The Iodine-catalyzed, Positional Isomerization of Olefins. A New Tool for the Precise Measurement of Thermodynamic Data

1963 ◽  
Vol 85 (10) ◽  
pp. 1385-1387 ◽  
Author(s):  
Sidney W. Benson ◽  
A. N. Bose
Keyword(s):  
Thermodynamic Data ◽  
Precise Measurement ◽  
Positional Isomerization

PRECISE MEASUREMENT OF ENERGY DISTRIBUTION IN Ga LMIS

1987 ◽  
Vol 48 (C6) ◽  
pp. C6-141-C6-146 ◽  
Author(s):  
M. Komuro ◽  
T. Kato
Keyword(s):  
Energy Distribution ◽  
Precise Measurement

Adsorption and corrosion inhibition characteristics of two medicinal molecules

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Half Life ◽  
Thermodynamic Data ◽  
Inhibition Efficiency ◽  
Gravimetric Method ◽  
Corrosive Environment ◽  
Corrosion Inhibition Efficiency

The corrosion inhibition characteristics of two medicinal molecules phenylalanine and rutin on mild steel in 1.0M Hydrochloric acid were evaluated using gravimetric method. Corrosion inhibition efficiency of 83.78 and 90.40 % was obtained respectively after seven days. However, phenylalanine showed weak accumulative higher corrosion inhibition efficiency. The presence of both molecules in the corrosive environment reduced the corrosion rate constant and increased the material half-life. Thermodynamic data calculated suggests a spontaneous adsorption of the molecules on the mild steel’s surface.

Sparse Representation Based Dielectric Loss Angle Measurement

2015 ◽  
Vol 9 (1) ◽  
pp. 566-570
Author(s):  
Zhang Ji ◽  
Jianfeng Zheng
Keyword(s):  
Dielectric Loss ◽  
Power Systems ◽  
Sparse Representation ◽  
Precise Measurement ◽  
Angle Measurement ◽  
Measuring Error ◽  
Loss Angle ◽  
Analysis Method ◽  
Electric Capacity ◽  
Dielectric Loss Angle

Precise measurement of dielectric loss angle is very important for electric capacity equipment in recent power systems. When signal-to-noise is low and fundamental frequency is fluctuating, aiming at the measuring error of dielectric loss angle based on some recent Fourier transform and wavelet transform harmonics analysis method, we propose a novel algorithm based on sparse representation, and improved it to be more flexible for signal sampling. Comparison experiments describe the advantages of our method.

The Potential-pH Diagrams Depicting the Hydrogen Chemisorption in the Pt-H2O, Ir-H2O, and Rh-H2O Systems at 25 °C

1995 ◽  
Vol 60 (4) ◽  
pp. 553-558 ◽  
Author(s):  
Tomáš Loučka
Keyword(s):  
Thermodynamic Data ◽  
Hydrogen Chemisorption

Thermodynamic data for the chemisorption of hydrogen on the Pt, Ir, and Rh electrodes were evaluated from data in the literature. On the basis of these data, the potential-pH diagrams were calculated for the Pt-H2O, Ir-H2O, and Rh-H2O systems describing the hydrogen chemisorption. For the hydrogen chemisorption, the surface was considered to be uniformly inhomogeneous.

Thermodynamic Data of Iodine Reactions Calculated by Quantum Chemistry. Training Set of Molecules

2008 ◽  
Vol 73 (10) ◽  
pp. 1340-1356 ◽  
Author(s):  
Katarína Mečiarová ◽  
Laurent Cantrel ◽  
Ivan Černušák
Keyword(s):  
Quantum Chemistry ◽  
Ab Initio ◽  
Thermodynamic Data ◽  
Theoretical Calculations ◽  
Reactor Core ◽  
Fission Products ◽  
Vapour Phase ◽  
Reactor Accident ◽  
Training Set ◽  
Coolant System

This paper focuses on the reactivity of iodine which is the most critical radioactive contaminant with potential short-term radiological consequences to the environment. The radiological risk assessments of 131I volatile fission products rely on studies of the vapour-phase chemical reactions proceeding in the reactor coolant system (RCS), whose function is transferring the energy from the reactor core to a secondary pressurised water line via the steam generator. Iodine is a fission product of major importance in any reactor accident because numerous volatile iodine species exist under reactor containment conditions. In this work, the comparison of the thermodynamic data obtained from the experimental measurements and theoretical calculations (approaching "chemical accuracy") is presented. Ab initio quantum chemistry methods, combined with a standard statistical-thermodynamical treatment and followed by inclusion of small energetic corrections (approximating full configuration interaction and spin-orbit effects) are used to calculate the spectroscopic and thermodynamic properties of molecules containing atoms H, O and I. The set of molecules and reactions serves as a benchmark for future studies. The results for this training set are compared with reference values coming from an established thermodynamic database. The computed results are promising enough to go on performing ab initio calculations in order to predict thermo-kinetic parameters of other reactions involving iodine-containing species.

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