Solution-Processed Organic Solar Cells with Power Conversion Efficiencies of 2.5% using Benzothiadiazole/Imide-Based Acceptors

2011 ◽  
Vol 23 (24) ◽  
pp. 5484-5490 ◽  
Author(s):  
Jason T. Bloking ◽  
Xu Han ◽  
Andrew T. Higgs ◽  
John P. Kastrop ◽  
Laxman Pandey ◽  
...  
2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.


Author(s):  
Shreyam Chatterjee ◽  
Seihou JINNAI ◽  
Yutaka Ie

Progressive advancement of remarkably high power conversion efficiencies (PCEs) of organic solar cells (OSCs) largely depends on the development of norfullerene acceptors (NFAs), revealing stupendous ability of OSCs to shift...


Nanoscale ◽  
2021 ◽  
Author(s):  
Congcong Zhao ◽  
Jiuxing Wang ◽  
Xuanyi Zhao ◽  
Zhonglin Du ◽  
Renqiang Yang ◽  
...  

The past decade has seen a tremendous development of organic solar cells (OSCs). To date, the high-performance OSCs have boosted the power conversion efficiencies (PCEs) over 17%, showing bright prospects...


2021 ◽  
Author(s):  
Haifen Liu ◽  
Zixuan Zhu ◽  
Huafeng Li ◽  
Weili Fan ◽  
Kaihua Ning ◽  
...  

Non-fullerene acceptors have received a great deal of attention over the past several years, and numerous modifications on the molecular structures significantly boosted the power conversion efficiencies (PCEs). To be...


2021 ◽  
Author(s):  
Zhaofan Yang ◽  
Shijie Liang ◽  
Baiqiao Liu ◽  
Jing Wang ◽  
Fan Yang ◽  
...  

Single-component organic solar cells (SCOSCs) have been recognized as the promising photovoltaic technology due to the excellent stability, but their power conversion efficiencies (PCEs) are far lagging their bulk-heterojunction counterparts....


2020 ◽  
Vol 10 (17) ◽  
pp. 5743
Author(s):  
Shabaz Alam ◽  
M. Shaheer Akhtar ◽  
Abdullah ◽  
Eun-Bi Kim ◽  
Hyung-Shik Shin ◽  
...  

A new and effective planar D-π-A configured small organic molecule (SOM) of 2-5-(3,5-dimethoxystyryl)thiophen-2-yl)methylene)-1H-indene-1,3(2H)-dione, abbreviated as DVB-T-ID, was synthesized using 1,3-indanedione acceptor and dimethoxy vinylbenzene donor units, connected through a thiophene π-spacer. The presence of a dimethoxy vinylbenzene unit and π-spacer in DVB-T-ID significantly improved the absorption behavior by displaying maximum absorbance at ~515 nm, and the reasonable band gap was estimated as ~2.06 eV. The electronic properties revealed that DVB-T-ID SOMs exhibited promising HOMO (−5.32 eV) and LUMO (−3.26 eV). The synthesized DVB-T-ID SOM was utilized as donor material for fabricating solution-processed bulk heterojunction organic solar cells (BHJ-OSCs) and showed a reasonable power conversion efficiency (PCE) of ~3.1% with DVB-T-ID:PC61BM (1:2, w/w) active layer. The outcome of this work clearly reflects that synthesized DVB-T-ID based on 1,3-indanedione units is a promising absorber (donor) material for BHJ-OSCs.


2019 ◽  
Vol 43 (26) ◽  
pp. 10442-10448 ◽  
Author(s):  
Sergey V. Dayneko ◽  
Arthur D. Hendsbee ◽  
Jonathan R. Cann ◽  
Clément Cabanetos ◽  
Gregory C. Welch

The addition of donor or acceptor type molecular semiconductors to PBDB-T:PC60BM based organic photovoltaics leads to increases in open circuit-voltages and overall power conversion efficiencies.


2019 ◽  
Vol 01 (01) ◽  
pp. 030-037 ◽  
Author(s):  
Jianyun Zhang ◽  
Wenrui Liu ◽  
Shengjie Xu ◽  
Xiaozhang Zhu

Recently, by elaborately designing nonfullerene acceptors and selecting suitable polymer donors great progresses have been made towards binary organic solar cells (OSCs) with power conversion efficiencies (PCEs) over 15%. Ternary organic photovoltaics by introducing a third component into the host binary system is recognized to be highly effective to elevate the performance through extending the light absorption, manipulating the recombination behavior of the carriers, and improving the morphology of the active layer. In this work, we synthesized a new electron-acceptor ZITI-4F matching it with the wide-bandgap polymer donor PBDB-T The PBDB-T:ZITI-4F-based OSC showed a high PCE of 12.33%. After introducing 40% of PC71BM as the third component, the ternary device achieved an improved PCE of 13.40% with simultaneously improved photovoltaic parameters. The higher performance of the ternary device can be attributed to the improved and more balanced charge mobility, reduced bimolecular recombination, and more favorable morphology. These results indicate that the cooperation of a fullerene-based acceptor and a nonfullerene acceptor to fabricate ternary OSCs is an effective approach to optimizing morphology and therefore to increase the performance of OSCs.


2017 ◽  
Vol 5 (6) ◽  
pp. 1275-1302 ◽  
Author(s):  
Wangqiao Chen ◽  
Qichun Zhang

The power conversion efficiencies (PCEs) of non-fullerene small molecule acceptors based on different donors have been compared and summarized.


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