Coupled modeling of biospheric and chemical weathering processes at the continental scale

2010 ◽  
Vol 24 (2) ◽  
pp. n/a-n/a ◽  
Author(s):  
C. Roelandt ◽  
Y. Goddéris ◽  
M.-P. Bonnet ◽  
F. Sondag
2021 ◽  
Author(s):  
Philippe Negrel ◽  
Anna Ladenberger ◽  
Clemens Reimann ◽  
Alecos Demetriades ◽  
Manfred Birke ◽  
...  

<p>Collection of agricultural soil samples in Europe (0–20 cm, 33 countries, 5.6 million km<sup>2</sup>) during the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) continental-scale project allowed the study of geochemical behaviour of major elements during weathering (SiO<sub>2</sub>, TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, Fe<sub>2</sub>O<sub>3</sub>, MgO, CaO, Na<sub>2</sub>O, K<sub>2</sub>O, P<sub>2</sub>O<sub>5</sub>) using their total concentrations (XRF data). The chemical composition of soil represents to a large extent the primary mineralogy of the source bedrock, the effects of pre- and post-depositional weathering and element mobility, either by leaching or mineral sorting with the addition of formation of secondary products such as clays.</p><p>Bulk geochemistry is used to calculate a set of weathering indices such as chemical index of alteration CIA, reductive and oxidative mafic index of alteration MIA, the change in mass balance t (calculation relative to immobile Nb) for soil derived from silicate parent materials defined as granite, gneiss and schist at the European continental-scale. Silicate minerals of soil parent materials can be either very resistant to weathering or very soluble and export of elements in dissolved form and precipitation of secondary phases can occur at a large scale. Either way, they leave a strong chemical signature in derived soil, which can be quantified and classified with help of geochemical indices that are useful tools to evaluate chemical weathering trends. Weathering indices and gain-loss mass transfer coefficients were applied to agricultural soil to provide an insight into the weathering processes affecting three silicate parent rocks and their impact on soil development at the European scale. Distinct chemical composition and weathering patterns has been evidenced in silicate derived soil. The interpretation of geographical distribution of soil types with silicate substrate allows better understanding of soil nutritional status, metal enrichments, degradation mechanisms under various climate conditions.</p>


2006 ◽  
Vol 235 (1-2) ◽  
pp. 76-94 ◽  
Author(s):  
J.P. Bernal ◽  
S.M. Eggins ◽  
M.T. McCulloch ◽  
R. Grün ◽  
R.A. Eggleton

2020 ◽  
Vol 118 (2) ◽  
pp. e2007051117
Author(s):  
Eric C. Dunham ◽  
John E. Dore ◽  
Mark L. Skidmore ◽  
Eric E. Roden ◽  
Eric S. Boyd

Life in environments devoid of photosynthesis, such as on early Earth or in contemporary dark subsurface ecosystems, is supported by chemical energy. How, when, and where chemical nutrients released from the geosphere fuel chemosynthetic biospheres is fundamental to understanding the distribution and diversity of life, both today and in the geologic past. Hydrogen (H2) is a potent reductant that can be generated when water interacts with reactive components of mineral surfaces such as silicate radicals and ferrous iron. Such reactive mineral surfaces are continually generated by physical comminution of bedrock by glaciers. Here, we show that dissolved H2 concentrations in meltwaters from an iron and silicate mineral-rich basaltic glacial catchment were an order of magnitude higher than those from a carbonate-dominated catchment. Consistent with higher H2 abundance, sediment microbial communities from the basaltic catchment exhibited significantly shorter lag times and faster rates of net H2 oxidation and dark carbon dioxide (CO2) fixation than those from the carbonate catchment, indicating adaptation to use H2 as a reductant in basaltic catchments. An enrichment culture of basaltic sediments provided with H2, CO2, and ferric iron produced a chemolithoautotrophic population related to Rhodoferax ferrireducens with a metabolism previously thought to be restricted to (hyper)thermophiles and acidophiles. These findings point to the importance of physical and chemical weathering processes in generating nutrients that support chemosynthetic primary production. Furthermore, they show that differences in bedrock mineral composition can influence the supplies of nutrients like H2 and, in turn, the diversity, abundance, and activity of microbial inhabitants.


Minerals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 760
Author(s):  
Melinda Hilton ◽  
Mandana Shaygan ◽  
Neil McIntyre ◽  
Thomas Baumgartl ◽  
Mansour Edraki

Coal mine spoils have the potential to create environmental impacts, such as salt load to surrounding environments, particularly when exposed to weathering processes. This study was conducted to understand the effect of physical and chemical weathering on the magnitude, rate, and dynamics of salt release from different coal mine spoils. Five spoil samples from three mines in Queensland were sieved to three different particle size fractions (<2 mm, 2–6 mm, and >6 mm). Two samples were dispersive spoils, and three samples were nondispersive spoils. The spoils were subjected to seven wet–dry cycles, where the samples were periodically leached with deionised water. The rate, magnitude, and dynamics of solutes released from spoils were spoil specific. One set of spoils did not show any evidence of weathering, but initially had higher accumulation of salts. In contrast, broad oxidative weathering occurred in another set of spoils; this led to acid generation and resulted in physical weathering, promoting adsorption–desorption and dissolution and, thus, a greater release of salts. This study indicated that the rate and magnitude of salt release decreased with increasing particle size. Nevertheless, when the spoil is dispersive, the degree of weathering manages salt release irrespective of initial particle size. This study revealed that the long-term salt release from spoils is not only governed by geochemistry, weathering degree, and particle size but also controlled by the water/rock ratio and hydrological conditions of spoils.


2020 ◽  
Vol 531 ◽  
pp. 119341
Author(s):  
Bei-Bei Chen ◽  
Si-Liang Li ◽  
Philip A.E. Pogge von Strandmann ◽  
Jian Sun ◽  
Jun Zhong ◽  
...  

2014 ◽  
Vol 2 (2) ◽  
pp. 383-401 ◽  
Author(s):  
B. W. Goodfellow ◽  
A. P. Stroeven ◽  
D. Fabel ◽  
O. Fredin ◽  
M.-H. Derron ◽  
...  

Abstract. Autochthonous blockfield mantles may indicate alpine surfaces that have not been glacially eroded. These surfaces may therefore serve as markers against which to determine Quaternary erosion volumes in adjacent glacially eroded sectors. To explore these potential utilities, chemical weathering features, erosion rates, and regolith residence durations of mountain blockfields are investigated in the northern Swedish Scandes. This is done, firstly, by assessing the intensity of regolith chemical weathering along altitudinal transects descending from three blockfield-mantled summits. Clay / silt ratios, secondary mineral assemblages, and imaging of chemical etching of primary mineral grains in fine matrix are each used for this purpose. Secondly, erosion rates and regolith residence durations of two of the summits are inferred from concentrations of in situ-produced cosmogenic 10Be and 26Al in quartz at the blockfield surfaces. An interpretative model is adopted that includes temporal variations in nuclide production rates through surface burial by glacial ice and glacial isostasy-induced elevation changes of the blockfield surfaces. Together, our data indicate that these blockfields are not derived from remnants of intensely weathered Neogene weathering profiles, as is commonly considered. Evidence for this interpretation includes minor chemical weathering in each of the three examined blockfields, despite consistent variability according to slope position. In addition, average erosion rates of ~16.2 and ~6.7 mm ka−1, calculated for the two blockfield-mantled summits, are low but of sufficient magnitude to remove present blockfield mantles, of up to a few metres in thickness, within a late Quaternary time frame. Hence, blockfield mantles appear to be replenished by regolith formation through, primarily physical, weathering processes that have operated during the Quaternary. The persistence of autochthonous blockfields over multiple glacial–interglacial cycles confirms their importance as key markers of surfaces that were not glacially eroded through, at least, the late Quaternary. However, presently blockfield-mantled surfaces may potentially be subjected to large spatial variations in erosion rates, and their Neogene regolith mantles may have been comprehensively eroded during the late Pliocene and early Pleistocene. Their role as markers by which to estimate glacial erosion volumes in surrounding landscape elements therefore remains uncertain.


2016 ◽  
Vol 4 (3) ◽  
pp. 675-684 ◽  
Author(s):  
Maarten Lupker ◽  
Christian France-Lanord ◽  
Bruno Lartiges

Abstract. Continental-scale chemical weathering budgets are commonly assessed based on the flux of dissolved elements carried by large rivers to the oceans. However, the interaction between sediments and seawater in estuaries can lead to additional cation exchange fluxes that have been very poorly constrained so far. We constrained the magnitude of cation exchange fluxes from the Ganga–Brahmaputra river system based on cation exchange capacity (CEC) measurements of riverine sediments. CEC values of sediments are variable throughout the river water column as a result of hydrological sorting of minerals with depth that control grain sizes and surface area. The average CEC of the integrated sediment load of the Ganga–Brahmaputra is estimated ca. 6.5 meq 100 g−1. The cationic charge of sediments in the river is dominated by bivalent ions Ca2+ (76 %) and Mg2+ (16 %) followed by monovalent K+ (6 %) and Na+ (2 %), and the relative proportion of these ions is constant among all samples and both rivers. Assuming a total exchange of exchangeable Ca2+ for marine Na+ yields a maximal additional Ca2+ flux of 28  ×  109 mol yr−1 of calcium to the ocean, which represents an increase of ca. 6 % of the actual river dissolved Ca2+ flux. In the more likely event that only a fraction of the adsorbed riverine Ca2+ is exchanged, not only for marine Na+ but also Mg2+ and K+, estuarine cation exchange for the Ganga–Brahmaputra is responsible for an additional Ca2+ flux of 23  ×  109 mol yr−1, while ca. 27  ×  109 mol yr−1 of Na+, 8  ×  109 mol yr−1 of Mg2+ and 4  ×  109 mol yr−1 of K+ are re-absorbed in the estuaries. This represents an additional riverine Ca2+ flux to the ocean of 5 % compared to the measured dissolved flux. About 15 % of the dissolved Na+ flux, 8 % of the dissolved K+ flux and 4 % of the Mg2+ are reabsorbed by the sediments in the estuaries. The impact of estuarine sediment–seawater cation exchange appears to be limited when evaluated in the context of the long-term carbon cycle and its main effect is the sequestration of a significant fraction of the riverine Na flux to the oceans. The limited exchange fluxes of the Ganga–Brahmaputra relate to the lower than average CEC of its sediment load that do not counterbalance the high sediment flux to the oceans. This can be attributed to the nature of Himalayan river sediment such as low proportion of clays and organic matter.


Clay Minerals ◽  
2014 ◽  
Vol 49 (5) ◽  
pp. 717-733 ◽  
Author(s):  
M. Setti ◽  
A. Lόpez-Galindo ◽  
M. Padoan ◽  
E. Garzanti

AbstractThe composition, morphology and crystal order of clay minerals in silt-sized sediments carried in suspensions from 25 major rivers across tropical southern Africa have been studied by X-ray diffractometry and scanning and transmission electron microscopy. Our goal was to determine the spatial variability of clay-mineral associations in diverse geological settings, and in climatic conditions ranging from humid Angola and Zambia to hyperarid Namibia and the Kalahari. Specific attention was paid to the micromorphology and chemical composition of smectite particles. The relative abundance of smectites, illite/mica, kaolinite and chlorite enabled identification of regions characterized by different physical and chemical processes: (1) negligible chemical weathering is documented in Namibia, where river muds mostly contain illite/mica or smectite derived from Damara metasedimentary or Etendeka volcanic rocks; (2) kaolinite documenting intense weathering, reaches a maximum in the Okavango, Kwando and Upper Zambezi, sourced in subequatorial Angola and Zambia; (3) suspended-load muds in the Limpopo and middle Zambezi catchments display intermediate features, with varied assemblages and smectite compositions reflecting diverse parent lithologies. Clay mineralogy and chemical composition are confirmed as a most effective tool to unravel present and past climatic conditions on a continental scale.


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