scholarly journals A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier

2016 ◽  
Vol 7 (1) ◽  
Author(s):  
Yvonne Rechkemmer ◽  
Frauke D. Breitgoff ◽  
Margarethe van der Meer ◽  
Mihail Atanasov ◽  
Michael Hakl ◽  
...  
Keyword(s):  
Energy Barrier ◽  
High Energy ◽  
High Energy Barrier ◽  
Very High Energy ◽  
Very High

Strong interactions at very high energy

1964 ◽  
Vol 82 (1) ◽  
pp. 3-81 ◽  
Author(s):  
Evgenii L. Feinberg ◽  
Dmitrii S. Chernavskii
Keyword(s):  
High Energy ◽  
Strong Interactions ◽  
Very High Energy ◽  
Very High

Enhancing the energy barrier and hysteresis temperature in two benchtop-stable Ho(III) single-ion magnets

2021 ◽  
Author(s):  
Kexin Jia ◽  
Xixi Meng ◽  
Mengmeng Wang ◽  
Xiaoshuang Gou ◽  
Yu-Xia Wang ◽  
...  
Keyword(s):  
Energy Barrier ◽  
High Energy ◽  
Halogen Anion ◽  
High Energy Barrier

The energy barrier and hysteresis temperature in two benchtop-stable D5h-symmetry HoIII single-ion magnets were significantly enhanced via the variation of halogen anion. The coexistence of high energy barrier of 418...

scholarly journals Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yanming Cai ◽  
Jiaju Fu ◽  
Yang Zhou ◽  
Yu-Chung Chang ◽  
Qianhao Min ◽  
...  
Keyword(s):  
Energy Barrier ◽  
Active Sites ◽  
Theoretical Calculations ◽  
High Energy ◽  
Single Atom ◽  
Faradaic Efficiency ◽  
High Energy Barrier ◽  
Catalytic Sites ◽  
Electron Reduction ◽  
First Time

AbstractSingle-atom catalysts (SACs) are promising candidates to catalyze electrochemical CO2 reduction (ECR) due to maximized atomic utilization. However, products are usually limited to CO instead of hydrocarbons or oxygenates due to unfavorable high energy barrier for further electron transfer on synthesized single atom catalytic sites. Here we report a novel partial-carbonization strategy to modify the electronic structures of center atoms on SACs for lowering the overall endothermic energy of key intermediates. A carbon-dots-based SAC margined with unique CuN2O2 sites was synthesized for the first time. The introduction of oxygen ligands brings remarkably high Faradaic efficiency (78%) and selectivity (99% of ECR products) for electrochemical converting CO2 to CH4 with current density of 40 mA·cm-2 in aqueous electrolytes, surpassing most reported SACs which stop at two-electron reduction. Theoretical calculations further revealed that the high selectivity and activity on CuN2O2 active sites are due to the proper elevated CH4 and H2 energy barrier and fine-tuned electronic structure of Cu active sites.

Slow magnetic relaxation in dinuclear dysprosium and holmium phenoxide bridged complexes: a Dy2 single molecule magnet with a high energy barrier

2021 ◽  
Author(s):  
Matilde Fondo ◽  
Julio Corredoira-Vázquez ◽  
Ana M. Garcia-Deibe ◽  
Jesus Sanmartin Matalobos ◽  
Silvia Gómez-Coca ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
High Energy ◽  
Single Molecule Magnet ◽  
High Energy Barrier ◽  
Slow Magnetic Relaxation

Dinuclear [M(H3L1,2,4)]2 (M = Dy, Dy2; M = Ho, Ho2) complexes were isolated from an heptadentate aminophenol ligand. The crystal structures of Dy2·2THF, and the pyridine adducts Dy2·2Py and Ho2·2Py,...

scholarly journals Focused VHEE (very high energy electron) beams and dose delivery for radiotherapy applications

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
L. Whitmore ◽  
R. I. Mackay ◽  
M. van Herk ◽  
J. K. Jones ◽  
R. M. Jones
Keyword(s):  
Electron Beams ◽  
Focal Point ◽  
External Beam Radiotherapy ◽  
High Energy ◽  
Energy Electron ◽  
High Energy Electron ◽  
Dose Delivery ◽  
Entrance Dose ◽  
Very High Energy ◽  
Very High

AbstractThis paper presents the first demonstration of deeply penetrating dose delivery using focused very high energy electron (VHEE) beams using quadrupole magnets in Monte Carlo simulations. We show that the focal point is readily modified by linearly changing the quadrupole magnet strength only. We also present a weighted sum of focused electron beams to form a spread-out electron peak (SOEP) over a target region. This has a significantly reduced entrance dose compared to a proton-based spread-out Bragg peak (SOBP). Very high energy electron (VHEE) beams are an exciting prospect in external beam radiotherapy. VHEEs are less sensitive to inhomogeneities than proton and photon beams, have a deep dose reach and could potentially be used to deliver FLASH radiotherapy. The dose distributions of unfocused VHEE produce high entrance and exit doses compared to other radiotherapy modalities unless focusing is employed, and in this case the entrance dose is considerably improved over existing radiations. We have investigated both symmetric and asymmetric focusing as well as focusing with a range of beam energies.

Very high energy nucleus-nucleus collisions and multi-chain model

1981 ◽  
Vol 8 (3) ◽  
pp. 205-213 ◽  
Author(s):  
Kisei Kinoshita ◽  
Akira Minaka ◽  
Hiroyuki Sumiyoshi
Keyword(s):  
High Energy ◽  
Chain Model ◽  
Very High Energy ◽  
Very High

scholarly journals Fermi LARGE AREA TELESCOPE DETECTION OF TWO VERY-HIGH-ENERGY ( E > 100 GeV) γ-RAY PHOTONS FROM THE z = 1.1 BLAZAR PKS 0426–380

2013 ◽  
Vol 777 (1) ◽  
pp. L18 ◽  
Author(s):  
Y. T. Tanaka ◽  
C. C. Cheung ◽  
Y. Inoue ◽  
Ł. Stawarz ◽  
M. Ajello ◽  
...  
Keyword(s):  
High Energy ◽  
Large Area ◽  
Very High Energy ◽  
Γ Ray ◽  
Very High

First principle simulation on oxidation mechanism of diethyl ether by nitrogen dioxide

2015 ◽  
Vol 14 (03) ◽  
pp. 1550020 ◽  
Author(s):  
Yuan Yuan ◽  
Wei Hu ◽  
Xuhui Chi ◽  
Cuihua Li ◽  
Dayong Gui ◽  
...  
Keyword(s):  
Diethyl Ether ◽  
Energy Barrier ◽  
Density Functional ◽  
Oxidation Process ◽  
Oxidation Mechanism ◽  
High Energy ◽  
First Principle ◽  
Functional Theory ◽  
The Third ◽  
High Energy Barrier

The oxidation mechanism of diethyl ethers by NO2was carried out using density functional theory (DFT) at the B3LYP/6-31+G (d, p) level. The oxidation process of ether follows four steps. First, the diethyl ether reacts with NO2to produce HNO2and diethyl ether radical with an energy barrier of 20.62 kcal ⋅ mol-1. Then, the diethyl ether radical formed in the first step directly combines with NO2to form CH3CH ( ONO ) OCH2CH3. In the third step, the CH3CH ( ONO ) OCH2CH3was further decomposed into the CH3CH2ONO and CH3CHO with a moderately high energy barrier of 32.87 kcal ⋅ mol-1. Finally, the CH3CH2ONO continues to react with NO2to yield CH3CHO , HNO2and NO with an energy barrier of 28.13 kcal ⋅ mol-1. The calculated oxidation mechanism agrees well with Nishiguchi and Okamoto's experiment and proposal.

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