Mesoporous Silica Sphere−Polysulfone Mixed Matrix Membranes for Gas Separation

Langmuir ◽  
2009 ◽  
Vol 25 (10) ◽  
pp. 5903-5909 ◽  
Author(s):  
Beatriz Zornoza ◽  
Silvia Irusta ◽  
Carlos Téllez ◽  
Joaquín Coronas
Keyword(s):  
Mesoporous Silica ◽  
Gas Separation ◽  
Silica Sphere ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Mesoporous Silica Sphere ◽  
Matrix Membranes

Mixed matrix membranes comprising glassy polymers and dispersed mesoporous silica spheres for gas separation

2011 ◽  
Vol 368 (1-2) ◽  
pp. 100-109 ◽  
Author(s):  
Beatriz Zornoza ◽  
Carlos Téllez ◽  
Joaquín Coronas
Keyword(s):  
Mesoporous Silica ◽  
Gas Separation ◽  
Glassy Polymers ◽  
Mixed Matrix Membranes ◽  
Silica Spheres ◽  
Mixed Matrix ◽  
Mesoporous Silica Spheres ◽  
Matrix Membranes

Investigation of the silica pore size effect on the performance of polysulfone (PSf) mixed matrix membranes (MMMs) for gas separation

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Gholamhossein Vatankhah ◽  
Babak Aminshahidy
Keyword(s):  
Mesoporous Silica ◽  
Pore Size ◽  
Gas Separation ◽  
Gas Permeation ◽  
Mixed Matrix Membranes ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Small Pore ◽  
Mcm 41 ◽  
Matrix Membranes

Abstract MCM-41 and SBA-15 mesoporous silica materials with different pore sizes (3.08 nm for small pore size MCM-41 (P 1), 5.89 nm for medium pore size SBA-15 (P 2), and 7.81 nm for large pore size SBA-15 (P 3)) were synthesized by the hydrothermal method and then functionalized with 3-aminopropyltrietoxysilane by postsynthesis treatments. Next, polysulfone-mesoporous silica mixed matrix membranes (MMMs) were prepared by the solution casting method. The obtained materials and MMMs were characterized by various techniques including X-ray diffraction, scanning electron microscopy, and N2 adsorption-desorption, and Brunauer-Emmett-Teller method to examine the crystallinity, morphology, and particle size, pore volume, specific surface area, and pore size distribution, respectively. Finally, the gas permeation rates of prepared MMMs were measured in 8 bar and 25 °C and the effect of pore size of modified and unmodified mesoporous silica on the gas separation performance of these MMMs were investigated. The experimental results indicate that the carbon dioxide (CO2) and methane (CH4) permeability and CO2/CH4 selectivity were increased with an enhancement in the particle pore size.

Mixed matrix membranes based on hyperbranched polyimide and mesoporous silica for gas separation

2011 ◽  
Vol 34 (1-3) ◽  
pp. 211-215 ◽  
Author(s):  
Petr Sysel ◽  
Evgenia Minko ◽  
Michal Hauf ◽  
Karel Friess ◽  
Vladimir Hynek ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Matrix Membranes

Preparation of polybenzimidazole‐based mixed matrix membranes containing modified‐COK ‐12 mesoporous silica and evaluation of the mixed‐gas separation performance

2022 ◽  
Author(s):  
Griselda Castruita‐de León ◽  
Ángel de Jesús Montes‐Luna ◽  
Claudia Y. Yeverino‐Miranda ◽  
Germán Alvarado‐Tenorio ◽  
Héctor Iván Meléndez‐Ortiz ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Mixed Gas ◽  
Gas Separation Performance ◽  
Matrix Membranes

Effect of new metal–organic framework (zeolitic imidazolate framework [ZIF-12]) in mixed matrix membranes on structure, morphology, and gas separation properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Mehtap Safak Boroglu ◽  
Ismail Boz ◽  
Busra Kaya
Keyword(s):  
Gas Separation ◽  
Gas Permeability ◽  
Metal Organic Framework ◽  
Thermomechanical Analysis ◽  
Variable Pressure ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Sem Images ◽  
Zeolitic Imidazolate Framework ◽  
Matrix Membranes

Abstract In our study, the synthesis of zeolitic imidazolate framework (ZIF-12) crystals and the preparation of mixed matrix membranes (MMMs) with various ZIF-12 loadings were targeted. The characterization of ZIF-12 and MMMs were carried out by Fourier transform infrared spectroscopy analysis, thermogravimetric analysis, scanning electron microscopy (SEM), and thermomechanical analysis. The performance of MMMs was measured by the ability of binary gas separation. Commercial polyetherimide (PEI-Ultem® 1000) polymer was used as the polymer matrix. The solution casting method was utilized to obtain dense MMMs. In the SEM images of ZIF-12 particles, the particles with a rhombic dodecahedron structure were identified. From SEM images, it was observed that the distribution of ZIF-12 particles in the MMMs was homogeneous and no agglomeration was present. Gas permeability experiments of MMMs were measured for H2, CO2, and CH4 gases at steady state, at 4 bar and 35 °C by constant volume-variable pressure method. PEI/ZIF-12-30 wt% MMM exhibited high permeability and ideal selectivity values for H2/CH4 and CO2/CH4 were P H 2 / CH 4 = 331.41 ${P}_{{\text{H}}_{2}/{\text{CH}}_{4}}=331.41$ and P CO 2 / CH 4 = 53.75 ${P}_{{\text{CO}}_{2}/{\text{CH}}_{4}}=53.75$ gas pair.

Investigation of cellulose acetate/gamma‐cyclodextrin MOF based mixed matrix membranes for CO 2 /CH 4 gas separation

2021 ◽  
Vol 11 (2) ◽  
pp. 313-330
Author(s):  
Ovaid Mehmood ◽  
Sarah Farrukh ◽  
Arshad Hussain ◽  
Mohammad Younas ◽  
Zarrar Salahuddin ◽  
...  
Keyword(s):  
Cellulose Acetate ◽  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Gamma Cyclodextrin ◽  
Matrix Membranes

scholarly journals Carbon nanotube-based mixed-matrix membranes with supramolecularly engineered interface for enhanced gas separation performance

2020 ◽  
Vol 598 ◽  
pp. 117794 ◽  
Author(s):  
Qinnan Zhang ◽  
Si Li ◽  
Ceming Wang ◽  
Hsueh-Chia Chang ◽  
Ruilan Guo
Keyword(s):  
Carbon Nanotube ◽  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Gas Separation Performance ◽  
Matrix Membranes

Fabrication of Homogenous Polymer-Zeolite Nanocomposites as Mixed-Matrix Membranes for Gas Separation

2012 ◽  
Vol 35 (5) ◽  
pp. 885-892 ◽  
Author(s):  
H. Karkhanechi ◽  
H. Kazemian ◽  
H. Nazockdast ◽  
M. R. Mozdianfard ◽  
S. M. Bidoki
Keyword(s):  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Matrix Membranes

Mixed matrix membranes comprising MOFs and porous silicate fillers prepared via spin coating for gas separation

2014 ◽  
Vol 107 ◽  
pp. 66-75 ◽  
Author(s):  
Philipp Burmann ◽  
Beatriz Zornoza ◽  
Carlos Téllez ◽  
Joaquín Coronas
Keyword(s):  
Gas Separation ◽  
Spin Coating ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Porous Silicate ◽  
Matrix Membranes
Sign in / Sign up

Export Citation Format

Share Document