Kinetics of the reactions of diatomic sulfur with atomic oxygen, molecular oxygen, ozone, nitrous oxide, nitric oxide, and nitrogen dioxide

1987 ◽  
Vol 91 (5) ◽  
pp. 1199-1204 ◽  
Author(s):  
Alan J. Hills ◽  
Ralph J. Cicerone ◽  
Jack G. Calvert ◽  
John W. Birks
Keyword(s):  
Nitric Oxide ◽  
Nitrous Oxide ◽  
Nitrogen Dioxide ◽  
Molecular Oxygen ◽  
Atomic Oxygen ◽  
Kinetics Of

THE EFFECT OF MOLECULAR OXYGEN ON THE REACTION OF OXYGEN ATOMS WITH cis-2-PENTENE

1959 ◽  
Vol 37 (5) ◽  
pp. 953-965 ◽  
Author(s):  
S. Sato ◽  
R. J. Cvetanović
Keyword(s):  
Nitric Oxide ◽  
Nitrous Oxide ◽  
Nitrogen Dioxide ◽  
Molecular Oxygen ◽  
Reaction Mechanisms ◽  
Room Temperature ◽  
Pressure Independent ◽  
Decomposition Of Nitrous Oxide ◽  
Oxygen Atoms

The effect of the presence of nitrogen, oxygen, and nitric oxide on the reaction between cis-2-pentene and oxygen atoms has been investigated at room temperature (25 ± 2 °C). For production of oxygen atoms use was made of mercury-photosensitized decomposition of nitrous oxide and of the photolysis of nitrogen dioxide at 3660 Å.In the N2O work, the presence of molecular oxygen induced the formation of acetaldehyde, propanal, methanol, and ethanol. In the NO2 work, the amounts of acetaldehyde, propanal, and ethyl nitrate formed increased rapidly with increasing pressure of molecular oxygen. Possible reaction mechanisms for the formation of these compounds are discussed.Additional information was obtained on the pressure-independent fragmentation in the reaction of oxygen atoms with cis-2-pentene.

Extending the use of the atomic oxygen + nitrogen dioxide .far. nitric oxide + molecular oxygen reaction for measuring low oxygen atom concentrations

1974 ◽  
Vol 78 (3) ◽  
pp. 208-210 ◽  
Author(s):  
Irene R. Slagle ◽  
Jolene A. Samlaska ◽  
Frank J. Pruss ◽  
D. Gutman
Keyword(s):  
Nitric Oxide ◽  
Oxygen Atom ◽  
Nitrogen Dioxide ◽  
Molecular Oxygen ◽  
Atomic Oxygen ◽  
Low Oxygen ◽  
Oxygen Reaction

NITROUS OXIDE AS AN OXIDIZING AGENT IN THE GASEOUS STATE

1935 ◽  
Vol 12 (5) ◽  
pp. 711-714 ◽  
Author(s):  
E. W. R. Steacie ◽  
R. D. McDonald
Keyword(s):  
Nitrous Oxide ◽  
Molecular Oxygen ◽  
Atomic Oxygen ◽  
Oxidizing Agent ◽  
Oxidation Reactions ◽  
Gaseous State ◽  
Oxygen Nitrous Oxide ◽  
Kinetics Of

The kinetics of a number of gaseous oxidation reactions have been investigated, using nitrous oxide as the oxidizing agent in place of oxygen. It is found that, in general, nitrous oxide is much less efficient as an oxidizing agent than is molecular oxygen. Nitrous oxide in most cases acts merely as a reservoir of atomic oxygen at temperatures where its rate of decomposition is appreciable.

Kinetics of the Nitrogen Dioxide Catalyzed Oxidation of Nitric Oxide

1957 ◽  
Vol 26 (5) ◽  
pp. 984-988 ◽  
Author(s):  
James D. Ray ◽  
Richard A. Ogg
Keyword(s):  
Nitric Oxide ◽  
Nitrogen Dioxide ◽  
Kinetics Of ◽  
Catalyzed Oxidation
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