Excited States of 4-Aminobenzonitrile (ABN) and 4-Dimethylaminobenzonitrile (DMABN):  Time-resolved Resonance Raman, Transient Absorption, Fluorescence, and ab Initio Calculations†

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W. M. Kwok ◽  
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D. Phillips ◽  
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Kentaro Koide

We have studied the relationship between the π-topology and the photo-excited high-spin states of π-conjugated spin systems, 9-anthracen-(3-phenyl-t-butylnitroxide) radical (1m) and 9-anthracen-(4-phenyl-t-butylnitroxide) radical (1p) systems, by time-resolved ESR and transient absorption spectroscopies.


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