Mediated Charge Transfer at Nanoelectrodes: A New Approach to Electrochemical Reactivity Mapping and Nanosensing

2021 ◽  
Author(s):  
Koushik Barman ◽  
Xiang Wang ◽  
Rui Jia ◽  
Michael V. Mirkin
Keyword(s):  
Charge Transfer ◽  
New Approach ◽  
Electrochemical Reactivity

A molecular tailoring approach – a new guide to quantify the energy of push–pull effects: a case study on (E)-3-(1H-pyrrol-2-yl)prop-2-enones

2020 ◽  
Vol 22 (39) ◽  
pp. 22190-22194
Author(s):  
Andrei V. Afonin ◽  
Danuta Rusinska-Roszak
Keyword(s):  
Charge Transfer ◽  
New Approach ◽  
Internal Charge Transfer ◽  
Internal Charge ◽  
Molecular Tailoring

We report a new approach to quantify the push–pull effect in molecules with internal charge transfer.

scholarly journals Excitonic Interactions in Bacteriochlorin Homo-Dyads Enable Charge Transfer: A New Approach to the Artificial Photosynthetic Special Pair

2018 ◽  
Vol 122 (14) ◽  
pp. 4131-4140 ◽  
Author(s):  
Christopher McCleese ◽  
Zhanqian Yu ◽  
Nopondo N. Esemoto ◽  
Charles Kolodziej ◽  
Buddhadev Maiti ◽  
...  
Keyword(s):  
Charge Transfer ◽  
New Approach ◽  
Special Pair ◽  
Excitonic Interactions ◽  
Artificial Photosynthetic

New approach to electrochemical reactivity of aniline tetramer through a combined view of DFT and CV descriptors

2018 ◽  
Vol 242 ◽  
pp. 8-16
Author(s):  
Nuno A. Barbosa ◽  
Kamil Wójcik ◽  
Robert Wieczorek ◽  
Maria Grzeszczuk
Keyword(s):  
New Approach ◽  
Electrochemical Reactivity

Application of Wide Band Gap Semiconductors to Increase Photocurrent in a Protein Based Photovoltaic Device

2012 ◽  
Vol 1414 ◽  
Author(s):  
Arash Takshi ◽  
Houman Yaghoubi ◽  
Daniel Jun ◽  
Rafael Saer ◽  
Ali Mahmoudzadeh ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Indium Tin Oxide ◽  
Wide Band ◽  
Photocurrent Density ◽  
Wide Bandgap ◽  
Semiconducting Materials ◽  
Wide Band Gap ◽  
Electron Hole ◽  
New Approach ◽  
Wide Band Gap Semiconductors

ABSTRACTReaction centers (RCs) from natural photosynthetic cells are photoactive proteins, which generate electron-hole pairs in presence of light. In a new approach presented in this work, a solution of suspended RCs with mediators has been applied as the electrolyte to build electrochemical based photovoltaic (PV) devices. In this approach, the mediators transfer charges from the RCs to the electrodes (indirect charge transfer). Various metallic and wide bandgap semiconducting materials, including Carbon, Au, Indium Tin Oxide (ITO), SnO2, WO3, have been tested as the electrodes. Among all WO3, which is a semiconductor, have shown the largest photocurrent density with an amount of ∼5.1 μA/cm2. The results show that the material of the electrode can affect the rates of the reactions in the cell. Choosing an appropriate material for the electrode, the charge transfer from the mediators to the electrode would be rectified to achieve a large photocurrent.

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