High Capacity Oil Denitrogenation over Azine- and Tetrazine-Decorated Metal–Organic Frameworks: Critical Roles of Hydrogen Bonding

2019 ◽  
Vol 11 (24) ◽  
pp. 21711-21719 ◽  
Author(s):  
Sayed Ali Akbar Razavi ◽  
Ali Morsali
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Frameworks ◽  
High Capacity ◽  
Metal Organic

Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3Architecture

2009 ◽  
Vol 131 (38) ◽  
pp. 13625-13627 ◽  
Author(s):  
Prashant Jain ◽  
Vasanth Ramachandran ◽  
Ronald J. Clark ◽  
Hai Dong Zhou ◽  
Brian H. Toby ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Frameworks ◽  
Metal Organic

Diamondoid-structured polymolybdate-based metal–organic frameworks as high-capacity anodes for lithium-ion batteries

2017 ◽  
Vol 53 (37) ◽  
pp. 5204-5207 ◽  
Author(s):  
Yuan-Yuan Wang ◽  
Mi Zhang ◽  
Shun-Li Li ◽  
Shu-Ran Zhang ◽  
Wei Xie ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
High Capacity ◽  
Lithium Ion ◽  
Metal Organic

Two novel isostructural polyoxometalate (POM)-based coordination polymers were obtained. The results reveal that NENU-507 could be directly utilized as an anode material for lithium-ion batteries with outstanding performance.

Anion Coordination in Metal−Organic Frameworks Functionalized with Urea Hydrogen-Bonding Groups

2006 ◽  
Vol 6 (2) ◽  
pp. 555-563 ◽  
Author(s):  
Radu Custelcean ◽  
Bruce A. Moyer ◽  
Vyacheslav S. Bryantsev ◽  
Benjamin P. Hay
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Frameworks ◽  
Anion Coordination ◽  
Metal Organic

scholarly journals Two metal–organic frameworks based on Sr2+ and 1,2,4,5-tetrakis(4-carboxyphenyl)benzene linkers

2021 ◽  
Vol 77 (12) ◽  
Author(s):  
Muhammad Usman ◽  
Lydia Ogebule ◽  
Raúl Castañeda ◽  
Evgenii Oskolkov ◽  
Tatiana Timofeeva
Keyword(s):  
Hydrogen Bonding ◽  
Single Crystal ◽  
Crystal Structures ◽  
Structural Control ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Solvent Systems ◽  
Semiconductor Properties

Two structurally different metal–organic frameworks based on Sr2+ ions and 1,2,4,5-tetrakis(4-carboxyphenyl)benzene linkers have been synthesized solvothermally in different solvent systems and studied with single-crystal X-ray diffraction technique. These are poly[[μ12-4,4′,4′′,4′′′-(benzene-1,2,4,5-tetrayl)tetrabenzoato](dimethylformamide)distrontium(II)], [Sr2(C34H18O8)(C3H7NO)2] n , and poly[tetraaqua{μ2-4,4′-[4,5-bis(4-carboxyphenyl)benzene-1,2-diyl]dibenzoato}tristrontium(II)], [Sr3(C34H20O8)2(H2O)4]. The differences are noted between the crystal structures and coordination modes of these two MOFs, which are responsible for their semiconductor properties, where structural control over the bandgap is desirable. Hydrogen bonding is present in only one of the compounds, suggesting it has a slightly higher structural stability.

scholarly journals Removal of Acid Orange 7 from Aqueous Solution by Metal-Organic Frameworks

Crystals ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 17 ◽  
Author(s):  
Sungwon Yoon ◽  
James Calvo ◽  
Monica So
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Bonding ◽  
Adsorption Capacity ◽  
Metal Clusters ◽  
Metal Organic Frameworks ◽  
Acid Orange 7 ◽  
Acid Orange ◽  
Zeta Potentials ◽  
Metal Organic ◽  
Capacity Data

We investigated the removal of a harmful anionic dye, acid orange 7 (AO7), from aqueous solution using metal-organic frameworks (MOFs). We prepared four different MOFs (ZIF-8, ZIF-67, UiO-66, UiO-66-NH2) by solvothermal reactions and then tested their adsorption of AO7. Infrared spectra and adsorption capacity data confirmed the removal of AO7 from aqueous solution. The factors we investigated affecting adsorption capacity include variation of the organic linkers and metal clusters of the MOFs. Our results suggest that the hydrogen bonding, π–π interactions, and zeta potentials facilitate the removal of AO7 from water. Of the four MOFs examined, ZIF-67 exhibited the highest adsorption capacity of AO7 and can be regenerated easily.

Sign in / Sign up

Export Citation Format

Share Document