Spectroscopic investigation of intramolecular interactions in cis and trans dimers of acenaphthylene

1970 ◽  
Vol 74 (6) ◽  
pp. 1255-1260 ◽  
Author(s):  
Nori Y. C. Chu ◽  
David R. Kearns
Keyword(s):  
Spectroscopic Investigation ◽  
Intramolecular Interactions ◽  
Cis And Trans ◽  
In Cis

scholarly journals Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen2NH3NCS]2+: The Preparation and Properties of trans-[Coen2NH3CN]2+

1973 ◽  
Vol 51 (24) ◽  
pp. 4152-4158 ◽  
Author(s):  
Albert Richard Norris ◽  
James William Lennox Wilson
Keyword(s):  
Hydrogen Peroxide ◽  
Spectral Properties ◽  
Peroxide Oxidation ◽  
Reaction Conditions ◽  
Thiocyanate Ion ◽  
Hydrogen Peroxide Oxidation ◽  
Percent Conversion ◽  
Cis And Trans ◽  
In Cis

The hydrogen peroxide oxidation of thiocyanate ion in cis- and trans-[Coen2NH3NCS]2+ leads to the formation of the corresponding cis- and trans-cyanoammine- and diamminebis(ethylenediamine)cobalt-(III) complexes. The spectral properties of the previously unreported trans-[Coe2NH3CN]2+ are reported and compared to the spectral properties of the cis-isomer.Observations are made concerning the reaction conditions which favor a high percent conversion of trans-[Coen2NH3NCS]2+ to trans-[Coen2NH3CN]2+.

Structure and chemical bonding in cis- and trans-M(NO)2(O2CR)2 (M=Cr and Mo) complexes

Polyhedron ◽  
2000 ◽  
Vol 19 (26-27) ◽  
pp. 2565-2572 ◽  
Author(s):  
Ludmiła Szterenberg ◽  
Szczepan Roszak ◽  
Renata Matusiak ◽  
Antoni Keller
Keyword(s):  
Chemical Bonding ◽  
Cis And Trans ◽  
In Cis

Hydrogen bonding and conformation in cis- and trans-2-alkoxy-3-hydroxytetrahydrofurans

1968 ◽  
Vol 46 (1) ◽  
pp. 21-24 ◽  
Author(s):  
W. W. Zajac Jr. ◽  
F. Sweet ◽  
R. K. Brown
Keyword(s):  
Hydrogen Bonding ◽  
Infrared Spectra ◽  
Hydroxyl Absorption ◽  
Cis And Trans ◽  
In Cis ◽  
Infrared Data ◽  
Hydrogen Bonded

Infrared spectra show both free and hydrogen bonded hydroxyl absorption in several trans-2-alkoxy-3-hydroxytetrahydrofurans. The extent of non-bonded hydroxyl is greater than that of bonded hydroxyl. Suggestions are made of possible conformations which might account for the infrared data.

Spectroscopic Study of Photosensitized Oxidation of Polyisoprene

1977 ◽  
Vol 50 (4) ◽  
pp. 704-713 ◽  
Author(s):  
M. A. Golub ◽  
M. L. Rosenberg ◽  
R. V. Gemmer
Keyword(s):  
Zero Order ◽  
Double Bonds ◽  
Photosensitized Oxidation ◽  
The Third ◽  
Type Process ◽  
Zero Order Kinetics ◽  
Hydroperoxide Formation ◽  
Cis And Trans ◽  
In Cis ◽  
Suitable Measure

Abstract The microstructural changes which occur in cis- and trans-1,4-polyisoprenes and in squalene during photosensitized oxidation were investigated with the aid of infrared and proton and carbon-13 NMR spectroscopy. The singlet oxygenation of these isoprenic compounds resulted in allylic hydroperoxides with shifted double bonds, according to the expected “ene”-type process. In contrast to trans-1,4-polyisoprene and squalene, which displayed the three possible double bond shifts, cis-1,4-polyisoprene showed essentially two of the shifts (to di- and trisubstituted double bonds) and very little of the third (to exomethylene groups). A suitable measure of the extent of hydroperoxidation was afforded by the absorbance ratio, A3400/A1440≡A′. Similar correlations of A′ with oxygen uptake were obtained for the three isoprenic compounds, using chlorophyll or methylene blue as sensitizer. The use of rose bengal gave erratic results indicative of some autoxidation accompanying the hydroperoxide formation. The singlet oxygenation followed zero-order kinetics, the relative rates for cis- and trans-1,4-polyisoprenes being approximately 1.0:1.5.

ChemInform Abstract: Is There Any Electronic Delocalization Operative in cis-1,2-Dihydro-1, 2-diphosphetes? Structural Comparison of cis and trans-1,2-Dihydro-1,2- diphosphetes.

ChemInform ◽  
2010 ◽  
Vol 24 (2) ◽  
pp. no-no
Author(s):  
N. MAIGROT ◽  
L. RICARD ◽  
C. CHARRIER ◽  
P. LE GOFF ◽  
F. MATHEY
Keyword(s):  
Structural Comparison ◽  
Electronic Delocalization ◽  
Cis And Trans ◽  
In Cis

Pyrrolidine ring puckering in cis and trans-proline residues in proteins and polypeptides

1992 ◽  
Vol 228 (3) ◽  
pp. 725-734 ◽  
Author(s):  
E.James Milner-White ◽  
Lachlan H. Bell ◽  
Peter H. Maccallum
Keyword(s):  
Pyrrolidine Ring ◽  
Ring Puckering ◽  
Cis And Trans ◽  
In Cis

A silencer element from the alpha-globin gene inhibits expression of beta-like genes

1988 ◽  
Vol 8 (11) ◽  
pp. 5047-5051
Author(s):  
G F Atweh ◽  
J M Liu ◽  
H E Brickner ◽  
X X Zhu
Keyword(s):  
Globin Gene ◽  
Expression System ◽  
Globin Genes ◽  
Beta Globin ◽  
Base Pair Fragment ◽  
Alpha Globin ◽  
In Trans ◽  
Cis And Trans ◽  
In Cis ◽  
Silencer Element

We have studied the cis and trans interactions of the alpha- and beta-globin genes in a transient expression system. We found that the alpha-globin gene inhibited beta-globin expression in cis but not in trans. The silencer element responsible for this inhibition was localized to a 259-base-pair fragment at the 5' end of the alpha-globin gene.

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