Multiple Interfacial Modifications in Poly(vinylidene fluoride)/Barium Titanate Nanocomposites via Double-Shell Architecture for Significantly Enhanced Energy Storage Density

2019 ◽  
Vol 2 (8) ◽  
pp. 5945-5953 ◽  
Author(s):  
Lingyu Zhang ◽  
Yao Wang ◽  
Meiyu Xu ◽  
Wentian Wei ◽  
Yuan Deng
Crystals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 633
Author(s):  
Ardian Agus Permana ◽  
Somyot Chirasatitsin ◽  
Chatchai Putson

In current, the energy storage materials based on electrets and ferroelectric polymers are urgently demanded for electric power supply and renewable energy applications. The high energy storage density can be enhanced by conducting or inorganic fillers to ferroelectric polymer matrix. However, agglomeration, phase separation of fillers, interfacial phase regions and crystallinity of matrix remain the main factors for the improvement of energy storage density in those composites. Poly(vinylidene fluoride-hexafluoropropylene) was modified with graphene nanoplatelets for enhanced the dielectric properties and energy storage density, which combines the irradiated by electron beam. Tuning effect of the crystalline regions and polar phases with graphene nanoplatelets and electron irradiation on its surface, structure, electrical and energy storage properties were observed. The film homogeneity was increased by reducing the pores, along with the improvement of surface roughness and hydrophobicity, which related with the dielectric properties and energy storage density. The β-phase fraction and crystallinity improvement significantly affect electrical properties by improving polarization and dielectric constant. As a core, electron beam dramatically reduce the crystals size by two times. Hence, energy storage density of composites was enhanced, while energy loss was reduced under operating conditions. Results on the improvement of energy efficiency were from 68.11 to 74.66% for neat poly(vinylidene fluoride-hexafluoropropylene) (P(VDF-HFP)), much higher than previously reported of 58%, and doubled for P(VDF-HFP)/GNPs composites which will be discussed and evaluated for the practical energy storage materials.


2018 ◽  
Vol 6 (17) ◽  
pp. 7573-7584 ◽  
Author(s):  
Lingyu Wu ◽  
Kai Wu ◽  
Dingyao Liu ◽  
Rui Huang ◽  
Jinlei Huo ◽  
...  

PVDF/OH-BNNS nanocomposites show improved dielectric, thermal and mechanical properties through cooperation with surface hydroxylated BNNSs.


2017 ◽  
Vol 5 (32) ◽  
pp. 16757-16766 ◽  
Author(s):  
Qingguo Chi ◽  
Tao Ma ◽  
Yue Zhang ◽  
Yang Cui ◽  
Changhai Zhang ◽  
...  

The significantly enhanced energy storage characteristics of 0.5Ba(Zr0.2Ti0.8)O3–0.5(Ba0.7Ca0.3)TiO3 nanofibers/PVDF dielectric composites with low doping ratios and large aspect ratio nanofillers.


RSC Advances ◽  
2015 ◽  
Vol 5 (84) ◽  
pp. 68515-68522 ◽  
Author(s):  
Hang Luo ◽  
Chao Chen ◽  
Kechao Zhou ◽  
Xuefan Zhou ◽  
Zhong Wu ◽  
...  

The dielectric properties and energy storage density of poly(vinylidene fluoride-co-hexafluoropropylene) were enhanced by the surface-functionalized relaxor ferroelectric ceramic Pb(Mg1/3Nb2/3)O3–PbTiO3.


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