Influence of the Annealing Temperature on the Photovoltaic Performance and Film Morphology Applying Novel Thermocleavable Materials

2010 ◽  
Vol 22 (19) ◽  
pp. 5617-5624 ◽  
Author(s):  
Martin Helgesen ◽  
Morten Bjerring ◽  
Niels Chr. Nielsen ◽  
Frederik C. Krebs
2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Dan Chen ◽  
Xiaoping Zou ◽  
Hong Yang ◽  
Ningning Zhang ◽  
Wenbin Jin ◽  
...  

The morphology of compact TiO2 film used as an electron-selective layer and perovskite film used as a light absorption layer in planar perovskite solar cells has a significant influence on the photovoltaic performance of the devices. In this paper, the spin coating speed of the compact TiO2 is investigated in order to get a high-quality film and the compact TiO2 film exhibits pinhole- and crack-free films treated by 2000 rpm for 60 s. Furthermore, the effect of annealing process, including annealing temperature and annealing program, on CH3NH3PbI3-XClX film morphology is studied. At the optimal annealing temperature of 100°C, the CH3NH3PbI3-XClX morphology fabricated by multistep slow annealing method has smaller grain boundaries and holes than that prepared by one-step direct annealing method, which results in the reduction of grain boundary recombination and the increase of Voc. With all optimal procedures, a planar fluorine-doped tin oxide (FTO) substrate/compact TiO2/CH3NH3PbI3-XClX/Spiro-MeOTAD/Au cell is prepared for an active area of 0.1 cm2. It has achieved a power conversion efficiency (PCE) of 14.64%, which is 80.3% higher than the reference cell (8.12% PCE) without optimal perovskite layer. We anticipate that the annealing process with optimal compact TiO2 layer would possibly become a promising method for future industrialization of planar perovskite solar cells.


2012 ◽  
Vol 22 (10) ◽  
pp. 4473-4482 ◽  
Author(s):  
Antti Ojala ◽  
Hannah Bürckstümmer ◽  
Jaehyung Hwang ◽  
Katja Graf ◽  
Bernhard von Vacano ◽  
...  

2014 ◽  
Vol 24 (21) ◽  
pp. 3250-3258 ◽  
Author(s):  
Amalie Dualeh ◽  
Nicolas Tétreault ◽  
Thomas Moehl ◽  
Peng Gao ◽  
Mohammad Khaja Nazeeruddin ◽  
...  

2014 ◽  
Vol 28 ◽  
pp. 151-162 ◽  
Author(s):  
Mohd Zikri Razali ◽  
Abdullah Huda ◽  
Sahbudin Shaari ◽  
Taha Mohd Raihan ◽  
Azimah Omar ◽  
...  

In this research, the CNT/TiO2 nanocomposite solution was prepared using sol-gel method process. Definite amounts of CNT (0.06 g) were sonicated in 30 ml anhydrate 2-propanol. The measured quantities of Titanium (IV) Tetraisopropoxide (TTIP) – 5 ml were introduced into the CNT/2-propanol solution. The CNT/TiO2 paste was doctor-bladed onto the FTO glass and consequently annealed at 250 °C, 350 °C and 450 °C for 30 min. The effect of annealing temperatures on the CNT/TiO2 thin films was discussed. The CNT/TiO2 thin films were characterized for morphological and electrical performance by Field Emission Scanning Electron Microscopy (FESEM), X-ray Diffraction (XRD), Incident Photon to Charge Carrier Efficiency (IPCE) and IV-Curve Efficiency analysis. The XRD patterns show the thin films major peak at (101) with average anatase phase crystallite size. The CNT/TiO2 thin film's morphological structure composed of compressed and porous distributed composition. The crystal structures were changed upon increasing the annealing temperature. The IV measurement shows that the dye-sensitized solar cell (DSSC) at 450 °C produced highest photoelectric conversion efficiency (η) with 3.88 %. IPCE graph shows the solar cell absorb light within the UV spectrum region. It is revealed that annealing temperature has influence toward photovoltaic performance of the assembled DSSC.


2021 ◽  
Vol 14 (04) ◽  
pp. 2344-2351
Author(s):  
Siti Utari Rahayu ◽  
Ming-Way Lee ◽  
Muhammad Noer Nasruddin ◽  
Kerista Sebayang ◽  
Herty Afrina Sianturi

Author(s):  
Jin-Liang Wang ◽  
Gao-Yang Ge ◽  
Wentao Xiong ◽  
Kai-Kai Liu ◽  
Hwasook Ryu ◽  
...  

We synthesize a pair of regioisomer-free selenophene-containing non-fullerene acceptors (NFAs) (TSeIC-M-Cl and TSeIC-P-Cl), which have an identical indacenodithieno[3,2-b]selenophene core and two types of monochlorinated (2,3-dihydro-3-oxo-1H-inden-1-ylidene)propanedinitrile (INCN) end groups with the...


2015 ◽  
Vol 3 (29) ◽  
pp. 7669-7676 ◽  
Author(s):  
Ying Sun ◽  
Chao Zhang ◽  
Qizan Huang ◽  
Bin Dai ◽  
Baoping Lin ◽  
...  

A naphthalene group was incorporated into the polymer side chain to help the active layer spontaneously form good film morphology.


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