Thermal Decomposition of Energetic Materials. 66. Kinetic Compensation Effects in HMX, RDX, and NTO

1994 ◽  
Vol 98 (47) ◽  
pp. 12242-12247 ◽  
Author(s):  
T. B. Brill ◽  
P. E. Gongwer ◽  
G. K. Williams
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials ◽  
Kinetic Compensation Effects

Low Pressure Thermal Decomposition Studies Selected Nitramine and Dinitramine Energetic Materials

1992 ◽  
Author(s):  
M. J. Rossi ◽  
D. F. McMillen ◽  
D. M. Golden
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials ◽  
Low Pressure

scholarly journals Comparative thermal research on tetraazapentalene-derived heat-resistant energetic structures

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jing Zhou ◽  
Li Ding ◽  
Yong Zhu ◽  
Bozhou Wang ◽  
Xiangzhi Li ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Energetic Materials ◽  
Great Influence ◽  
Fourier Transform Infrared ◽  
Thermal Decomposition Mechanism ◽  
Scanning Calorimetry ◽  
In Situ Ftir Spectroscopy ◽  
Heat Resistant

AbstractOrganic inner salt structures are ideal backbones for heat-resistant energetic materials and systematic studies towards the thermal properties of energetic organic inner salt structures are crucial to their applications. Herein, we report a comparative thermal research of two energetic organic inner salts with different tetraazapentalene backbones. Detailed thermal decomposition behaviors and kinetics were investigated through differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods, showing that the thermal stability of the inner salts is higher than most of the traditional heat-resistant energetic materials. Further studies towards the thermal decomposition mechanism were carried out through condensed-phase thermolysis/Fourier-transform infrared (in-situ FTIR) spectroscopy and the combination of differential scanning calorimetry-thermogravimetry-mass spectrometry-Fourier-transform infrared spectroscopy (DSC-TG-MS-FTIR) techniques. The experiment and calculation results prove that the arrangement of the inner salt backbones has great influence on the thermal decompositions of the corresponding energetic materials. The weak N4-N5 bond in “y-” pattern tetraazapentalene backbone lead to early decomposition process and the “z-” pattern tetraazapentalene backbone exhibits more concentrated decomposition behaviors.

Thermal decomposition of energetic materials

1991 ◽  
Vol 181 ◽  
pp. 71-77 ◽  
Author(s):  
J.K. Chen ◽  
T.B. Brill
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials

Early Thermal Decay of Energetic Hydrogen- and Nitro-Free Furoxan Compounds: The Case of DNTF and BTF

2021 ◽  
Author(s):  
Shuangfei Zhu ◽  
Wei Yang ◽  
Qiang Gan ◽  
Nianshou Cheng ◽  
Changgen Feng
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials ◽  
Decomposition Mechanism ◽  
Thermal Decomposition Mechanism ◽  
Thermal Decay

Exploring the initial reactions of H-free and nitro-free energetic materials could enrich our understanding into the thermal decomposition mechanism of various energetic materials (EMs). In this work, two furoxan compounds,...

Thermal decomposition of energetic materials 27. Synthesis, characterization, and thermolysis of Cu(II)-doped “blue RDX”

1988 ◽  
Vol 72 (2) ◽  
pp. 153-158 ◽  
Author(s):  
Stephen F. Palopoli ◽  
Thomas B. Brill
Keyword(s):  
Thermal Decomposition ◽  
Energetic Materials

Molecular Dynamics Insight into the Evolution of Al Nanoparticles in the Thermal Decomposition of Energetic Materials

2020 ◽  
Vol 124 (19) ◽  
pp. 10783-10792
Author(s):  
Weizhe Hao ◽  
Gang Li ◽  
Liangliang Niu ◽  
Ruijun Gou ◽  
Chaoyang Zhang
Keyword(s):  
Molecular Dynamics ◽  
Thermal Decomposition ◽  
Energetic Materials ◽  
Al Nanoparticles ◽  
Insight Into
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