Electrosorption of Inorganic Salts from Aqueous Solution Using Carbon Aerogels

2002 ◽  
Vol 36 (13) ◽  
pp. 3010-3019 ◽  
Author(s):  
Christopher J. Gabelich ◽  
Tri D. Tran ◽  
I. H. “Mel” Suffet

1993 ◽  
Vol 271 (7) ◽  
pp. 657-667 ◽  
Author(s):  
P. Bahadur ◽  
K. Pandya ◽  
M. Almgren ◽  
P. Li ◽  
P. Stilbs


1977 ◽  
Vol 55 (23) ◽  
pp. 4018-4027 ◽  
Author(s):  
Robert Aveyard ◽  
Syed M. Saleem

An approach to the study of the influence of electrolytes on adsorbed nonelectrolytes at liquid surfaces is described. The adsorption of tetrabutylammonium bromide (Bu4NBr) from aqueous solution to the interfaces with octane, decanol, and air has been determined. Results are presented for the effects of some inorganic salts (NaCl, NH4Br, and Na2CO3), and of Bu4NBr on monolayers of butanol at the air – aqueous solution interface, and of Bu4NBr on dodecanol adsorbed at the octane – aqueous solution interface. The interfacial salt effects differ from the bulk effects in the cases studied. The inorganic salts, which salt-out butanol (and alkanols generally) in aqueous solution, have little or no effect on adsorbed butanol. On the other hand, Bu4NBr which salts-in alkanols in bulk aqueous solution has a strong salting-out effect on dodecanol at the liquid–liquid interface; a similar but less marked effect is observed for butanol at the liquid–vapour surface. Salting-in of alkanols by Bu4NBr in bulk has previously been ascribed to hydrophobic interactions between cations and alkyl groups of the alkanol, whereas the surface effect is assumed to result from interactions between alcoholic OH groups and cations.



1984 ◽  
Vol 265O (1) ◽  
Author(s):  
O. Sölmel ◽  
P. Novotny ◽  
Z. Sole


1973 ◽  
Vol 46 (12) ◽  
pp. 3703-3707 ◽  
Author(s):  
Kazuo Mochida ◽  
Akio Kagita ◽  
Yoshihisa Matsui ◽  
Yoshio Date


2008 ◽  
Vol 16 (5) ◽  
pp. 507-512 ◽  
Author(s):  
Wenjin Yang ◽  
Dingcai Wu ◽  
Ruowen Fu


2016 ◽  
Vol 852 ◽  
pp. 1349-1355
Author(s):  
Jia Yi Zhu ◽  
Xi Yang ◽  
Zhi Bing Fu ◽  
Chao Yang Wang ◽  
Wei Dong Wu ◽  
...  

The ultra-low density carbon aerogel, as low as 20 mg/cm3, was fabricated by pyrolysis of the organic aerogel formed by aqueous condensation of resorcinol and formaldehyde. Its surface area was as high as 1783 m2/g and it was used for investigation of electrochemical capacitive behaviours. The ultra-low density carbon aerogel displayed capacitive performance (110 F/g at 0.2 A/g) in 6 M KOH aqueous solution. Additionally, over 98% of the initial capacitance was retained after repeating the cyclic voltammetry test for 1000 cycles. The electrochemical performance might be attributed to the combination of three dimensional “opened” structure and high surface area of the carbon aerogel.





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