Chemistry of N-haloamines. XIX. Amination of toluene, adamantane, and tert-butyl chloride with monochloramine-aluminum chloride

1973 ◽  
Vol 95 (9) ◽  
pp. 2977-2982 ◽  
Author(s):  
John W. Strand ◽  
Peter. Kovacic
Keyword(s):  
Aluminum Chloride ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Chloride

scholarly journals tert.-Butylation of Toluene: A Statistical Study

1970 ◽  
Vol 43 (4) ◽  
pp. 545-552
Author(s):  
Mohammad Ismail ◽  
Mohammad Abu Hanif ◽  
Mirza Galib ◽  
Manoranjan Saha
Keyword(s):  
Statistical Model ◽  
Aluminum Chloride ◽  
Molar Ratio ◽  
Butyl Chloride ◽  
Anhydrous Aluminum Chloride ◽  
Tert Butyl ◽  
Catalyst Temperature ◽  
Experimental Yield ◽  
The Difference ◽  
Tert Butyl Chloride

A statistical model was developed for the alkylation of toluene with tert.-butyl chloride in presence of anhydrous aluminum chloride as catalyst. Temperature, molar ratio of toluene to tert.-butyl chloride and amount of anhydrous aluminum chloride were chosen for investigation. A set of trials was planned according to a 3 factor 2-level Yates pattern experimental design with 2 replicates and the center point trial with 4 replicates. The critical response was the yield of tert.-butyl toluene. Two- and three-factor interaction effects together with the main effects were statistically significant. The adequacy of the suggested model was checked up. The difference between the experimental and predicted yields did not exceed 2.22%. The best yield of the tert.-butyl toluene was 51.2%. Key words: tert. Butylation, Yates pattern, Experimental yield, Statistical model.     doi: 10.3329/bjsir.v43i4.2245 Bangladesh J. Sci. Ind. Res. 43(4), 545-552, 2008

tert-Butyl Chloride-Aluminum Chloride

2001 ◽  
Author(s):  
George A. Olah ◽  
G. K. Surya Prakash ◽  
Qi Wang ◽  
Xing-ya Li
Keyword(s):  
Aluminum Chloride ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Chloride

Liquid-phase isobutane alkylation with butenes over aluminum chloride complexes synthesized in situ from activated aluminum and tert-butyl chloride

2012 ◽  
Vol 53 (3) ◽  
pp. 357-362 ◽  
Author(s):  
A. B. Arbuzov ◽  
V. A. Drozdov ◽  
M. O. Kazakov ◽  
A. V. Lavrenov ◽  
M. V. Trenikhin ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Aluminum Chloride ◽  
Butyl Chloride ◽  
Chloride Complexes ◽  
Tert Butyl ◽  
Isobutane Alkylation ◽  
Tert Butyl Chloride

scholarly journals tert-Butylation of 1-Naphthol with tert-Butyl Alcohol or tert-Butyl Chloride in the Presence of Sulfuric Acid or Zinc Chloride

1973 ◽  
Vol 31 (10) ◽  
pp. 831-834 ◽  
Author(s):  
Toshiyuki MIYATA ◽  
Takahiro HAMADA ◽  
Tsuneaki HIRASHIMA ◽  
Osamu MANABE ◽  
Hachiro HIYAMA
Keyword(s):  
Sulfuric Acid ◽  
Zinc Chloride ◽  
Butyl Alcohol ◽  
Butyl Chloride ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Tert Butyl Chloride
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