scholarly journals Backbone Hydrogen Bond Energies in Membrane Proteins Are Insensitive to Large Changes in Local Water Concentration

2020 ◽  
Vol 142 (13) ◽  
pp. 6227-6235 ◽  
Author(s):  
Henry J. Lessen ◽  
Ananya Majumdar ◽  
Karen G. Fleming
Nature ◽  
1963 ◽  
Vol 200 (4908) ◽  
pp. 776-777 ◽  
Author(s):  
MANSEL DAVIES ◽  
BRIAN KYBETT

1985 ◽  
Vol 63 (7) ◽  
pp. 1399-1406 ◽  
Author(s):  
G. Caldwell ◽  
P. Kebarle

Experimental measurements of the gas phase ion equilibria X− + HX = XHX−, X−(HX)n−1 + HX = X−(HX)n, and X− + HY = XHY where X, Y = Cl, Br, I, with a high pressure mass spectrometer, combined with the recent determination of F− + HF = FHF− by Larson and McMahon, provide a very complete set of hydrogen bond dissociation enthalpies and free energies for the hydrogen bihalide ions. The bond energy trends in the different XHX− and XHY− are discussed. The data can be used also for the evaluation of lattice energies of salts containing the bihalide ions and for determinations of the solvation energies of these ions.


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