Multifunctional Anthracene-Based Ni-MOF with Encapsulated Fullerenes: Polarized Fluorescence Emission and Selective Separation of C70 from C60

Author(s):  
Serhii I. Vasylevskyi ◽  
Guillaume Raffy ◽  
Stefan Salentinig ◽  
André Del Guerzo ◽  
Katharina M. Fromm ◽  
...  

2020 ◽  
Author(s):  
Tyson C Davis ◽  
Jeremiah O. Bechtold ◽  
Anni Shi ◽  
Erin N. Lang ◽  
Anamika Singh ◽  
...  

Here, we show that striped monolayers of diyne amphiphiles, assembled on graphite and photopolymerized, can be covalently transferred to polydimethylsiloxane (PDMS), an elastomer common in applications including microfluidics, soft robotics, wearable electronics, and cell culture. This process creates precision polymer films < 1 nm thick, with 1-nm-wide functional patterns, that control interfacial wetting, reactivity, and adsorption of flexible, ultranarrow inorganic nanowires. The polydiacetylenes exhibit polarized fluorescence emission, revealing polymer location, orientation, and environment, and resist engulfment, a common problem in PDMS functionalization. These findings illustrate a route for controlling surface chemistry well below the length scale of heterogeneity in an amorphous material.





2020 ◽  
Author(s):  
Tyson C Davis ◽  
Jeremiah O. Bechtold ◽  
Anni Shi ◽  
Erin N. Lang ◽  
Anamika Singh ◽  
...  

Here, we show that striped monolayers of diyne amphiphiles, assembled on graphite and photopolymerized, can be covalently transferred to polydimethylsiloxane (PDMS), an elastomer common in applications including microfluidics, soft robotics, wearable electronics, and cell culture. This process creates precision polymer films < 1 nm thick, with 1-nm-wide functional patterns, that control interfacial wetting, reactivity, and adsorption of flexible, ultranarrow inorganic nanowires. The polydiacetylenes exhibit polarized fluorescence emission, revealing polymer location, orientation, and environment, and resist engulfment, a common problem in PDMS functionalization. These findings illustrate a route for controlling surface chemistry well below the length scale of heterogeneity in an amorphous material.





2017 ◽  
Vol 5 (39) ◽  
pp. 10320-10331 ◽  
Author(s):  
L. Favaretto ◽  
M. Zambianchi ◽  
S. G. Lopez ◽  
A. Mazzanti ◽  
C. Zanardi ◽  
...  

A new monoreduced thienopyrrole-dione ended oligothiophene showing polarized fluorescence emitting microstructures is reported.



2007 ◽  
Vol 2 (2) ◽  
pp. 257-264
Author(s):  
Satoko Nishiyama ◽  
Masahiro Tajima ◽  
Yasuhiko Yoshida


2017 ◽  
Author(s):  
Pedro M. R. Paulo ◽  
David Botequim ◽  
Agnieszka Jóskowiak ◽  
Sofia Martins ◽  
Duarte M. F. Prazeres ◽  
...  

<div> <div> <div> <p>We have employed DNA-directed assembly to prepare dimers of gold nanoparticles and used their longitudinally coupled plasmon mode to enhance the fluorescence emission of an organic red-emitting dye, Atto-655. The plasmon- enhanced fluorescence of this dye using dimers of 80 nm particles was measured at single molecule detection level. The top enhancement factors were above 1000-fold in 71% of the dimers within a total of 32 dimers measured, and, in some cases, they reached almost 4000-fold, in good agreement with model simulations. Additionally, fluorescence lifetime correlation analysis enabled the separation of enhanced from non-enhanced emission simultaneously collected in our confocal detection volume. This approach allowed us to recover a short relaxation component exclusive to enhanced emission that is attributed to the interaction of the dye with DNA in the interparticle gaps. </p> </div> </div> </div>







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