Why do molecules interact? The origin of electron donor-acceptor complexes, hydrogen bonding and proton affinity

1977 ◽  
Vol 10 (8) ◽  
pp. 294-300 ◽  
Author(s):  
Keiji Morokuma

2019 ◽  
Vol 131 (48) ◽  
Author(s):  
Cheng‐Hao Liu ◽  
Muhammad Rizwan Niazi ◽  
Dmitrii F. Perepichka


2007 ◽  
Vol 129 (51) ◽  
pp. 16057-16071 ◽  
Author(s):  
Florian Wessendorf ◽  
Jan-Frederik Gnichwitz ◽  
Ginka H. Sarova ◽  
Kristine Hager ◽  
Uwe Hartnagel ◽  
...  


2019 ◽  
Vol 58 (48) ◽  
pp. 17312-17321 ◽  
Author(s):  
Cheng‐Hao Liu ◽  
Muhammad Rizwan Niazi ◽  
Dmitrii F. Perepichka


2019 ◽  
Vol 58 (48) ◽  
Author(s):  
Cheng‐Hao Liu ◽  
Muhammad Rizwan Niazi ◽  
Dmitrii F. Perepichka


2019 ◽  
Vol 131 (48) ◽  
pp. 17473-17482 ◽  
Author(s):  
Cheng‐Hao Liu ◽  
Muhammad Rizwan Niazi ◽  
Dmitrii F. Perepichka


2020 ◽  
Author(s):  
José Tiago Menezes Correia ◽  
Gustavo Piva da Silva ◽  
Camila Menezes Kisukuri ◽  
Elias André ◽  
Bruno Pires ◽  
...  

A metal- and catalyst-free photoinduced radical cascade hydroalkylation of 1,7-enynes has been disclosed. The process is triggered by a SET event involving a photoexcited electron-donor-aceptor complex between NHPI ester and Hantzsch ester, which decomposes to afford a tertiary radical that is readily trapped by the enyne. <a>The method provides an operationally simple, robust and step-economical approach to the construction of diversely functionalized dihydroquinolinones bearing quaternary-centers. A sequential one-pot hydroalkylation-isomerization approach is also allowed giving access to a family of quinolinones. A wide substrate scope and high functional group tolerance was observed in both approaches</a>.





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