Hydrogen Peroxide Oxidation of Coordinated Thiocyanate Ion in cis- and trans-[Coen2NH3NCS]2+: The Preparation and Properties of trans-[Coen2NH3CN]2+
Keyword(s):
The hydrogen peroxide oxidation of thiocyanate ion in cis- and trans-[Coen2NH3NCS]2+ leads to the formation of the corresponding cis- and trans-cyanoammine- and diamminebis(ethylenediamine)cobalt-(III) complexes. The spectral properties of the previously unreported trans-[Coe2NH3CN]2+ are reported and compared to the spectral properties of the cis-isomer.Observations are made concerning the reaction conditions which favor a high percent conversion of trans-[Coen2NH3NCS]2+ to trans-[Coen2NH3CN]2+.
Keyword(s):
1972 ◽
Vol 5
(2)
◽
pp. 146-150
◽
2005 ◽
Vol 4
(4)
◽
pp. 519-535
2017 ◽
Vol 13
(6)
◽
pp. 473-487
1996 ◽
Vol 56
(1-4)
◽
pp. 199-210
◽
Keyword(s):
2014 ◽
Vol 258
◽
pp. 334-340
◽