Preparation of Nanocomposite Poly(allylamine)−Poly(ethylene glycol) Thin Films Using Michael Addition

Langmuir ◽  
2000 ◽  
Vol 16 (8) ◽  
pp. 4052-4054 ◽  
Author(s):  
Ryan J. Russell ◽  
Kaushik Sirkar ◽  
Michael V. Pishko
Keyword(s):  
Thin Films ◽  
Ethylene Glycol ◽  
Michael Addition ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene

FABRICATION OF QCM TYPE SMOTHER DETECTION SENSOR BY PLASMA POLYMERIZING SnOx ORGANIC-LIKE FILMS AND SPIN COATING WITH POLY ETHYLENE GLYCOL

2012 ◽  
Vol 24 (02) ◽  
pp. 179-183
Author(s):  
Ko-Shao Chen ◽  
Shu-Chuan Liao ◽  
Hsin-Ming Wu ◽  
Yu-Chia Tsao ◽  
Hong-Ru Lin
Keyword(s):  
Thin Films ◽  
Ethylene Glycol ◽  
Spin Coating ◽  
Room Temperature ◽  
Plasma Deposition ◽  
Post Treatment ◽  
Detection Sensitivity ◽  
Poly Ethylene Glycol ◽  
Frequency Drop ◽  
Poly Ethylene

Quartz crystal microbalances (QCM) are transducers for chemical and biochemical sensing. The oscillation frequency of QCM is affected by the adsorbed mass on the surface. In this work, a new room temperature type gas sensor device fabricated by organically hybridized plasma deposition of tetramethyltin (TMT) and oxygen. Post treatment with poly ethylene glycol (PEG) was developed to detect the ambient environmental smother, and the responses of the fabricated sensor to smother detection were investigated. SnO x C y thin films on the sensor electrodes were obtained by plasma deposition from TMT and O 2 gas mixtures at room temperature. A spin coating post treatment on the SnO x C y thin films turns into hydrophilic property. The response of the QCM sensor to the smother detection shows a frequency drop during the burning of candle and has good detection sensitivity with Δf equal to 2400 Hz. Repeated smother testing with the QCM type smother detection sensor also indicates the stability of the fabricated sensor.

Hydroxy-Assisted Catalyst-Free Michael Addition—Dehydroxylation of Baylis—Hillman Adducts in Poly(ethylene glycol).

ChemInform ◽  
2006 ◽  
Vol 37 (31) ◽  
Author(s):  
S. Chandrasekhar ◽  
B. Saritha ◽  
V. Jagadeswar ◽  
Ch. Narsihmulu ◽  
Dolly Vijay ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Michael Addition ◽  
Poly Ethylene Glycol ◽  
Catalyst Free ◽  
Poly Ethylene

Effects of poly(ethylene glycol) additive molecular weight on the microstructure and properties of sol-gel-derived lead zirconate titanate thin films

2003 ◽  
Vol 18 (3) ◽  
pp. 737-741 ◽  
Author(s):  
Shuhui Yu ◽  
Kui Yao ◽  
Santiranjan Shannigrahi ◽  
Francis Tay Eng Hock
Keyword(s):  
Thin Films ◽  
Molecular Weight ◽  
Ethylene Glycol ◽  
Lead Zirconate Titanate ◽  
Sol Gel ◽  
Lead Zirconate ◽  
Poly Ethylene Glycol ◽  
Molecular Weights ◽  
Zirconate Titanate ◽  
Poly Ethylene

Poly(ethylene glycol) (PEG) additives with different molecular weights were used to modify sol-gel precursor solutions for preparing lead zirconate titanate (PZT) thin films. The morphology, crystalline structure, and mechanical and electrical properties of the films were characterized. The relationship between the characteristics of the films and the molecular weight of PEG was investigated. It was observed that the PEG eliminated cracking of the films during multiple pyrolysis treatments. However, with the increase of the PEG molecular weight, the films became less dense, which led to decreased Young's modulus and dielectric constant and increased coercive field. Our experiments showed that films prepared from sols modified by PEG with a molecular weight of 200 exhibited a dense morphology and excellent mechanical and electric properties without cracking.

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