Tetrathiafulvalene-Based Materials for Organic Field Effect Transistors. Inspection of Their Semiconductor Properties by Means of Molecular Spectroscopy and Quantum Chemistry

2007 ◽  
Vol 111 (27) ◽  
pp. 10110-10118 ◽  
Author(s):  
Juan Casado ◽  
Marek Z. Zgierski ◽  
Mari Carmen Ruiz Delgado ◽  
Juan T. López Navarrete ◽  
Marta Mas-Torrent ◽  
...  
2020 ◽  
Vol 02 (03) ◽  
pp. 204-213
Author(s):  
Miriam Hauschild ◽  
Michal Borkowski ◽  
Pavlo O. Dral ◽  
Tomasz Marszalek ◽  
Frank Hampel ◽  
...  

We report the synthesis of 5,7,12,14-tetraphenyl-substituted 6,13-dihydro-6,13-diazapentacene and its fully aromatic 6,13-diazapentacene congener. Both arylated diazapentacenes were characterized by X-ray crystallography to investigate their solid-state structures and by UV–vis spectroscopy and cyclic voltammetry to unveil their electronic properties. The experimental results are complemented with theoretical investigations. The semiconductor properties of both diazapentacene derivatives were assessed in organic field-effect transistors, whereby the fully aromatized compound showed comparably less abundant n-type behavior.


Nano Select ◽  
2021 ◽  
Author(s):  
Yanjun Shi ◽  
Jie Liu ◽  
Yuanyuan Hu ◽  
Wenping Hu ◽  
Lang Jiang

2021 ◽  
Author(s):  
Chaoyang Zong ◽  
Xiaoting Zhu ◽  
Zhanqiang Xu ◽  
Lifeng Zhang ◽  
Jun Xu ◽  
...  

2021 ◽  
Author(s):  
Yankai Zhou ◽  
Weifeng Zhang ◽  
Gui Yu

This review highlights the recent structural evolution of lactam- and imide-functionalized polymers applied in organic field-effect transistors and organic solar cells.


2021 ◽  
Vol 03 (02) ◽  
pp. 303-308
Author(s):  
Dror Ben Abba Amiel ◽  
Choongik Kim ◽  
Ori Gidron

Donor–acceptor–donor (DAD) triad systems are commonly applied as active materials in ambipolar organic field-effect transistors, organic solar cells, and NIR-emitting organic light-emitting diodes. Often, these triads utilize oligothiophenes as donors, whereas their oxygen-containing analogs, oligofurans, are far less studied in this setup. Here we introduce a family of DAD triads in which the donors are oligofurans and the acceptor is benzothiadiazole. In a combined computational and experimental study, we show that these triads display optical bandgaps similar to those of their thiophene analogs, and that a bifuran donor is sufficient to produce emission in the NIR spectral region. The presence of a central acceptor unit increases the photostability of oligofuran-based DAD systems compared with parent oligofurans of the similar length.


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