Oxidation State Analysis of a Four-Component Redox Series [Os(pap)2(Q)]nInvolving Two Different Non-Innocent Ligands on a Redox-Active Transition Metal

2011 ◽  
Vol 50 (15) ◽  
pp. 7090-7098 ◽  
Author(s):  
Dipanwita Das ◽  
Biprajit Sarkar ◽  
Tapan Kumar Mondal ◽  
Shaikh M. Mobin ◽  
Jan Fiedler ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Redox Active ◽  
Active Transition ◽  
State Analysis

scholarly journals Generation of Bis(ferrocenyl)silylenes from Siliranes

Molecules ◽  
2020 ◽  
Vol 25 (24) ◽  
pp. 5917
Author(s):  
Yang Pan ◽  
Shogo Morisako ◽  
Shinobu Aoyagi ◽  
Takahiro Sasamori
Keyword(s):  
Transition Metal ◽  
Building Block ◽  
Building Blocks ◽  
Redox Behavior ◽  
Organosilicon Compounds ◽  
Design And Synthesis ◽  
Mild Conditions ◽  
Redox Active ◽  
Electronic Perturbation ◽  
Active Transition

Divalent silicon species, the so-called silylenes, represent attractive organosilicon building blocks. Isolable stable silylenes remain scarce, and in most hitherto reported examples, the silicon center is stabilized by electron-donating substituents (e.g., heteroatoms such as nitrogen), which results in electronic perturbation. In order to avoid such electronic perturbation, we have been interested in the chemistry of reactive silylenes with carbon-based substituents such as ferrocenyl groups. Due to the presence of a divalent silicon center and the redox-active transition metal iron, ferrocenylsilylenes can be expected to exhibit interesting redox behavior. Herein, we report the design and synthesis of a bis(ferrocenyl)silirane as a precursor for a bis(ferrocenyl)silylene, which could potentially be used as a building block for redox-active organosilicon compounds. It was found that the isolated bis(ferrocenyl)siliranes could be a bottleable precursor for the bis(ferrocenyl)silylene under mild conditions.

Tailoring the redox-active transition metal content to enhance cycling stability in cation-disordered rock-salt oxides

2021 ◽  
Vol 43 ◽  
pp. 275-283
Author(s):  
Ke Zhou ◽  
Yining Li ◽  
Shiyao Zheng ◽  
Maojie Zhang ◽  
Chunyang Zhang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Rock Salt ◽  
Metal Content ◽  
Cycling Stability ◽  
Redox Active ◽  
Active Transition

Low-density lipoprotein modification by normal, myeloperoxidase-deficient and NADPH oxidase-deficient granulocytes and the impact of redox active transition metal ions

Redox Report ◽  
2002 ◽  
Vol 7 (2) ◽  
pp. 111-119 ◽  
Author(s):  
Claudia E. Gerber ◽  
Gernot Bruchelt ◽  
Gerhard Ledinski ◽  
Joachim Greilberger ◽  
Dietrich Niethammer ◽  
...  
Keyword(s):  
Transition Metal ◽  
Nadph Oxidase ◽  
Metal Ions ◽  
Low Density Lipoprotein ◽  
Density Lipoprotein ◽  
Transition Metal Ions ◽  
Low Density ◽  
Redox Active ◽  
Active Transition ◽  
The Impact

Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions

2018 ◽  
Vol 47 (33) ◽  
pp. 11303-11307 ◽  
Author(s):  
N. Leconte ◽  
B. Baptiste ◽  
C. Philouze ◽  
F. Thomas
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Pincer Ligand ◽  
Tert Butyl ◽  
Redox Active ◽  
Active Transition

The ligand undergoes N–N and C–N bond formations in the presence of redox-active transition metal ions, in air and coordinating solvents.

Arborols Based on Luminescent and Redox-Active Transition Metal Complexes

1992 ◽  
Vol 31 (11) ◽  
pp. 1493-1495 ◽  
Author(s):  
Scolastica Serroni ◽  
Gianfranco Denti ◽  
Sebastiano Campagna ◽  
Alberto Juris ◽  
Mauro Ciano ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Redox Active ◽  
Active Transition
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