Synthesis, characterization and electrochemical behavior of mononuclear, binuclear nickel(II) and heterobinuclear zinc(II)nickel(II) complexes derived from novel macrobicyclic tricompartmental ligands: kinetics of the catalytic hydrolysis of 4-nitrophenyl phosphate by the complexes

Two novel dodecyliminodiacetate nickel (II) and copper (II) complexes were synthesized and characterized, and these complexes were used as mimic hydrolytic in catalytic hydrolysis of bis (p-nitrophenyl) phosphate (BNPP). The analysis of specific absorption spectra of the hydrolytic reaction systems indicated that the catalytic hydrolysis involved the key intermediates formed by BNPP with nickel (II) complexes. The kinetic parameter of BNPP catalytic hydrolysis has been calculated and the temperature effect of reaction system and structure effect of the complexes on the rate of BNPP hydrolysis catalyzed by the complexes have been discussed.

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Mechanism of Intramolecular Nucleophilic Substitution in the Catalytic Hydrolysis of Bis(4-Nitrophenyl) Phosphate Ester in a Metallomicelle

Progress in Reaction Kinetics and Mechanism ◽

10.3184/146867806x207627 ◽

2006 ◽

Vol 31 (4) ◽

pp. 189-204 ◽

Cited By ~ 13

Author(s):

Li Jun ◽

Sang Xue-mei ◽

Wan Min ◽

Chen Guo-xu ◽

Xie Jia-qing

Keyword(s):

Nucleophilic Substitution ◽

Phosphate Ester ◽

Catalytic Hydrolysis ◽

Intramolecular Nucleophilic Substitution ◽

Nitrophenyl Phosphate ◽

Hydrolysis Of

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Catalytic hydrolysis of waste residue from the melamine process and the kinetics of melamine hydrolysis in NaOH solution

Reaction Kinetics Mechanisms and Catalysis ◽

10.1007/s11144-016-1014-9 ◽

2016 ◽

Vol 118 (2) ◽

pp. 377-391 ◽

Cited By ~ 1

Author(s):

Hai Gong ◽

Shengwei Tang ◽

Tao Zhang

Keyword(s):

Catalytic Hydrolysis ◽

Naoh Solution ◽

Kinetics Of ◽

Hydrolysis Of

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The Study of the Hydrolysis of the Phosphate Diester Catalyzed by an Anion Metallomicelle of Ce3+-Diethylenetriamine

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.554-556.353 ◽

2012 ◽

Vol 554-556 ◽

pp. 353-356

Author(s):

Shu Lan Cai ◽

Fa Mei Feng ◽

Tao Wang ◽

Xiu Lan Zhang

Keyword(s):

Critical Micelle Concentration ◽

High Activity ◽

Catalytic Efficiency ◽

Active Species ◽

Phosphate Ester ◽

Catalytic Hydrolysis ◽

Phosphate Diester ◽

Nitrophenyl Phosphate ◽

Hydrolysis Of ◽

Lauroyl Sarcosinate

The catalytic hydrolysis of Bis(p-nitrophenyl) phosphate ester (BNPP) in the metallomicelle made up of Ce3+-diethylenetriamine and LSS (N-lauroyl sarcosinate) was investigated by UV/VIS method. The effect of the catalytic efficiency and stability of the system was studied under the different conditions. The results indicated that the catalytic system exhibited high activity, stability and reproducibility in the BNPP catalytic hydrolysis under proper proportion of Ce3+ion and diethylenetriamine, pH and temperature when the concentration of LSS is higher than its CMC (critical micelle concentration). The results also showed that the active species is the complex made up of Ce3+ion and diethylenetriamine.

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Hydrolysis of phosphate diester catalysed by transition metal complexes of a salicylaldimine Schiff base bearing dibenzo-18-crown-6

Journal of Chemical Research ◽

10.3184/0308234054497137 ◽

2005 ◽

Vol 2005 (2) ◽

pp. 130-134 ◽

Cited By ~ 5

Author(s):

Jin Zhang ◽

Jia-qing Xie ◽

Ying Tang ◽

Jun Li ◽

Jian-zhang Li ◽

...

Keyword(s):

Mathematical Model ◽

Schiff Base ◽

Crown Ether ◽

Transition Metal Complexes ◽

Catalytic Hydrolysis ◽

Reaction Conditions ◽

Reaction Systems ◽

Phosphate Diester ◽

Nitrophenyl Phosphate ◽

Hydrolysis Of

A new crowned Schiff base ligand and its cobalt(II) and manganese(III) complexes were synthesised and characterised. These complexes were used to catalyse the hydrolysis of bis(4-nitrophenyl) phosphate (BNPP) in order to mimic the action of hydrolytic metalloenzymes. The kinetics and the mechanism of the titled reactions were investigated. The change of the characteristic ultraviolet spectra of the reaction systems was also analysed. A kinetic mathematical model of BNPP cleavage catalysed by the complexes is proposed. The function of the crown ether ring and the effects of the reaction conditions on the catalytic hydrolysis of BNPP are discussed.

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