Photophysical Properties and Ultrafast Excited-State Dynamics of a New Two-Photon Absorbing Thiopyranyl Probe

2013 ◽  
Vol 117 (23) ◽  
pp. 11941-11952 ◽  
Author(s):  
Kevin D. Belfield ◽  
Mykhailo V. Bondar ◽  
Alma R. Morales ◽  
Andrew Frazer ◽  
Ivan A. Mikhailov ◽  
...  

2006 ◽  
Vol 110 (40) ◽  
pp. 11435-11439 ◽  
Author(s):  
Grzegorz M. Balkowski ◽  
Michiel Groeneveld ◽  
Hong Zhang ◽  
Cindy C. J. Hendrikx ◽  
Michael Polhuis ◽  
...  


2014 ◽  
Vol 5 (3) ◽  
pp. 560-565 ◽  
Author(s):  
Oliver Schalk ◽  
Andrey E. Boguslavskiy ◽  
Albert Stolow


2017 ◽  
Vol 34 (4) ◽  
pp. 043101 ◽  
Author(s):  
Jin-You Long ◽  
Chun-Long Hu ◽  
Bing Zhang


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3904
Author(s):  
Kaveendra Maduwantha ◽  
Shigeyuki Yamada ◽  
Kaveenga Rasika Koswattage ◽  
Tsutomu Konno ◽  
Takuya Hosokai

Room-temperature phosphorescent (RTP) materials have been attracting tremendous interest, owing to their unique material characteristics and potential applications for state-of-the-art optoelectronic devices. Recently, we reported the synthesis and fundamental photophysical properties of new RTP materials based on benzil, i.e., fluorinated monobenzil derivative and fluorinated and non-fluorinated bisbenzil derivative analogues [Yamada, S. et al., Beilstein J. Org. Chem. 2020, 16, 1154–1162.]. To deeply understand their RTP properties, we investigated the excited-state dynamics and photostability of the derivatives by means of time-resolved and steady-state photoluminescence spectroscopies. For these derivatives, clear RTP emissions with lifetimes on the microsecond timescale were identified. Among them, the monobenzil derivative was found to be the most efficient RTP material, showing both the longest lifetime and highest amplitude RTP emission. Time-resolved photoluminescence spectra, measured at 77 K, and density functional theory calculations revealed the existence of a second excited triplet state in the vicinity of the first excited singlet state for the monobenzil derivative, indicative of the presence of a fast intersystem crossing pathway. The correlation between the excited state dynamics, emission properties, and conformational flexibility of the three derivatives is discussed.



2008 ◽  
Vol 25 (7) ◽  
pp. 2456-2459 ◽  
Author(s):  
Yan Yong-Li ◽  
Li Bo ◽  
Liu Kang-Jun ◽  
Dong Zhi-Wei ◽  
Ma Guo-Hong ◽  
...  


2016 ◽  
Vol 18 (7) ◽  
pp. 5587-5596 ◽  
Author(s):  
David J. Stewart ◽  
Matthew J. Dalton ◽  
Stephanie L. Long ◽  
Ramamurthi Kannan ◽  
Zhenning Yu ◽  
...  

Steric hindrance inhibits excited-state relaxation and intramolecular charge-transfer, which significantly alters the photophysical properties.





2020 ◽  
Vol 49 (33) ◽  
pp. 11668-11674
Author(s):  
Abdulaziz A. Alanazi ◽  
Lukasz Wojtas ◽  
Jacob M. Mayers ◽  
Jaroslava Miksovska ◽  
Randy W. Larsen

Porphyrin deformation in the new metal organic framework RWLAA-1 modulates the photohysical properties of the material specifically by limiting excited state dynamics.



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