Boron-Doped Nanocrystalline Diamond–Carbon Nanospike Hybrid Electron Emission Source

2019 ◽  
Vol 11 (51) ◽  
pp. 48612-48623
Author(s):  
Kamatchi Jothiramalingam Sankaran ◽  
Mateusz Ficek ◽  
Kalpataru Panda ◽  
Chien-Jui Yeh ◽  
Miroslaw Sawczak ◽  
...  
2010 ◽  
Vol 152-153 ◽  
pp. 413-417
Author(s):  
You Sheng Zou ◽  
Zheng Xue Li ◽  
Hao Yang

The boron-doped nanocrystalline diamond films were prepared on Si(100) substrates by microwave plasma chemical vapor deposition in gas mixture of CH4/H2/trimethylboron (TMB) with B/C ratio in the range of 0-1900ppm. The dependencies of surface morphology, microstructure, phase composition and field electron emission properties on the B/C ratio were systematically investigated by scanning electron microscope, X-ray diffractometer, visible and UV Raman spectroscopy. The results show that the diamond grains gather together forming ball-like clusters with inhomogeneous size, the doped boron atoms can promote the growth of plane (111) surface and terminate the diamond growth sites, resulting in the reduction of growth rate with the increase of B/C ratio in the gas mixture. The two peaks located at approximately 500 and 1220cm-1 resulted from Fano interference were observed in the visible Raman spectra for the heavily boron-doped nanocrystalline diamond film, and the sp2/sp3 ratio of carbon bonds increased with B/C ratio increasing in gas mixture. The field electron emission performances of the boron-doped nanocrystalline diamond films were obviously dependent on B/C ratio in the gas mixture, and boron doping can improve their field electron emission properties remarkably. The low turn-on electric field of 7.6V/μm was achieved for the boron-doped nanocrystalline diamond film deposited at B/C ratio of 1900ppm.


2014 ◽  
Vol 87 ◽  
pp. 903-906 ◽  
Author(s):  
Dimitre Iankov ◽  
Verena Zuerbig ◽  
Wilfried Pletschen ◽  
Christian Giese ◽  
Robert Iannucci ◽  
...  

2010 ◽  
Vol 207 (9) ◽  
pp. 2110-2113 ◽  
Author(s):  
Tim Clukers ◽  
Bart Van Grinsven ◽  
Thijs Vandenryt ◽  
Stoffel D. Janssens ◽  
Patrick Wagner ◽  
...  

2017 ◽  
Vol 214 (11) ◽  
pp. 1700222 ◽  
Author(s):  
Daria Majchrowicz ◽  
Monika Kosowska ◽  
Przemysław Struk ◽  
Małgorzata Jędrzejewska-Szczerska

2010 ◽  
Vol 426-427 ◽  
pp. 30-34
Author(s):  
Bing Kun Xiang ◽  
Dun Wen Zuo ◽  
Xiang Feng Li ◽  
Feng Xu ◽  
M. Wang

Boron-doped micro-nanocrystalline diamond coating may be successfully prepared on Mo substrate with DC arc plasmas jet deposition device. Along with the increase of doped-boron concentration in the film, two-point resistance measurement indicates that film resistance presents exponential decrease; Raman spectrum test shows that, the characteristic peak value of diamond 1332cm-1 in the spectrum moves toward low frequency, the semi-height width of diamond peak, peak D and peak G, etc. in the spectrum is expanded, and the component of non-diamond bonds such as sp2, etc. in the film is increased; SEM and AFM observation shows that, increasing the doped-boron concentration could further subdivide the crystal grains in the film, and is beneficial for the growth of nano- or ultra-nano-crystalline diamond film; film annealing test shows that, micro-nanocrystalline diamond film with higher doped-boron concentration has better thermal stability than the micro-nanocrystalline diamond film without doped boron.


2013 ◽  
Vol 28 (5) ◽  
pp. 688-692
Author(s):  
丁明清 DING Ming-qing ◽  
李莉莉 LI Li-li ◽  
冯进军 FENG Jin-jun

Vacuum ◽  
2019 ◽  
Vol 168 ◽  
pp. 108813 ◽  
Author(s):  
T.H. Stuchliková ◽  
Z. Remes ◽  
V. Mortet ◽  
A. Taylor ◽  
P. Ashcheulov ◽  
...  

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 653 ◽  
Author(s):  
Kamatchi Sankaran ◽  
Kalpataru Panda ◽  
Ping-Yen Hsieh ◽  
Paulius Pobedinskas ◽  
Jeong Park ◽  
...  

Low temperature (350 °C) grown conductive nanocrystalline diamond (NCD) films were realized by lithium diffusion from Cr-coated lithium niobate substrates (Cr/LNO). The NCD/Cr/LNO films showed a low resistivity of 0.01 Ω·cm and excellent field electron emission characteristics, viz. a low turn-on field of 2.3 V/µm, a high-current density of 11.0 mA/cm2 (at 4.9 V/m), a large field enhancement factor of 1670, and a life-time stability of 445 min (at 3.0 mA/cm2). The low temperature deposition process combined with the excellent electrical characteristics offers a new prospective for applications based on temperature sensitive materials.


2002 ◽  
Vol 737 ◽  
Author(s):  
Wensha Yang ◽  
Orlando Auciello ◽  
James E. Butler ◽  
Wei Cai ◽  
John A. Carlisle ◽  
...  

ABSTRACTNanocrystalline diamond thin films of sub-micron thickness have been covalently modified with DNA oligonucleotides. Quantitative studies of hybridization of surface-bound oligonucleotides with fluorescently tagged complementary and non-complementary oligonucleotides were performed. The results show no detectable nonspecific adsorption, with extremely good selectivity between matched and mismatched sequences. Impedance spectroscopy measurements were made of DNA-modified boron-doped nanocrystalline diamond films. The results show that exposure to non-complementary sequences induce only small changes in impedance, while complementary DNA sequences produce a pronounced decrease in impedance. The combination of high stability, selectivity, and the ability to directly detect DNA hybridization via electrical means suggest that diamond may be an ideal substrate for continuously-monitoring biological sensors.


Sign in / Sign up

Export Citation Format

Share Document