Bifunctional Metal–Organic Layers for Tandem Catalytic Transformations Using Molecular Oxygen and Carbon Dioxide

2021 ◽  
Author(s):  
Wenjie Shi ◽  
Yangjian Quan ◽  
Guangxu Lan ◽  
Kaiyuan Ni ◽  
Yang Song ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Molecular Oxygen ◽  
Organic Layers ◽  
Catalytic Transformations ◽  
Metal Organic

Metal–Organic Layers Leading to Atomically Thin Bismuthene for Efficient Carbon Dioxide Electroreduction to Liquid Fuel

2020 ◽  
Vol 132 (35) ◽  
pp. 15124-15130 ◽  
Author(s):  
Changsheng Cao ◽  
Dong‐Dong Ma ◽  
Jia‐Fang Gu ◽  
Xiuyuan Xie ◽  
Guang Zeng ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Liquid Fuel ◽  
Organic Layers ◽  
Metal Organic ◽  
Carbon Dioxide Electroreduction

Photosensitizing Metal–Organic Layers for Efficient Sunlight-Driven Carbon Dioxide Reduction

2018 ◽  
Vol 140 (39) ◽  
pp. 12369-12373 ◽  
Author(s):  
Guangxu Lan ◽  
Zhe Li ◽  
Samuel S. Veroneau ◽  
Yuan-Yuan Zhu ◽  
Ziwan Xu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Reduction ◽  
Organic Layers ◽  
Metal Organic

Metal–Organic Layers Leading to Atomically Thin Bismuthene for Efficient Carbon Dioxide Electroreduction to Liquid Fuel

2020 ◽  
Vol 59 (35) ◽  
pp. 15014-15020 ◽  
Author(s):  
Changsheng Cao ◽  
Dong‐Dong Ma ◽  
Jia‐Fang Gu ◽  
Xiuyuan Xie ◽  
Guang Zeng ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Liquid Fuel ◽  
Organic Layers ◽  
Metal Organic ◽  
Carbon Dioxide Electroreduction

N-Functionality Actuated Largely Improved CO2 Adsorption and Nanomolar Turn-on Detection of Organo-Toxins with Guest-Induced Fluorescence Modulation in Isostructural Diamondoid Frameworks

2021 ◽  
Author(s):  
Manpreet Singh ◽  
Athulya S. Palakkal ◽  
Renjith S. Pillai ◽  
Subhadip Neogi
Keyword(s):  
Carbon Dioxide ◽  
Functional Group ◽  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Turn On ◽  
Metal Organic ◽  
Fluorescence Modulation

Metal-organic frameworks (MOFs) have surfaced as incipient class of multifaceted materials for selective carbon dioxide (CO2) adsorption and luminescent detection of assorted classes of lethal organo-aromatics, where functional group assisted...

scholarly journals Understanding carbon dioxide capture on metal–organic frameworks from first-principles theory: The case of MIL-53(X), with X = Fe3+, Al3+, and Cu2+

2021 ◽  
Vol 155 (2) ◽  
pp. 024701
Author(s):  
Giane B. Damas ◽  
Luciano T. Costa ◽  
Rajeev Ahuja ◽  
C. Moyses Araujo
Keyword(s):  
Carbon Dioxide ◽  
First Principles ◽  
Carbon Dioxide Capture ◽  
Metal Organic Frameworks ◽  
Metal Organic

Synergistic effect of phosphomolybdic acid on rhodium-based metal-organic frameworks for the efficient selective photocatalytic reduction of CO2 to CO

2021 ◽  
Author(s):  
Yurong Shan ◽  
Dexiang Liu ◽  
Chunyan Xu ◽  
Peng Zhan ◽  
Hui Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electronic Structure ◽  
Synergistic Effect ◽  
Metal Organic Frameworks ◽  
Phosphomolybdic Acid ◽  
Photocatalytic Reduction ◽  
Structure And Morphology ◽  
Spherical Structure ◽  
Metal Organic ◽  
Reduction Of Co2

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...

Robust photocatalytic hydrogen production on metal-organic layers of Al-TCPP with ultrahigh turnover numbers

2021 ◽  
Author(s):  
Hui Yu ◽  
Xiang Wu ◽  
Qiaoqiao Mu ◽  
Zhihe Wei ◽  
Yindong Gu ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Photocatalytic Hydrogen Production ◽  
Organic Layers ◽  
Metal Organic

scholarly journals Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Omid T. Qazvini ◽  
Ravichandar Babarao ◽  
Shane G. Telfer
Keyword(s):  
Carbon Dioxide ◽  
Density Functional ◽  
Metal Organic Framework ◽  
Density Functional Theory Calculations ◽  
Time Lags ◽  
X Ray Crystallography ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Short Time ◽  
Organic Framework

AbstractEfficient and sustainable methods for carbon dioxide capture are highly sought after. Mature technologies involve chemical reactions that absorb CO2, but they have many drawbacks. Energy-efficient alternatives may be realised by porous physisorbents with void spaces that are complementary in size and electrostatic potential to molecular CO2. Here, we present a robust, recyclable and inexpensive adsorbent termed MUF-16. This metal-organic framework captures CO2 with a high affinity in its one-dimensional channels, as determined by adsorption isotherms, X-ray crystallography and density-functional theory calculations. Its low affinity for other competing gases delivers high selectivity for the adsorption of CO2 over methane, acetylene, ethylene, ethane, propylene and propane. For equimolar mixtures of CO2/CH4 and CO2/C2H2, the selectivity is 6690 and 510, respectively. Breakthrough gas separations under dynamic conditions benefit from short time lags in the elution of the weakly-adsorbed component to deliver high-purity hydrocarbon products, including pure methane and acetylene.

A Microporous Titanate‐Based Metal–Organic Framework for Efficient Separation of Acetylene from Carbon Dioxide

2021 ◽  
Author(s):  
Huanxin Chen ◽  
Xin Li ◽  
Miaoyu Liu ◽  
Yuxun Zhang ◽  
Yong Liu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Efficient Separation ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A Cofacial Metal-Organic Framework Based Photocathode for Carbon Dioxide Reduction

2021 ◽  
Author(s):  
Bowen Ding ◽  
Bun Chan ◽  
Nicholas Proschogo ◽  
Marcello Solomon ◽  
Cameron Kepert ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Energy Harvesting ◽  
Solar Energy ◽  
Metal Organic Framework ◽  
Carbon Dioxide Reduction ◽  
Solar Energy Harvesting ◽  
Metal Organic ◽  
Organic Framework

Innovative and robust photosensitisation materials play a cardinal role in advancing the combined effort towards efficient solar energy harvesting. Here, we demonstrate the photocathode functionality of a Metal-Organic Framework (MOF)...

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