Flexible and Transparent Oligothiophene-o-Carborane-Containing Hybrid Films for Nonlinear Optical Limiting Based on Efficient Two-Photon Absorption

Author(s):  
Wan Feng ◽  
Ke Liu ◽  
Jianyang Zang ◽  
Gang Wang ◽  
Rong Miao ◽  
...  
2007 ◽  
Vol 16 (02) ◽  
pp. 247-254 ◽  
Author(s):  
ASLI KARAKAS ◽  
AYHAN ELMALI

To provide an insight into the optical limiting (OL) behavior of a series of 3 metallated 1,4,8,11,15,18,22,25-octaalkylphthalocyanines; the third-order nonlinear optical (NLO) properties, one-photon absorption (OPA) and two-photon absorption (TPA) characterizations have been theoretically investigated by means of AM1, ZINDO and configuration interaction (CI) methods. The highest values for the TPA cross-section (δ(ω)) are exhibited by derivatives metallated with indium and lead. It is also seen that the nickel-metallated compound might be a passive optical limiter of the series, indicating the weakest δ(ω) and second hyperpolarizability (γ). Our calculated results are in good agreement with the previous experimental observations on the examined molecules.


1997 ◽  
Vol 479 ◽  
Author(s):  
B. A. Reinhardt ◽  
L. L. Brott ◽  
S. J. Clarson ◽  
R. Kannan ◽  
A. G. Dillard

AbstractThe molecular structure / nonlinear optical (NLO) property relationship is explored with seven recently synthesized chromophores. Two symmetrical compounds were made using electron withdrawing groups separated by an electron rich core while five asymmetrical molecules were developed using electron donating and withdrawing groups coupled by a it electron bridging group. Pendant chains were added to some of the chromophores to improve processibility. Their syntheses are described and their optical limiting properties discussed.


2008 ◽  
Vol 18 (18) ◽  
pp. 2770-2779 ◽  
Author(s):  
Qingdong Zheng ◽  
Sandesh K. Gupta ◽  
Guang S. He ◽  
Loon-Seng Tan ◽  
Paras N. Prasad

1997 ◽  
Vol 22 (24) ◽  
pp. 1843 ◽  
Author(s):  
J. E. Ehrlich ◽  
X. L. Wu ◽  
I.-Y. S. Lee ◽  
Z.-Y. Hu ◽  
H. Röckel ◽  
...  

1995 ◽  
Vol 117 (1-2) ◽  
pp. 133-136 ◽  
Author(s):  
Guang S. He ◽  
Raz Gvishi ◽  
Paras N. Prasad ◽  
Bruce A. Reinhardt

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