Dissolving pulps from Zea maize by alkaline sulfide and sulfite pulping

1983 ◽  
Vol 22 (3) ◽  
pp. 506-508 ◽  
Author(s):  
Mohamed A. Abou-State ◽  
Fouad F. Abd El-Megeid ◽  
Refaat I. Nesseem
TAPPI Journal ◽  
2010 ◽  
Vol 9 (7) ◽  
pp. 35-41
Author(s):  
OUTI A. HYÖKYVIRTA ◽  
TOM E. GUSTAFSSON

This investigation evaluated the applicability of a molybdenum sulfide reference electrode (MSRE) as an internal reference electrode for use in alkaline sulfide solutions over a range of pulp digester liquors at 170°C. The electrode remained stable during the exposure period of two weeks. The experimentally determined half cell potential of the MSRE is E = -0.91 VSHE. The surface of the MSRE was examined by scanning electron microscope (SEM) and electron spectroscopy for chemical analysis (ESCA) to verify the chemical composition of the thin surface film. Based on ESCA studies, the surface film contained molybdenum disulfide and sodium disulfide. During storage of the specimens, sulfide was partly oxidized to sodium sulfite in air. Next to the metallic molybdenum, a mixed molybdenum disulfide and molybdenum hydroxide layer was detected.


Author(s):  
Shishir Mundra ◽  
John L. Provis

AbstractThe pore fluid within many concretes is highly alkaline and rich in reduced sulfur species, but the influence of such alkaline-sulfide solutions on the surface film formed on steel reinforcement is poorly understood. This study investigates the critical role of HS− in defining mild steel passivation chemistry. The surface film formed on the steel in alkaline-sulfide solutions contains Fe(OH)2 and Fe–S complexes, and the critical chloride concentration to induce corrosion increases at high sulfide concentration. However, this behavior is dependent on the duration of exposure of the steel to the electrolyte, and the nature of the sulfidic surface layer.


Cellulose ◽  
2021 ◽  
Author(s):  
Isabel Carrillo-Varela ◽  
Regis Teixeira Mendonça ◽  
Miguel Pereira ◽  
Pablo Reyes-Contreras ◽  
David Contreras

Sign in / Sign up

Export Citation Format

Share Document