scholarly journals Biogenically induced bedded chert formation in the alkaline palaeo-lake of the Green River Formation

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ryusei Kuma ◽  
Hitoshi Hasegawa ◽  
Koshi Yamamoto ◽  
Hidekazu Yoshida ◽  
Jessica H. Whiteside ◽  
...  

Abstract Rhythmically bedded cherts are observed in both pelagic marine and lacustrine deposits, but the formation mechanism in the latter remains highly uncertain. Our study of alternating chert–dolomite beds in the Eocene Green River Formation, Utah, USA reveals dense accumulations of organic-matter spheres (30–50 μm diameter) of probable algal cyst origin in the chert layers, and centennial- to millennial-scale periodicities in chert layer deposition. A positive correlation between the degree of degradation of the organic spheres and Si distribution implies decomposition of algal organic matter lead to precipitation of lacustrine chert. As both alkalinity and dissolved silica were likely high in the palaeo-lake waters of the Green River Formation, we hypothesize that decomposition of algal organic matter lowered the pH of sediment pore waters and caused silica precipitation. We propose a formation model in which the initial abundance of algal organic matter in sediment varies with productivity at the lake surface, and the decomposition of this algal matter controls the extent of silica precipitation in sediment. The formation of rhythmically bedded chert–dolomite may be linked to centennial- to millennial-scale climatic/environmental factors that modulate algal productivity, which are possibly tied to solar activity cycles known to have similar periodicities.

2017 ◽  
Author(s):  
Megan Rohrssen ◽  
◽  
Gordon N. Inglis ◽  
Gordon N. Inglis ◽  
Alice Charteris ◽  
...  

Radiocarbon ◽  
1999 ◽  
Vol 41 (3) ◽  
pp. 271-286 ◽  
Author(s):  
Elisabeth Gibert ◽  
Yves Travi ◽  
Marc Massault ◽  
Tesfaye Chernet ◽  
Florent Barbecot ◽  
...  

We studied a 12.6-m-long sequence from Lake Abiyata (Central Ethiopia) to establish a reliable and accurate chronology for use in global paleoclimatic reconstructions. The 26 accelerator mass spectrometry radiocarbon (AMS 14C) ages, performed on carbonates and organic matter, define 2 parallel chronologies, representing the complete Holocene period. However, these chronologies show a significant discrepancy from 500 to 900 BP in depth; ages obtained on carbonates were always older than those on organic matter. The hydrogeological and geochemical behavior of the Lake Abiyata basin has shed light on this discrepancy. We found that the carbonate crystallization is due mainly to the mixing of lake waters with groundwaters from the multi-layered aquifer contained in the 600-m-thick basement of the lake. The 14C activity of total dissolved inorganic carbon (TDIC) measured by AMS from bottom and surface lake waters (111.4 and 111.8 pMC, respectively) confirms that the mixing occurs at the water-sediment interface. This evidence of groundwater participation in the carbonate crystallization calls into question the current paleoclimatic reconstructions based on inorganic carbonates in lakes. Specific attention should thus be given to the respective proportions of each end-member in the mixing for the quantitative estimation of the groundwater input. This will help to validate the paleoenvironmental reconstructions and to highlight an eventual diagenetical evolution of inorganic carbonates during burial, via the study of pore waters.


2019 ◽  
Vol 132 (3-4) ◽  
pp. 562-587 ◽  
Author(s):  
L.P. Birgenheier ◽  
M.D. Vanden Berg ◽  
P. Plink-Björklund ◽  
R.D. Gall ◽  
E. Rosencrans ◽  
...  

Abstract In light of a modern understanding of early Eocene greenhouse climate fluctuations and new highly seasonal fluvial system faces models, the role of climate in the evolution of one classically-cited continental, terminal lake system is re-examined. Detailed stratigraphic description and elemental abundance data from fifteen cores and seven outcrop regions of the Green River Formation were used to construct a ∼150 km cross section across the Uinta Basin, Utah, USA. Lake Uinta in the Uinta Basin is divided into five lake phases: (1) post-Paleocene Eocene Thermal Maximum, (2) peak Eocene hyperthermal, (3) waning hyperthermal, Early Eocene Climatic Optimum (EECO), (4) post-hyperthermal, and (5) post-EECO regimes, based primarily on climatically driven changes in fluvial style in combination with sedimentary indicators of lacustrine carbonate deposition, organic matter preservation, salinity, and lake depth. Basinwide siliciclastic dominated intervals were deposited by highly seasonal fluvial systems and record negative organic carbon isotope excursions associated with early Eocene abrupt, transient global warming (hyperthermal) events. Carbonate dominated or organic rich intervals record stable, less seasonal climate periods between hyperthermals, with lower siliciclastic sediment supply allowing the development of carbonate and organic matter preservation. The stratigraphic progression from alternating organic rich and lean zones to the overlying organic rich Mahogany and R8 zones represents the global transition out of the pulsed early Eocene hyperthermal climate regime to a time of sediment starvation and lake stratification, sequestering sedimentary organic carbon. This study provides a novel approach to terrestrial paleoclimate reconstruction that relies largely on unique sedimentary indicators and secondarily on isotopic proxy records within the context of a large basin-wide sedimentologic and stratigraphic data set, thus setting the stage for future detailed geochemical terrestrial paleoclimate proxy development.


Paleobiology ◽  
2017 ◽  
Vol 43 (2) ◽  
pp. 224-247 ◽  
Author(s):  
Evan P. Anderson ◽  
Dena M. Smith

AbstractInsects in the fossil record are generally preserved in lacustrine shales or in amber. For those in lacustrine shales, preservation is usually via keroginization or mineralization. Given the extended period of microbial decay required to generate ions for mineralization, there is a predicted inherent bias toward lower preservation quality for this pathway by most taphonomic indices compared with keroginization. This study tests this hypothesis by comparing multiple measures of preservation quality between sites with similar sedimentology in the Eocene Green River Formation of Colorado. Here, insects are either mineralized in iron oxides (likely after pyrite) at the Paleoburn site or keroginized at the Anvil Points site.Generally, the prediction that keroginization preserves soft-bodied fossils with higher preservational quality than mineralization is affirmed, but with some caveats. Beetles, known for their robust cuticles, are proportionately more abundant at the Paleoburn site, but eight of the nine orders recorded are shared between sites. As predicted, insects show lower preservation fidelity at the Paleoburn site, but they also show higher degrees of disarticulation. This second bias should be acquired primarily during the biostratinomy stage, and not early diagenesis. Nonetheless, higher-energy biostratinomic conditions may be compatible with taphonomic conditions that promote mineralization over keroginization.Comparing the inherent taphonomic bias of different preservation pathways is often difficult, since fossil deposits may be preserved millions of years or thousands of kilometers apart. By studying two different preservation pathways of insects within the same formation, we can affirm that keroginization does indeed preserve recalcitrant organic matter with higher quality than pyritization or iron-oxide mineralization. Additionally, some guidelines can be proposed concerning the body parts and taxa that can be compared, and for what purpose, when contrasting mineralized and keroginized soft-bodied deposits.


2018 ◽  
Vol 55 (4) ◽  
pp. 177-216 ◽  
Author(s):  
Ronald Johnson ◽  
Justin Birdwell ◽  
Tracey Mercier

The Green River Formation deposited in Eocene Lake Uinta in the Uinta and Piceance Basins, Utah and Colorado, contains the largest oil shale resource in the world with an estimated 1.53 trillion barrels of oil in place in the Piceance Basin and 1.32 trillion barrels in the Uinta Basin. The Douglas Creek arch, a slowly subsiding hinge-line between the two basins, created separate deep depocenters, one in each basin with shallow water conditions near the crest of the arch. Lake Uinta was a saline lake throughout its history with a lower saline to hypersaline layer (monimolimnion) and an upper less saline layer (mixolimnion). Most of the organic matter in the Green River Formation was derived primarily from algae that lived in the photic zone of the lake and is very hydrogen-rich and oil-prone. In many modern large and deep lakes, rates of organic matter production are highly variable due to differences in nutrient supply. However, cyclonic circulation often leads to winnowing out of organic and mineral matter in the mixolimnion leading to organic matter and fine-grained mineral matter being deposited in increasing amounts toward hydro-dynamically dead zones in the center of the circulation producing concentric bands of increasing organic matter content. Organic matter transport through the dense, hypersaline monimolimnion may have been facilitated by low density organic matter attaching to more dense clay mineral particles. Most of the oil shale intervals deposited in Lake Uinta display similar patterns in their organic matter distributions, increasing in very regular fashion toward the central areas of the lake’s two depocenters. This concentric feature is particularly prominent in the most laminated oil shale zones. Here, we propose that cyclonic circulation was present in Lake Uinta. Each basin appears to have had its own circulation currents, separated by shallow water conditions near the Douglas Creek arch, and one hydrodynamically dead zone in each basin. Sediment gravity flow processes were also very active in some strata of Lake Uinta, leading to the reworking and re-depositing of sediments. Two general types of sediment gravity flows are recognized: (1) organic-rich sediment gravity flows that reworked and may have concentrated organic-rich material closer to the two deep depocenters, and (2) sandstone- and siltstone-rich organic-poor mass movement deposits that originated on marginal shelves. Mass movements could have been triggered by various natural processes and/or possibly by the movement of dense brines that evolved on marginal shelves and moved along the bottom of the water column toward the deep part of the lake. The uppermost, poorly consolidated sediment layer was incorporated in sediment gravity flows as they moved, and in many cases sediment gravity flows scoured down significantly into the more consolidated underlying sediment producing large rip-up clasts of laminated sediments. Truncation of more than 100 ft occurs at the base of a sequence of sediment gravity flows in one well, indicating a significant incised channel. Coarser-grained sediment gravity flows terminated before reaching the lake’s deepest areas, forming thick concentric buildups of organically lean sediment near the base of the marginal slopes. Intervals dominated by organic-rich fine-grained sediment gravity flows have tightly concentric bands of increasing organic matter toward the deepest parts of the lake and can be organically richer than the richest laminated intervals. There is some evidence that the hydrodynamically quiet zones did not always correspond closely to the deepest areas of the lake, extending in some cases into some shallower areas.


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