Study of relativistic effects in atoms and molecules by the kinetically balanced LCAO approach: Ground state of hydrogen and of hydrogenic atoms in Slater and Gaussian basis functions

1993 ◽  
Vol 70 (11) ◽  
pp. 894 ◽  
Author(s):  
Lorenzo Pisani ◽  
Jean-Marie Andre ◽  
Marie-Claude Andre ◽  
Enrico Clementi
Keyword(s):  
Ground State ◽  
Relativistic Effects ◽  
Basis Functions ◽  
Atoms And Molecules ◽  
Gaussian Basis Functions

scholarly journals Photoionisation Cross Sections of Chlorine Atoms and Molecules at 584 Å

1986 ◽  
Vol 39 (5) ◽  
pp. 779 ◽  
Author(s):  
WJ van der Meer ◽  
RJ Butselaar ◽  
CA de Lange
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Ground State ◽  
Modulation Method ◽  
Absolute Cross Section ◽  
Molecular Chlorine ◽  
Chlorine Atoms ◽  
Atoms And Molecules ◽  
Ionic States ◽  
State Ionic

A recently developed modulation method is used to obtain cross sections for the photoionisation of ground state neutral to ground state ionic, atomic and molecular chlorine relative to that of the HCl + (X2n 1IZ,3IZ) +-- HCl(XI ~ +) transition at the He Ia wavelength. With the known absolute cross section of the latter process, determined by (e,2e) coincidence spectroscopy, the present ell,periments provide absolute photoionisation cross sections of the CI + epz,l,o) +-- Clep) and Cli (XZ n g, 1IZ,3 IZ) +-- Clz (X I ~ t) transitions. Relative cross sections, previously determined for the transitions to the additional Cl and Clz ionic states accessible with He Ia radiation, are used to obtain absolute cross sections for the Cl+(IDz, ISO) +-- Clep) and Cli(AZnu,1IZ,3IZ, BZ~t) +-- Clz(XI~t) ionisation processes.

Approximation of Gaussian basis functions in the problem of adaptive control of nonlinear objects

2011 ◽  
Vol 47 (1) ◽  
pp. 1-10 ◽  
Author(s):  
O. G. Rudenko ◽  
A. A. Bezsonov ◽  
A. S. Liashenko ◽  
R. A. Sunna
Keyword(s):  
Adaptive Control ◽  
Basis Functions ◽  
Gaussian Basis Functions

An Investigation on the Fine Structure Levels in the Ground State Configuration for the Antimony Anion

2014 ◽  
Vol 69 (8-9) ◽  
pp. 397-402
Author(s):  
Leyla Özdemir ◽  
Sadiye Tuna
Keyword(s):  
Fine Structure ◽  
Ground State ◽  
Transition Probabilities ◽  
Relativistic Effects ◽  
Electric Quadrupole ◽  
Radiative Transition ◽  
Ground State Configuration ◽  
Hartree Fock ◽  
First Time ◽  
State Configuration

We have investigated the correlation, relativistic, and isotope shift effects on the fine structure levels in the ground state configuration for the antimony anion ( Sb-). Energies and radiative transition probabilities (for magnetic dipole, M1, and electric quadrupole, E2) have been obtained using the multiconfiguration Hartree-Fock method within the framework of the Breit-Pauli Hamiltonian. Therefore, the most important configuration interaction and relativistic effects have been included. Comparisons with other available works are presented. For some M1 and E2 lines the considered transition probabilities are reported for the first time

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