Nucleophilic aromatic substitution by organostannylsodiums. A second-order reaction displaying a solvent cage effect

1978 ◽  
Vol 100 (9) ◽  
pp. 2779-2789 ◽  
Author(s):  
Karl R. Wursthorn ◽  
Henry G. Kuivila ◽  
Gary F. Smith
Keyword(s):  
Order Reaction ◽  
Second Order ◽  
Nucleophilic Aromatic Substitution ◽  
Cage Effect ◽  
Aromatic Substitution ◽  
Second Order Reaction ◽  
Solvent Cage

Stability of radical anions derived from substituted 5-nitrofurans investigated by ESR spectroscopy

1985 ◽  
Vol 50 (7) ◽  
pp. 1594-1601 ◽  
Author(s):  
Jiří Klíma ◽  
Larisa Baumane ◽  
Janis Stradinš ◽  
Jiří Volke ◽  
Romualds Gavars
Keyword(s):  
Radical Anion ◽  
High Stability ◽  
Esr Spectroscopy ◽  
Reaction Path ◽  
Order Reaction ◽  
Second Order ◽  
Radical Anions ◽  
Second Order Reaction ◽  
Unpaired Electron Density ◽  
The Stability

It has been found that the decay in dimethylformamide and dimethylformamide-water mixtures of radical anions in five of the investigated 5-nitrofurans is governed by a second-order reaction. Only the decay of the radical anion generated from 5-nitro-2-furfural III may be described by an equation including parallel first- and second-order reactions; this behaviour is evidently caused by the relatively high stability of the corresponding dianion, this being an intermediate in the reaction path. The presence of a larger conjugated system in the substituent in position 2 results in a decrease of the unpaired electron density in the nitro group and, consequently, an increase in the stability of the corresponding radical anions.

Kinetics of the reaction between hexamethylenediisocyanate and 1-pentanol

1983 ◽  
Vol 48 (11) ◽  
pp. 3279-3286
Author(s):  
Slavko Hudeček ◽  
Miloslav Bohdanecký ◽  
Ivana Hudečková ◽  
Pavel Špaček ◽  
Pavel Čefelín
Keyword(s):  
Liquid Chromatography ◽  
Rate Constants ◽  
Reversed Phase ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Reversed Phase Liquid Chromatography ◽  
Consecutive Reactions ◽  
Phase Liquid ◽  
Kinetics Of

The reaction between hexamethylenediisocyanate and 1-pentanol in toluene was studied by means of reversed-phase liquid chromatography. By employing this method, it was possible to determine all components of the reaction mixture including both products, i.e. N-(6-isocyanate hexyl)pentylcarbamate and N,N'-bis(pentyloxycarbonyl)hexamethylenediamine. Relations for the calculation of kinetic constants were derived assuming a competitive consecutive second-order reaction. It was demonstrated that the reaction involved in this case is indeed a second-order reaction, and the rate constants of the first and second consecutive reactions were determined.

Internal-state nonequilibrium effects for a fast, second-order reaction

1985 ◽  
Vol 89 (1) ◽  
pp. 5-7 ◽  
Author(s):  
Carmay Lim ◽  
Donald G. Truhlar
Keyword(s):  
Internal State ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Nonequilibrium Effects

Analytical resolution of a parallel second-order reaction mechanism

2003 ◽  
Vol 35 (6) ◽  
pp. 246-251
Author(s):  
A. E. Croce ◽  
L. V. Mogni ◽  
C. Vicente Irrazábal
Keyword(s):  
Reaction Mechanism ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Analytical Resolution

scholarly journals Ribonucleic acid–deoxyribonucleic acid hybridization as a second-order reaction

1973 ◽  
Vol 135 (3) ◽  
pp. 573-576 ◽  
Author(s):  
Bryan D. Young ◽  
John Paul
Keyword(s):  
Dna Hybridization ◽  
Ribonucleic Acid ◽  
Deoxyribonucleic Acid ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Reaction Theory

Certain features of RNA–DNA hybridization can be accounted for in terms of second-order-reaction theory. These include the use of annealing kinetics to estimate RNA complexity and the occurrence of approximately linear double-reciprocal plots.

Kinetics of binding the mRNA cap analogues to the translation initiation factor eIF4E under second-order reaction conditions

2007 ◽  
Vol 129 (2-3) ◽  
pp. 289-297 ◽  
Author(s):  
Elżbieta Błachut-Okrasińska ◽  
Elżbieta Bojarska ◽  
Janusz Stępiński ◽  
J.M. Antosiewicz
Keyword(s):  
Translation Initiation ◽  
Order Reaction ◽  
Second Order ◽  
Translation Initiation Factor ◽  
Initiation Factor ◽  
Second Order Reaction ◽  
Reaction Conditions ◽  
Kinetics Of
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