N-Functionality Actuated Largely Improved CO2 Adsorption and Nanomolar Turn-on Detection of Organo-Toxins with Guest-Induced Fluorescence Modulation in Isostructural Diamondoid Frameworks

Turn On ◽

Metal Organic ◽

Fluorescence Modulation

Metal-organic frameworks (MOFs) have surfaced as incipient class of multifaceted materials for selective carbon dioxide (CO2) adsorption and luminescent detection of assorted classes of lethal organo-aromatics, where functional group assisted...

Enhanced CO2 adsorption capacity of amine-functionalized MIL-100(Cr) metal–organic frameworks

CrystEngComm ◽

10.1039/c4ce01265h ◽

2015 ◽

Vol 17 (2) ◽

pp. 430-437 ◽

Cited By ~ 29

Author(s):

Carlos Palomino Cabello ◽

Gloria Berlier ◽

Giuliana Magnacca ◽

Paolo Rumori ◽

Gemma Turnes Palomino

Keyword(s):

Carbon Dioxide ◽

Adsorption Capacity ◽

Co2 Adsorption ◽

Metal Organic Framework ◽

Sorption Properties ◽

Amine Functionalized ◽

Carbon Dioxide Sorption ◽

Metal Organic ◽

Co2 Adsorption Capacity

Functionalization of the MIL-100(Cr) metal–organic framework with alkylamines (ethylenediamine and N,N′-dimethylethylenediamine) improves carbon dioxide sorption properties, especially in the case of ethylenediamine.

Adsorption of carbon dioxide on MIL53(Al), CuBTC and K- NaX zeolite

ICONTECH INTERNATIONAL JOURNAL ◽

10.46291/icontechvol4iss3pp30-42 ◽

2020 ◽

Vol 4 (3) ◽

pp. 30-42

Author(s):

Fehime Cakicioglu-Ozkan

Keyword(s):

Carbon Dioxide ◽

Specific Surface ◽

Surface Area ◽

Specific Surface Area ◽

Co2 Adsorption ◽

Ultrasonic Method ◽

Isosteric Heat ◽

Metal Organic ◽

Increasing Temperature

CO2 adsorption on K exchanged NaX zeolites, and metal organic frameworks (MOFs), namely Cu-BTC and MIL53 (Al) was studied at 5 °C and 25 °C. Exchange via ultrasonic and traditional methods, was conducted at 50 °C and 70 °C. The maximum replacement of Na+ ion with K+ ion in the extra framework of zeolite was increased from 76% to 83% with increasing temperature from 50 °C to 70 °C in the ultrasonic method which is more effective than traditional one. Compared with the zeolites, the MOF adsorbents used in this work have higher Langmuir specific surface area values namely 1278, 1473 and about 1000 m2/g for MIL 53, Cu-BTC and zeolite adsorbents respectively. The resulting CO2 isotherms can be well represented by the Toth equation. Comparison of the isosteric heat of adsorption at zero loading shows that CO2 was adsorbed more weakly on MOFs than zeolites.

Tetrazole-based porous metal–organic frameworks for selective CO2 adsorption and isomerization studies

Dalton Transactions ◽

10.1039/c9dt04068d ◽

2020 ◽

Vol 49 (7) ◽

pp. 2145-2150 ◽

Cited By ~ 1

Author(s):

Rui Zhang ◽

De-Xian Meng ◽

Fa-Yuan Ge ◽

Jv-Hua Huang ◽

Li-Fei Wang ◽

...

Keyword(s):

Carbon Dioxide ◽

High Selectivity ◽

Co2 Adsorption ◽

Porous Metal ◽

Tetrazole-based porous MOFs and isomers were synthesized for adsorbing carbon dioxide, showing high selectivity.

Understanding carbon dioxide capture on metal–organic frameworks from first-principles theory: The case of MIL-53(X), with X = Fe3+, Al3+, and Cu2+

The Journal of Chemical Physics ◽

10.1063/5.0054874 ◽

2021 ◽

Vol 155 (2) ◽

pp. 024701

Author(s):

Giane B. Damas ◽

Luciano T. Costa ◽

Rajeev Ahuja ◽

C. Moyses Araujo

Keyword(s):

Carbon Dioxide ◽

First Principles ◽

Carbon Dioxide Capture ◽

Synergistic effect of phosphomolybdic acid on rhodium-based metal-organic frameworks for the efficient selective photocatalytic reduction of CO2 to CO

New Journal of Chemistry ◽

10.1039/d0nj06053d ◽

2021 ◽

Author(s):

Yurong Shan ◽

Dexiang Liu ◽

Chunyan Xu ◽

Peng Zhan ◽

Hui Wang ◽

...

Keyword(s):

Carbon Dioxide ◽

Electronic Structure ◽

Synergistic Effect ◽

Phosphomolybdic Acid ◽

Photocatalytic Reduction ◽

Structure And Morphology ◽

Spherical Structure ◽

Metal Organic ◽

Reduction Of Co2

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

Journal of Energy Chemistry ◽

10.1016/j.jechem.2019.04.013 ◽

2020 ◽

Vol 40 ◽

pp. 156-170 ◽

Cited By ~ 27

Author(s):

Ping Shao ◽

Luocai Yi ◽

Shumei Chen ◽

Tianhua Zhou ◽

Jian Zhang

Keyword(s):

Carbon Dioxide ◽

Electrochemical Reduction ◽

Metal Centers ◽

Selective CO2 Adsorption by Nitro Functionalized Metal Organic Frameworks

Crystal Growth & Design ◽

10.1021/acs.cgd.5b01686 ◽

2016 ◽

Vol 16 (3) ◽

pp. 1162-1167 ◽

Cited By ~ 56

Author(s):

Dilip Kumar Maity ◽

Arijit Halder ◽

Biswajit Bhattacharya ◽

Anamika Das ◽

Debajyoti Ghoshal

Keyword(s):

Co2 Adsorption ◽

Enhancing activity for carbon dioxide methanation by encapsulating (1 1 1) facet Ni particle in metal–organic frameworks at low temperature

Journal of Catalysis ◽

10.1016/j.jcat.2017.02.031 ◽

2017 ◽

Vol 348 ◽

pp. 200-211 ◽

Cited By ~ 52

Author(s):

Wenlong Zhen ◽

Feng Gao ◽

Bin Tian ◽

Ping Ding ◽

Yibing Deng ◽

...

Keyword(s):

Carbon Dioxide ◽

Low Temperature ◽

Metal Organic ◽

Carbon Dioxide Methanation

The difference in CO2 adsorption capacities of different functionalized pillar-layered metal-organic frameworks (MOFs)

Dalton Transactions ◽

10.1039/d1dt00498k ◽

2021 ◽

Author(s):

Xiang-Jing Gao ◽

Hegen Zheng

Keyword(s):

Co2 Adsorption ◽

Co2 Concentration ◽

Fossil Energy ◽

Adsorption Capacities ◽

Metal Organic ◽

The Difference

The excessive use of fossil energy has caused the CO2 concentration in the atmosphere to increase year by year. MOFs are ideal CO2 adsorbents that can be used in CO2...