Intramolecular Form Factor in Dense Polymer Systems:  Systematic Deviations from the Debye Formula

Oriented overgrowth of polymer materials onto ionic crystals is well known and recently it was demonstrated that this epitaxial crystallisation can also occur in polymer/polymer systems, under certain conditions. The morphologies and the resulting physical properties of such systems will be presented, especially the influence of epitaxial interfaces on the adhesion of polymer laminates and the mechanical properties of epitaxially crystallized sandwiched layers.Materials used were polyethylene, PE, Lupolen 6021 DX (HDPE) and 1810 D (LDPE) from BASF AG; polypropylene, PP, (PPN) provided by Höchst AG and polybutene-1, PB-1, Vestolen BT from Chemische Werke Hüls. Thin oriented films were prepared according to the method of Petermann and Gohil, by winding up two different polymer films from two separately heated glass-plates simultaneously with the help of a motor driven cylinder. One double layer was used for TEM investigations, while about 1000 sandwiched layers were taken for mechanical tests.

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The effect of temperature on high-resolution TEM image contrast

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100139573 ◽

1995 ◽

Vol 53 ◽

pp. 640-641

Author(s):

T. Geipel ◽

W. Mader ◽

P. Pirouz

Keyword(s):

Form Factor ◽

Inelastic Scattering ◽

Accurate Method ◽

Waller Factor ◽

Effect Of Temperature ◽

Specimen Thickness ◽

Influence Of Temperature ◽

Debye Waller Factor ◽

Influence Of Temperature On ◽

Atomic Form Factor

Temperature affects both elastic and inelastic scattering of electrons in a crystal. The Debye-Waller factor, B, describes the influence of temperature on the elastic scattering of electrons, whereas the imaginary part of the (complex) atomic form factor, fc = fr + ifi, describes the influence of temperature on the inelastic scattering of electrons (i.e. absorption). In HRTEM simulations, two possible ways to include absorption are: (i) an approximate method in which absorption is described by a phenomenological constant, μ, i.e. fi; - μfr, with the real part of the atomic form factor, fr, obtained from Hartree-Fock calculations, (ii) a more accurate method in which the absorptive components, fi of the atomic form factor are explicitly calculated. In this contribution, the inclusion of both the Debye-Waller factor and absorption on HRTEM images of a (Oll)-oriented GaAs crystal are presented (using the EMS software.Fig. 1 shows the the amplitudes and phases of the dominant 111 beams as a function of the specimen thickness, t, for the cases when μ = 0 (i.e. no absorption, solid line) and μ = 0.1 (with absorption, dashed line).

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Approaches for TEM imaging of cavitation in toughened nylon

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100153737 ◽

1989 ◽

Vol 47 ◽

pp. 352-353

Author(s):

Barbara A. Wood

Keyword(s):

Morphological Characteristics ◽

Structure Property ◽

Polymer Systems ◽

Selective Staining ◽

Structure Property Relationships ◽

Rubber Toughened ◽

Shear Yield ◽

Controversial Topic ◽

Selection Of ◽

Diamond Knife

A controversial topic in the study of structure-property relationships of toughened polymer systems is the internal cavitation of toughener particles resulting from damage on impact or tensile deformation.Detailed observations of the influence of morphological characteristics such as particle size distribution on deformation mechanisms such as shear yield and cavitation could provide valuable guidance for selection of processing conditions, but TEM observation of damaged zones presents some experimental difficulties.Previously published TEM images of impact fractured toughened nylon show holes but contrast between matrix and toughener is lacking; other systems investigated have clearly shown cavitated impact modifier particles. In rubber toughened nylon, the physical characteristics of cavitated material differ from undamaged material to the extent that sectioning of heavily damaged regions by cryoultramicrotomy with a diamond knife results in sections of greater than optimum thickness (Figure 1). The detailed morphology is obscured despite selective staining of the rubber phase using the ruthenium trichloride route to ruthenium tetroxide.

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