Characterization and Performance in a Multicycle Test in a Fixed-Bed Reactor of Silica-Supported Copper Oxide as Oxygen Carrier for Chemical-Looping Combustion of Methane

2006 ◽  
Vol 20 (1) ◽  
pp. 148-154 ◽  
Author(s):  
B. M. Corbella ◽  
L. de Diego ◽  
F. García-Labiano ◽  
J. Adánez ◽  
J. M. Palacios
Keyword(s):  
Copper Oxide ◽  
Oxygen Carrier ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
And Performance

Chemical-looping combustion of methane with CaSO4 oxygen carrier in a fixed bed reactor

2008 ◽  
Vol 49 (11) ◽  
pp. 3178-3187 ◽  
Author(s):  
Qilei Song ◽  
Rui Xiao ◽  
Zhongyi Deng ◽  
Huiyan Zhang ◽  
Laihong Shen ◽  
...  
Keyword(s):  
Oxygen Carrier ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Caso4 Oxygen Carrier

Effects of ZnO Addition on Fe2O3/Al2O3 Oxygen Carriers on CH4 Reduction for Chemical Looping Combustion

2016 ◽  
Vol 872 ◽  
pp. 196-200
Author(s):  
Sujinda Thongsermsuk ◽  
Benjapon Chalermsinsuwan ◽  
Prapan Kuchonthara ◽  
Pornpote Piumsomboon
Keyword(s):  
Oxygen Carrier ◽  
Synergetic Effect ◽  
Fixed Bed ◽  
Reduction Process ◽  
Fixed Bed Reactor ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Oxygen Carriers ◽  
Fuel Gas ◽  
Physical Mixing

Fe2O3/Al2O3/ZnO oxygen carriers with small content ZnO (5 wt% to 10 wt%) were prepared by physical mixing method and were evaluated its capability as an oxygen carrier in a chemical looping combustion. The combustion was conducted by using CH4 as a fuel gas. The reduction process of Fe2O3/Al2O3/ZnO oxygen carrier was carried out in a fixed bed reactor. The solid reduction products were characterized by X-ray diffraction (XRD) and Scanning Electron Microscope with EDS Attachment (SEM-EDS). The results show that the reactivity of Fe2O3/Al2O3/ZnO oxygen carriers is greater than that of Fe2O3/Al2O3 which is implied the synergetic effect between ZnO and Fe2O3. XRD results show that the iron oxide in the oxygen carriers is reduced to metallic iron. SEM-EDS also shows that the iron agglomeration is prevented. Consequently, the suitable content of ZnO in oxygen carriers is ranged from 5 wt% to 10 wt%.

Investigation of a Novel Gas Turbine Cycle With Coal Gas Fueled Chemical-Looping Combustion

2000 ◽  
Author(s):  
Hongguang Jin ◽  
Masaru Ishida
Keyword(s):  
Natural Gas ◽  
Fixed Bed ◽  
Combined Cycle ◽  
Fixed Bed Reactor ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Gas Combustion ◽  
Coal Gas ◽  
New Type ◽  
Oxidation Reactor

Abstract A new type of integrated gasification combined cycle (IGCC) with chemical-looping combustion and saturation for air is proposed and investigated. Chemical-looping combustion may be carried out in two successive reactions between two reactors, a reduction reactor (coal gas with metal oxides) and an oxidation reactor (the reduced metal with oxygen in air). The study on the new system has revealed that the thermal efficiency of this new-generation power plant will be increased by approximately 10–15 percentage points compared to the conventional IGCC with CO2 recovery. Furthermore, to develop the chemical-looping combustor, we have experimentally examined the kinetic behavior between solid looping materials and coal gas in a high-pressure fixed bed reactor. We have identified that the coal gas chemical-looping combustor has much better reactivity, compared to the natural gas one. This finding is completely different from the direct combustion in which combustion with natural gas is much easier than that with other fuels. Hence, this new type of coal gas combustion will make breakthrough in clean coal technology by simultaneously resolving energy and environment problems.

Performance in a Fixed-Bed Reactor of Titania-Supported Nickel Oxide as Oxygen Carriers for the Chemical-Looping Combustion of Methane in Multicycle Tests

2006 ◽  
Vol 45 (1) ◽  
pp. 157-165 ◽  
Author(s):  
Beatriz M. Corbella ◽  
Luis F. de Diego ◽  
Francisco García-Labiano ◽  
Juan Adánez ◽  
José M. Palacios
Keyword(s):  
Nickel Oxide ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Oxygen Carriers

Combined calcium looping and chemical looping combustion cycles with CaO–CuO pellets in a fixed bed reactor

Fuel ◽  
2015 ◽  
Vol 153 ◽  
pp. 202-209 ◽  
Author(s):  
Firas N. Ridha ◽  
Dennis Lu ◽  
Arturo Macchi ◽  
Robin W. Hughes
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Calcium Looping

scholarly journals Kinetic Behavior of Fabricated CuO/ZrO2 Oxygen Carriers for Chemical Looping Oxygen Uncoupling

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2156
Author(s):  
Young Ku ◽  
Chia-Wei Chang ◽  
Shr-Han Shiu ◽  
Hsuan-Chih Wu ◽  
Niels Michiel Moed
Keyword(s):  
Elevated Temperatures ◽  
Cupric Oxide ◽  
Oxygen Carrier ◽  
Fixed Bed ◽  
Reduction Rate ◽  
Fixed Bed Reactor ◽  
Chemical Looping ◽  
Oxygen Carriers ◽  
Redox Cycles ◽  
Reduction And Oxidation

Chemical looping with oxygen uncoupling (CLOU) is an innovative alternative to conventional combustion. CuO/ZrO2 oxygen carriers were tested in this system for their effectiveness and resilience. Cupric oxide (CuO) was demonstrated to be a reliable oxygen carrier for oxygen-uncoupling with consistent recyclability even after 50 redox cycles in a thermogravimetric analyzer (TGA). The reduction of CuO to generate Cu2O and oxygen was observed to be improved markedly for experiments operated at higher temperatures; however, the oxidation of Cu2O by air to generate CuO was hindered for experiments carried out at elevated temperatures. The reduction rate of fabricated CuO/ZrO2 particles containing 40% CuO was enhanced with increasing temperature and decreased with increasing particle size for experiments operated in a fixed bed reactor. The geometrical contraction and Avrami-Erofe’ev models were demonstrated to be appropriate for describing the reduction and oxidation of CuO/ZrO2, respectively. The activation energies for the reduction and oxidation were determined to be 250.6 kJ/mol and 57.6 kJ/mol, respectively, based on experimental results in the temperature range between 850 and 1000 °C.

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