Reactivity of Strained Compounds:  Is Ground State Destabilization the Major Cause for Rate Enhancement?1

1996 ◽  
Vol 118 (2) ◽  
pp. 416-420 ◽  
Author(s):  
Ariel Sella ◽  
Harold Basch ◽  
Shmaryahu Hoz
Keyword(s):  
Ground State ◽  
Rate Enhancement

scholarly journals An Ancestral Tryptophanyl-tRNA Synthetase Precursor Achieves High Catalytic Rate Enhancement without Ordered Ground-State Tertiary Structures

2016 ◽  
Vol 11 (6) ◽  
pp. 1661-1668 ◽  
Author(s):  
Paul J. Sapienza ◽  
Li Li ◽  
Tishan Williams ◽  
Andrew L. Lee ◽  
Charles W. Carter
Keyword(s):  
Ground State ◽  
Trna Synthetase ◽  
Tertiary Structures ◽  
Rate Enhancement ◽  
Catalytic Rate

Remarkably large solvolytic rate enhancement due to relief of ground state leaving group strain

1974 ◽  
Vol 96 (6) ◽  
pp. 1969-1970 ◽  
Author(s):  
Joel Slutsky ◽  
Richard C. Bingham ◽  
Paul V. R. Schleyer ◽  
W. C. Dickason ◽  
H. C. Brown
Keyword(s):  
Ground State ◽  
Rate Enhancement ◽  
Leaving Group ◽  
Group Strain

ChemInform Abstract: A REMARKABLY LARGE SOLVOLYTIC RATE ENHANCEMENT DUE TO RELIEF OF GROUND STATE LEAVING GROUP STRAIN

1974 ◽  
Vol 5 (22) ◽  
pp. no-no
Author(s):  
JOEL SLUTSKY ◽  
RICHARD C. BINGHAM ◽  
PAUL VON R. SCHLEYER ◽  
W. C. DICKASON ◽  
H. C. BROWN
Keyword(s):  
Ground State ◽  
Rate Enhancement ◽  
Leaving Group ◽  
Group Strain

Renilla Bioluminescence: A Morphologic Approach to the Location of Photocytes

1974 ◽  
Vol 32 ◽  
pp. 208-209
Author(s):  
Ben O. Spurlock ◽  
Milton J. Cormier
Keyword(s):  
Excited State ◽  
Ground State ◽  
Molecular Basis ◽  
Light Emission ◽  
Chemical Basis ◽  
Electronic Excited State ◽  
Colonial Form ◽  
The Common ◽  
Eighteenth And Nineteenth Centuries ◽  
Catalyzed Oxidation

The phenomenon of bioluminescence has fascinated layman and scientist alike for many centuries. During the eighteenth and nineteenth centuries a number of observations were reported on the physiology of bioluminescence in Renilla, the common sea pansy. More recently biochemists have directed their attention to the molecular basis of luminosity in this colonial form. These studies have centered primarily on defining the chemical basis for bioluminescence and its control. It is now established that bioluminescence in Renilla arises due to the luciferase-catalyzed oxidation of luciferin. This results in the creation of a product (oxyluciferin) in an electronic excited state. The transition of oxyluciferin from its excited state to the ground state leads to light emission.

The ground state energy of the ±J spin glass from the genetic algorithm

1994 ◽  
Vol 4 (9) ◽  
pp. 1281-1285 ◽  
Author(s):  
P. Sutton ◽  
D. L. Hunter ◽  
N. Jan
Keyword(s):  
Genetic Algorithm ◽  
Spin Glass ◽  
Ground State Energy ◽  
Ground State ◽  
State Energy
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