Interpretation of Carbonyl Band Splitting Phenomenon of a Novel Thermotropic Liquid Crystalline Polymer without Conventional Mesogens: Combination Method of Spectral Analysis and Molecular Simulation

2010 ◽  
Vol 114 (10) ◽  
pp. 3439-3448 ◽  
Author(s):  
Shengtong Sun ◽  
Hui Tang ◽  
Peiyi Wu
Keyword(s):  
Spectral Analysis ◽  
Molecular Simulation ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Combination Method ◽  
Thermotropic Liquid Crystalline Polymer ◽  
Band Splitting ◽  
Carbonyl Band

scholarly journals Fiber Formation and Structural Development of HBA/HNA Thermotropic Liquid Crystalline Polymer in High-Speed Melt Spinning

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1134
Author(s):  
Bo Seok Song ◽  
Jun Young Lee ◽  
Sun Hwa Jang ◽  
Wan-Gyu Hahm
Keyword(s):  
Mechanical Properties ◽  
Shear Rate ◽  
High Speed ◽  
Melt Spinning ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Fiber Formation ◽  
Structural Development ◽  
Thermotropic Liquid Crystalline Polymer

High-speed melt spinning of thermotropic liquid crystalline polymer (TLCP) resin composed of 4-hydroxybenzoic acid (HBA) and 2-hydroxy-6-napthoic acid (HNA) monomers in a molar ratio of 73/27 was conducted to investigate the characteristic structure development of the fibers under industrial spinning conditions, and the obtained as-spun TLCP fibers were analyzed in detail. The tensile strength and modulus of the fibers increased with shear rate in nozzle hole, draft in spin-line and spinning temperature and exhibited the high values of approximately 1.1 and 63 GPa, respectively, comparable to those of industrial as-spun TLCP fibers, at a shear rate of 70,000 s−1 and a draft of 25. X-ray diffraction demonstrated that the mechanical properties of the fibers increased with the crystalline orientation factor (fc) and the fractions of highly oriented crystalline and non-crystalline anisotropic phases. The results of structure analysis indicated that a characteristic skin–core structure developed at high drafts (i.e., spinning velocity) and low spinning temperatures, which contributed to weakening the mechanical properties of the TLCP fibers. It is supposed that this heterogeneous structure in the cross-section of the fibers was induced by differences in the cooling rates of the skin and core of the fiber in the spin-line.

Morphology and properties of compatibilized ternary blends (nylon 6/a thermotropic liquid crystalline polymer/a functionalized polypropylene) processed under different conditions

Polymer ◽  
1999 ◽  
Vol 40 (16) ◽  
pp. 4441-4450 ◽  
Author(s):  
Yongsok Seo ◽  
Byeongyeol Kim ◽  
Soonjong Kwak ◽  
Kwang Ung Kim ◽  
Jinhwan Kim
Keyword(s):  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Nylon 6 ◽  
Ternary Blends ◽  
Thermotropic Liquid Crystalline Polymer

Molecular dynamics of thermotropic liquid-crystalline polymer: Polydecamethyleneterephthaloyl-bis-4-oxybenzoate using2H NMR spectroscopy

1990 ◽  
Vol 1 (3) ◽  
pp. 525-531
Author(s):  
V. M. Kapralova ◽  
V. V. Zuev ◽  
A. I. Koltsov ◽  
S. S. Skorokhodov ◽  
A. S. Khachaturov
Keyword(s):  
Molecular Dynamics ◽  
Nmr Spectroscopy ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Thermotropic Liquid Crystalline Polymer

Properties of Thermotropic Liquid Crystalline Polymer Blends

2019 ◽  
pp. 331-364
Author(s):  
Tsung-Tang Hsieh ◽  
Carlos Tiu ◽  
George P. Simon ◽  
Stuart R. Andrews ◽  
Graham Williams ◽  
...  
Keyword(s):  
Polymer Blends ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Thermotropic Liquid Crystalline Polymer

Shear and extensional flow of a thermotropic liquid crystalline polymer

1996 ◽  
Vol 36 (1) ◽  
pp. 23-33 ◽  
Author(s):  
A. P. Pickles ◽  
A. G. Gibson
Keyword(s):  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Extensional Flow ◽  
Crystalline Polymer ◽  
Thermotropic Liquid Crystalline Polymer

Application of thermotropic liquid crystalline polymer reinforced acrylonitrile butadiene styrene in fused filament fabrication

2019 ◽  
Vol 29 ◽  
pp. 100813 ◽  
Author(s):  
Mubashir Q. Ansari ◽  
Alec Redmann ◽  
Tim A. Osswald ◽  
Michael J. Bortner ◽  
Donald G. Baird
Keyword(s):  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Acrylonitrile Butadiene Styrene ◽  
Crystalline Polymer ◽  
Fused Filament Fabrication ◽  
Thermotropic Liquid Crystalline Polymer ◽  
Butadiene Styrene
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