Temperature Dependence of the Heat Capacity and Vapor Pressure of Pure Self-Associated Liquids. A New Correlation Based on a Two-State Association Model

2006 ◽  
Vol 45 (6) ◽  
pp. 2150-2155 ◽  
Author(s):  
Milton Medeiros ◽  
Carlos O. Armas-Alemán ◽  
Miguel Costas ◽  
Claudio A. Cerdeiriña
Keyword(s):  
Heat Capacity ◽  
Vapor Pressure ◽  
Temperature Dependence ◽  
Association Model ◽  
New Correlation ◽  
State Association

ABOUT HEAT CAPACITY OF TITANIUM CARBIDE TiCx

2019 ◽  
pp. 56-66
Author(s):  
I. Khidirov ◽  
V. V. Getmanskiy ◽  
A. S. Parpiev ◽  
Sh. A. Makhmudov
Keyword(s):  
Heat Capacity ◽  
High Temperature ◽  
Titanium Carbide ◽  
Temperature Dependence ◽  
Carbon Concentration ◽  
Room Temperature ◽  
Thermodynamic Characteristics ◽  
Liquid Nitrogen Temperature ◽  
Analysis Data ◽  
Thermal Excitation

This work relates to the field of thermophysical parameters of refractory interstitial alloys. The isochoric heat capacity of cubic titanium carbide TiCx has been calculated within the Debye approximation in the carbon concentration  range x = 0.70–0.97 at room temperature (300 K) and at liquid nitrogen temperature (80 K) through the Debye temperature established on the basis of neutron diffraction analysis data. It has been found out that at room temperature with decrease of carbon concentration the heat capacity significantly increases from 29.40 J/mol·K to 34.20 J/mol·K, and at T = 80 K – from 3.08 J/mol·K to 8.20 J/mol·K. The work analyzes the literature data and gives the results of the evaluation of the high-temperature dependence of the heat capacity СV of the cubic titanium carbide TiC0.97 based on the data of neutron structural analysis. It has been proposed to amend in the Neumann–Kopp formula to describe the high-temperature dependence of the titanium carbide heat capacity. After the amendment, the Neumann–Kopp formula describes the results of well-known experiments on the high-temperature dependence of the heat capacity of the titanium carbide TiCx. The proposed formula takes into account the degree of thermal excitation (a quantized number) that increases in steps with increasing temperature.The results allow us to predict the thermodynamic characteristics of titanium carbide in the temperature range of 300–3000 K and can be useful for materials scientists.

On Temperature Dependence of Excess Gibbs Energy

1999 ◽  
Vol 64 (7) ◽  
pp. 1093-1099 ◽  
Author(s):  
Ivona Malijevská ◽  
Anatol Malijevský
Keyword(s):  
Heat Capacity ◽  
Gibbs Energy ◽  
Temperature Dependence ◽  
Excess Gibbs Energy ◽  
Excess Enthalpy ◽  
Excess Heat Capacity ◽  
Wilson Equation ◽  
Excess Heat ◽  
Energy Excess ◽  
Wilson And Nrtl Equations

Temperature dependence of GE is discussed for three widely used equations linear and nonlinear in parameters. It is shown that the Wilson equation predicts always positive excess heat capacity regardless of values of its parameters. Several temperature modifications of the Redlich-Kister, Wilson and NRTL equations are discussed with respect to the sign of the excess Gibbs energy, excess enthalpy and excess heat capacity.

2,3-Dithiabutane: Low Temperature Heat Capacity, Heat of Fusion, Heat of Vaporization, Vapor Pressure, Entropy and Thermodynamic Functions1,2

1950 ◽  
Vol 72 (6) ◽  
pp. 2424-2430 ◽  
Author(s):  
D. W. Scott ◽  
H. L. Finke ◽  
M. E. Gross ◽  
G. B. Guthrie ◽  
H. M. Huffman
Keyword(s):  
Heat Capacity ◽  
Low Temperature ◽  
Vapor Pressure ◽  
Heat Of Fusion ◽  
Heat Of Vaporization ◽  
Temperature Heat ◽  
Low Temperature Heat Capacity

Heat capacity of activation for the hydrolysis of methanesulfonyl chloride and benzenesulfonyl chloride in light and heavy water

1969 ◽  
Vol 47 (22) ◽  
pp. 4199-4206 ◽  
Author(s):  
R. E. Robertson ◽  
B. Rossall ◽  
S. E. Sugamori ◽  
L. Treindl
Keyword(s):  
Heat Capacity ◽  
Free Energy ◽  
Temperature Dependence ◽  
Heavy Water ◽  
Bond Formation ◽  
Sulfonyl Chlorides ◽  
Benzenesulfonyl Chloride ◽  
Methanesulfonyl Chloride ◽  
Hydrolysis Of ◽  
Parameter Temperature Dependence

Rates of solvolysis of methanesulfonyl chloride and benzenesulfonyl chloride have been determined in H2O and D2O. The free energy, enthalpy, entropy, and heat capacity of activation were calculated. The exceptional accuracy of the data permitted an estimation of dΔCp≠/dT from a four parameter temperature dependence of the kinetic rates.From these data we conclude that both sulfonyl chlorides hydrolyse by the same mechanism (Sn2) The change in R from CH3 to C6H5 in RSO2Cl did not alter ΔCp≠ but ΔS≠ (20°) was changed from −8.32 to −13.25 cal deg−1 mole−1, respectively. The significance of this difference is attributed to the probability of bond formation rather than to differences in solvent reorganization.

The Heat Capacity and Entropy, Heats of Fusion and Vaporization and the Vapor Pressure of Silicon Tetramethyl

1941 ◽  
Vol 63 (9) ◽  
pp. 2343-2348 ◽  
Author(s):  
J. G. Aston ◽  
R. M. Kennedy ◽  
G. H. Messerly
Keyword(s):  
Heat Capacity ◽  
Vapor Pressure

Temperature dependence of the heat capacity of some titanium alloys

1967 ◽  
Vol 9 (6) ◽  
pp. 452-453 ◽  
Author(s):  
V. D. Sukhanov ◽  
Yu. N. Tsiovkin
Keyword(s):  
Heat Capacity ◽  
Temperature Dependence ◽  
Titanium Alloys
Sign in / Sign up

Export Citation Format

Share Document