Double defects-induced elastic wave coupling and energy localization in a phononic crystal

This study aims to investigate elastic wave localization that leverages defect band splitting in a phononic crystal with double defects through in-depth analysis of comparison of numerical and experimental results. When more than one defect is created inside a phononic crystal, these defects can interact with each other, resulting in a distinctive physical phenomenon from a single defect case: defect band splitting. For a phononic crystal consisting of circular-hole type unit cells in a thin aluminum plate, under A0 (the lowest antisymmetric) Lamb waves, both numerical simulations and experiments successfully confirm the defect band splitting phenomenon via frequency response functions for the out-of-plane displacement calculated/measured at the double defects within a finite distance. Furthermore, experimental visualization of in-phase and out-of-phase defect mode shapes at each frequency of the split defect bands is achieved and found to be in excellent agreement with the simulated results. Different inter-distance combinations of the double defects reveal that the degree of the defect band splitting decreases with the increasing distance due to weaker coupling between the defects. This work may shed light on engineering applications of a multiple-defect-introduced phononic crystal, including broadband energy harvesting, frequency detectors, and elastic wireless power transfer.

Manipulation of hot carrier cooling dynamics in two-dimensional Dion–Jacobson hybrid perovskites via Rashba band splitting

Hot-carrier cooling processes of perovskite materials are typically described by a single parabolic band model that includes the effects of carrier-phonon scattering, hot phonon bottleneck, and Auger heating. However, little is known (if anything) about the cooling processes in which the spin-degenerate parabolic band splits into two spin-polarized bands, i.e., the Rashba band splitting effect. Here, we investigated the hot-carrier cooling processes for two slightly different compositions of two-dimensional Dion–Jacobson hybrid perovskites, namely, (3AMP)PbI4 and (4AMP)PbI4 (3AMP = 3-(aminomethyl)piperidinium; 4AMP = 4-(aminomethyl)piperidinium), using a combination of ultrafast transient absorption spectroscopy and first-principles calculations. In (4AMP)PbI4, upon Rashba band splitting, the spin-dependent scattering of hot electrons is responsible for accelerating hot-carrier cooling at longer delays. Importantly, the hot-carrier cooling of (4AMP)PbI4 can be extended by manipulating the spin state of the hot carriers. Our findings suggest a new approach for prolonging hot-carrier cooling in hybrid perovskites, which is conducive to further improving the performance of hot-carrier-based optoelectronic and spintronic devices.