Transference Numbers of Colloidal "Ferric Hydroxide."

1936 ◽  
Vol 40 (8) ◽  
pp. 997-1004 ◽  
Author(s):  
James W. McBain ◽  
Winifred McClatchie Thomas
Keyword(s):  
Ferric Hydroxide ◽  
Transference Numbers

New Technologies for Decontamination of Radioactive Substances Scattered by Nuclear Accident / Nowe Technologie Dekontaminacji Radioaktywnych Substancji Rozproszonych Przez Awarie Nuklearna

2013 ◽  
Vol 58 (1) ◽  
pp. 283-290 ◽  
Author(s):  
Y. Nishizaki ◽  
H. Miyamae ◽  
S. Ichikawa ◽  
K. Izumiya ◽  
T. Takano ◽  
...  
Keyword(s):  
Radioactive Waste ◽  
New Technologies ◽  
Ferric Hydroxide ◽  
Nuclear Accident ◽  
Radioactive Cesium ◽  
Cesium Ions ◽  
Naoh Solution ◽  
High Concentrations ◽  
Water Rinsing

Our effort for decontamination of radioactive cesium scattered widely by nuclear accident in March 2011 in Fukushima, Japan has been described. Radioactive cesium scattered widely in Japan has been accumulating in arc or plasma molten-solidified ash in waste incinerating facilities up to 90,000 Bq/kg of the radioactive waste. Water rinsing of the ash resulted in dissolution of cesium ions together with high concentrations of potassium and sodium ions. Although potassium inhibits the adsorption of cesium on zeolite, we succeeded to precipitate cesium by in-situ formation of ferric ferrocyanide and iron rust in the radioactive filtrate after rinsing of the radioactive ash with water. Because the regulation of no preservation of any kind of cyanide substances, cesium was separated from the precipitate consisting of cesium-captured ferric ferrocyanide and ferric hydroxide in diluted NaOH solution and subsequent filtration gave rise to the potassium-free radioactive filtrate. Cesium was captured by zeolite from the potassium-free radioactive filtrate. The amount of this final radioactive waste of zeolite was significantly lower than that of the arc-molten-solidified ash.

scholarly journals Iron-Oxidizing Bacteria Are Associated with Ferric Hydroxide Precipitates (Fe-Plaque) on the Roots of Wetland Plants

1999 ◽  
Vol 65 (6) ◽  
pp. 2758-2761 ◽  
Author(s):  
David Emerson ◽  
Johanna V. Weiss ◽  
J. Patrick Megonigal
Keyword(s):  
Ferric Hydroxide ◽  
Root Systems ◽  
Wetland Plants ◽  
Positive Correlation ◽  
Cell Numbers ◽  
Iron Oxidizing Bacteria ◽  
Soil Solutions ◽  
Fe Plaque ◽  
Ph Range

ABSTRACT The presence of Fe-oxidizing bacteria in the rhizosphere of four different species of wetland plants was investigated in a diverse wetland environment that had Fe(II) concentrations ranging from tens to hundreds of micromoles per liter and a pH range of 3.5 to 6.8. Enrichments for neutrophilic, putatively lithotrophic Fe-oxidizing bacteria were successful on roots from all four species; acidophilic Fe-oxidizing bacteria were enriched only on roots from plants whose root systems were exposed to soil solutions with a pH of <4. InSagittaria australis there was a positive correlation (P < 0.01) between cell numbers and the total amount of Fe present; the same correlation was not found for Leersia oryzoides. These results present the first evidence for culturable Fe-oxidizing bacteria associated with Fe-plaque in the rhizosphere.

scholarly journals Turbidity Changes during Carbamazepine Oxidation by Photo-Fenton

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 894
Author(s):  
Natalia Villota ◽  
Cristian Ferreiro ◽  
Hussein A. Qulatein ◽  
Jose M. Lomas ◽  
Jose Ignacio Lombraña
Keyword(s):  
Ferric Hydroxide ◽  
Coordination Complexes ◽  
Strong Increase ◽  
H2o2 Concentration ◽  
Iron Species ◽  
Ph Values ◽  
Carboxylic Groups ◽  
Main Decomposition ◽  
High Turbidity ◽  
Catalyst Dosage

The objective of this study is to evaluate the turbidity generated during the Fenton photo-reaction applied to the oxidation of waters containing carbamazepine as a function of factors such as pH, H2O2 concentration and catalyst dosage. The results let establish the degradation pathways and the main decomposition byproducts. It is found that the pH affects the turbidity of the water. Working between pH = 2.0 and 2.5, the turbidity is under 1 NTU due to the fact that iron, added as a catalyst, is in the form of a ferrous ion. Operating at pH values above 3.0, the iron species in their oxidized state (mainly ferric hydroxide in suspension) would cause turbidity. The contribution of these ferric species is a function of the concentration of iron added to the process, verifying that the turbidity increases linearly according to a ratio of 0.616 NTU L/mg Fe. Performing with oxidant concentrations at (H2O2) = 2.0 mM, the turbidity undergoes a strong increase until reaching values around 98 NTU in the steady state. High turbidity levels can be originated by the formation of coordination complexes, consisting of the union of three molecules containing substituted carboxylic groups (BaQD), which act as ligands towards an iron atom with Fe3+ oxidation state.

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

scholarly journals Investigating the effects of process parameters on the filtration performance of ferric hydroxide in a continuous MSMPR reactor

2021 ◽  
Vol 202 ◽  
pp. 105594
Author(s):  
Ina Beate Jenssen ◽  
Seniz Ucar ◽  
Ole Morten Dotterud ◽  
Oluf Bøckman ◽  
Jens-Petter Andreassen
Keyword(s):  
Process Parameters ◽  
Ferric Hydroxide ◽  
Filtration Performance

scholarly journals Polyester‐ZrO 2 Nanocomposite Electrolytes with High Li Transference Numbers for Ambient Temperature All‐Solid‐State Lithium Batteries

2020 ◽  
Author(s):  
Tian Khoon Lee ◽  
Rassmus Andersson ◽  
Nurul Akmaliah Dzulkurnain ◽  
Guiomar Hernández ◽  
Jonas Mindemark ◽  
...  
Keyword(s):  
Solid State ◽  
Ambient Temperature ◽  
Lithium Batteries ◽  
Transference Numbers ◽  
Nanocomposite Electrolytes

Arsenic removal from groundwater through iron oxyhydroxide coated waste productsA paper submitted to the Journal of Environmental Engineering and Science.

2009 ◽  
Vol 36 (5) ◽  
pp. 881-888 ◽  
Author(s):  
Elsadig A.M. Abdallah ◽  
Graham A. Gagnon
Keyword(s):  
Ferric Oxide ◽  
Arsenic Removal ◽  
Ferric Hydroxide ◽  
Structure Surface ◽  
Seafood Industry ◽  
Isotherm Adsorption ◽  
Scallop Shells ◽  
Glass Recycling ◽  
By Products ◽  
Better Than

The goal of this research was to remove arsenic from groundwater supplies via adsorption into media obtained from waste material generated as by-products from glass recycling programs and the seafood industry such as crushed glass and scallop shells. During the course of this research four new adsorbents were developed: ferric hydroxide coated crushed glass (FHCCG); ferric oxide coated crushed glass (FOCCG); ferric hydroxide coated scallop shells (FHCSS); and ferric oxide coated scallop shells (FOCSS). The adsorbents were characterized through evaluation of their structure, surface area, chemical composition, iron content, and coating stability. Efficiency of the adsorbents to remove arsenic from water was examined through batch kinetic and isotherm adsorption experiments. The adsorption capacity of the adsorbents was also evaluated by performing column experiments using real ground waters and a synthetic water. Arsenic removal to a concentration less than 10 μg/L was achieved with the FHCSS and more than 9000 bed volumes of water were treated before the breakthrough point was reached. The research results revealed that scallop shells coated with ferric hydroxideperformed better than crushed glass coated with ferric hydroxide. Both FOCCG and FOCSS had poor arsenic removal compared with FHCSS and granular ferric hydroxide (GFH). Ferric hydroxide coated scallop shells performed similarly to GFH.

THE ACTIVITY COEFFICIENTS AND TRANSFERENCE NUMBERS OF BARIUM BROMIDE

1926 ◽  
Vol 48 (6) ◽  
pp. 1504-1506 ◽  
Author(s):  
Ralph W. Gelbach ◽  
Walter F. Huppke
Keyword(s):  
Activity Coefficients ◽  
Transference Numbers
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