scholarly journals Nanostructured Copper-Based Electrodes Electrochemically Synthesized on a Carbonaceous Gas Diffusion Membrane with Catalytic Activity for the Electroreduction of CO2

Author(s):  
Martina Serafini ◽  
Federica Mariani ◽  
Andrea Fasolini ◽  
Erika Scavetta ◽  
Francesco Basile ◽  
...  

2006 ◽  
Vol 126 (1) ◽  
pp. 19-23
Author(s):  
Yoshitaka Mizutani ◽  
Hiroyuki Matsuda ◽  
Toru Ishiji ◽  
Nagakazu Furuya




Author(s):  
Nicholas Schwartz ◽  
Jason Harrington ◽  
Kirk J Ziegler ◽  
Philip Cox

Abstract The direct electrochemically driven separation of CO2 from a humidified N2, O2, and CO2 gas mixture was conducted using an asymmetric membrane electrode assembly (MEA). The MEA was fabricated using a screen-printed ionomer bound Pt cathode, an anion exchange membrane (AEM), and ionomer bound IrO2 anode. Electrocatalyst materials were physically and chemically characterized prior to inclusion within the electrode. Electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV) measurements using a rotating disk electrode (RDE) were used to quantify the catalytic activity and determine the effects of the catalyst-to-ionomer ratio. Catalysts were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET) surface analysis, and (dynamic light scattering) DLS to evaluate catalyst structure, active surface area, and determine the particle size and bulk particle size distribution (PSD). The electrocatalyst layer of the electrodes were fabricated by screen printing a uniformly dispersed mixture of catalyst, dissolved anionic ionomer, and a solvent system onto an electrode supporting gas diffusion layer (GDL). Pt IrO2 MEAs were fabricated and current-voltage relationships were determined using constant-current measurements over a range of applied current densities and flow rates. Baseline reaction kinetics for CO2 separation were established with a standard set of Pt-IrO2 MEAs.



2004 ◽  
Vol 124 (11) ◽  
pp. 402-406 ◽  
Author(s):  
Yoshitaka Mizutani ◽  
Hiroyuki Matsuda ◽  
Toru Ishiji ◽  
Nagakazu Furuya


Talanta ◽  
2004 ◽  
Vol 64 (2) ◽  
pp. 278-282 ◽  
Author(s):  
Wolfgang Frenzel ◽  
Jürgen Schulz-Brüssel ◽  
Betty Zinvirt


1975 ◽  
Vol 6 (2) ◽  
pp. 49-49
Author(s):  
Melvin R. Click


2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Hao Zhou ◽  
Yilin Song ◽  
Zheng Yang

A coupled chip aiming at economical and highly selective ammonium detection was fabricated. It consisted of a reaction chip, a gas-diffusion chip, and a detection chip. Zinc tetraphenylporphyrin dyed on the cation-exchange resin microbeads was used as the indicating material to avoid excess consumption for its reversibility. PDMS was selected as the material of the gas-diffusion membrane. A portable spectrometer was applied for spectrum analysis. By analysis of spectrum change, the high selectivity was confirmed because no component had interference on detection effect. Good performance was shown for all the tested concentrations (0.2–50 mg·L−1). The stability and reversibility were also judged by the spectrum data obtained from the indicating process and the recovering process. Finally, real samples containing ammonium were tested and the results were compared to those came from a standard method to confirm the accuracy of our method.



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