as cetane, ignites effortlessly when heated gives diesel additional advantages in shorter ignition delays as well as longer duration of combustion.

Study on Scientific Analysis about Red Pigment And Binder - The Korean Ancient Red Pottery -

From the collection of the National Kimhae Museum, qualitative analyses using microscopic observation, SEM-EDS, Raman spectroscopy, FT-IR-ATR spectroscopy, and GC-MS were conducted on three burnished red potteries—Jeoksaekmaoyeonwa burnished red pottery (Neolithic age red pottery), Dandomaoyeonwan burnished red pottery(Bronze age red pottery) and Jeoksaekmaoyeongajimun burnished red pottery(Bronze age red pottery)—to investigate the components of the red pigments and the binder. After the layers of the primer were separated from the red surface, crystals of red pigment particles and minerals were found on the red surface. Through SEM-EDS, Raman estimates that the red pigment is Among soil pigments with iron oxide(Fe2O3) as the main color development source, Red Ocher(Fe2O3). A band characteristic of the Urushiol polymer was detected in the FTIR-ATRspectra(4000∼600cm-1), GC-MS analysis confirmed the presence of the benzenemethanol-2-prophenyl, 4-heptylphenol, 1-tetracecanol, heptafluorobutyric texidecane, all of which are the ingredients of the directional structure of the lacquer present in the red layer. Therefore, it seemed that the three burnished red pottery: Jeoksaekmaoyeonwan pottery(Neolithic age burnished red pottery), Dandomaoyeonwan pottery(bronze age burnished red pottery) and the Jeoksaekmaoyeongajimun pottery(bronze age burnished red pottery) made by mixing minerals and Red Ocher(Fe2O3), with lacquer.