Influence of TiO2 pigment particles on chromate ion transport in epoxy films

Transport of active species (i.e., ions) leaching from pigment particles incorporated in a polymer matrix is the main mechanism behind the anticorrosive performance of protective coatings. Understanding this mechanism is necessary for the effective design of the systems utilizing pigments less toxic than the most efficient chromate salts. It was demonstrated that anticorrosive pigment particles can themselves facilitate the transport of active species via the pathways formed after pigment leaching from a coating. It was also suggested that other paint components, e.g., certain additives, pigments, and fillers can be involved in the formation of transport pathways. Investigation of the possible influence of inert pigment (TiO2) on creating the pathways for chromate ion transport in polymer coatings was the primary objective of this work. In an experiment mimicking the transport of pigment species (i.e., chromate ions), a model epoxy coating containing particles of a single pigment (TiO2) was exposed to a chromate solution (aqueous, or with the addition of acetone as a polymer swelling agent). It was shown that the chromate ions can be transported in the epoxy film preferentially via the TiO2 particles/polymer matrix interface.

Efficient removal of chromate ions from aqueous solution using a highly cost-effective ferric coordinated [3-(2-aminoethylamino)propyl]trimethoxysilane–MCM-41 adsorbent

The present investigation involves synthesis and characterization of MCM-41–AEAPTMS–Fe(iii)Cl using coordinated Fe(iii) on MCM-41–AEAPTMS for efficient removal of hazardous Cr(vi) ions from aqueous solution.

Efficient detection of Fe(iii) and chromate ions in water using two robust lanthanide metal–organic frameworks

Two novel robust Ln-MOFs feature a 3D highly porous pillared-layer framework and demonstrate selective sensing of Fe(iii) and chromate ions in aqueous solution.

Reinforcement of Quaternary Ammonium Modified Silica (QAMS) with Magnetite and its Application by Solid Phase Adsorption (SPA) to Adsorb Chromate Ions

Chromium (VI) in the form of chromate anions that have toxic properties needs to be overcome. This study aims to reinforce cationic sorbent quaternary amine-modified silica with magnetite (QAMS-Fe3O4) to adsorb chromate ions. QAMS prepared by reflux methylation ammine modified silica (AMS) obtained from destruction silicate from rice husk ash followed by the addition of 3-APTMS. Characterization QAMS-Fe3O4 by FT-IR showed successfully of methylation process indicated by disappearing absorbance at 1388 cm-1, and emerging absorbance at 2939 cm-1 in QAMS and QAMS-Fe3O4 indicated a transformation of N-H from -NH2 group to [-N+(CH3)3]. XRD analysis denotes 2θ = 30.15°, 35.53°, 43.12°, 57.22°, and 62.90° (JCPDS No. 00-033-0664) fathomed as a characteristic peak of magnetite. SEM-EDX reveals the homogenous topological spherical form with an average particle size 0.006 µm that is dominated by Si element (52.81%) with magnetic moment value = 34.1 emu/g. The stability test shows that this material stable in an acid condition. The adsorption of chromate ions was conducted by the SPA method. Optimal pH obtained by pH range 4-7 with more than 90% adsorbed chromate ions. Variation of increasing series flow rate from 0.05 to 1.5 mL min-1 resulted in decreased adsorbed chromate ions. The use of SPA methods offered simpler and easier handling than the batch method without overriding the adsorption process effectiveness.

Sequential Detection of Palladium and Chromium Oxyanion by a Fluorescein Based Chemosensor in Mixed Aqueous Media

A new highly selective chemosensor, based on fluorescein-allyloxy benzene conjugate 1, was developed for the sequential detection of palladium and chromium oxyanions in a mixed aqueous media, and was studied by UV-visible and fluorescence spectroscopy. The sensing of palladium ions produces a chemodosimetric and ratiometric change in the emission band of 1 from 450 to 525 nm, followed by the sensing of chromate ions by 2 that quenches the emission band at 525 nm in a buffered H2O: DMF solution (9:1, pH = 7.4). The rate constants of palladium and chromate ions were found to be 8.6 × 105 M−1, 2.1 × 105 M−1, and 5.4 × 104 M−1 respectively. The chemosensor 1 has a palladium detection limit of 49 ppb while the sequential detection limit of chromate ions (CrO42− and Cr2O72−) were 127 and 259 ppb. The ratiometric change in the emission is produced due to the deallylation of 1 by palladium to produce 2 that restores the ESIPT (excited state intramolecular proton transfer) of the phenolic ring and enhances the electron transfer (ET) phenomenon from the phenolic group to fluorescein. The sequential binding of chromate ions to 2 inhibits the ESIPT and causes chelation enhanced quenching (CHEQ) of the fluorescence.